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Technology to Control Heterogeneous Catalytic Reactions by Forced Temperature Cycling

Research Project

Project/Area Number 19360360
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionThe University of Tokushima

Principal Investigator

SOTOWA Ken-ichiro  The University of Tokushima, 大学院・ソシオテクノサイエンス研究部, 准教授 (00336009)

Co-Investigator(Kenkyū-buntansha) SUGIYAMA Shigeru  徳島大学, 大学院・ソシオテクノサイエンス研究部, 教授 (70175404)
KATOH Masahiro  徳島大学, 大学院・ソシオテクノサイエンス研究部, 准教授 (80274257)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2008: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2007: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
Keywords反応率 / 吸着 / 触媒 / 選択率 / 非定常 / 温度周期操作 / 一酸化炭素 / 最適化 / 触媒反応
Research Abstract

Chemical reactors are usually operated at a steady state. In this work, the effect of unsteady state operations on the conversion of catalytic reactions was studied. A chemical reactor particularly suited for temperature cycling operation was developed, and in an experimental study conducted using the reactor, it was demonstrated that a higher conversion can be achieved by employing a temperature cycling operation. Also, a result from a theoretical study showed that there are cases where further acceleration of chemical reaction can be expected.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (57 results)

All 2010 2009 2008 2007 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (48 results)

  • [Journal Article] The Effect of Carbon Monoxide on the Hydrogen Permeability of a Palladium Membrane2010

    • Author(s)
      M.Katoh, et al.
    • Journal Title

      International Journal of Modern Physics B (印刷中)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application of the Unique Redox Properties of Magnesiumortho-Vanadate Incorporated with Palladium in the Unsteady-state Operation of the Oxidative Dehydrogenation of Propane2008

    • Author(s)
      Sugiyama S, et al.
    • Journal Title

      Journal of Catalysis 260

      Pages: 157-163

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidative Dehydrogenation of Propane over Vanadate Catalysts-on calcium and Strontium Hydroxyapatites2008

    • Author(s)
      S. Sugiyama
    • Journal Title

      Journal of the Japan Petroleum Institute 51

      Pages: 50-57

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Removal and Regeneration of Aqueous Divalent Cations Using Boehmite2008

    • Author(s)
      S. Sugiyama
    • Journal Title

      Journal of Colloid and Interface Science 320

      Pages: 535-539

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Redox Nature of Fe-incorporated Magnesium ortho-Vanadate as a Catalyst for the Oxidative Dehydrogenation of Propane2007

    • Author(s)
      S. Sugiyama, T. Osaka, Y. Hirata, Y. Kondo, K. Nakagawa, K.-I. Sotowa
    • Journal Title

      Journal of Chemical Engineering of Japan Vol.40,No.12

      Pages: 1064-1071

    • NAID

      10020287511

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 51V MAS NMR and XAFS Evidences for Redox of Magnesium pyro-and ortho-Vanadates on the Oxidative Dehydrogenation of Propane2007

    • Author(s)
      S. Sugiyama
    • Journal Title

      Journal of the Ceramic Society of Japan 115

      Pages: 667-671

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Redox Nature of Fe-incorporated Magnesium ortho-Vanadate as a Catalyst for the Oxidative Dehydrogenation of Propane2007

    • Author(s)
      S. Sugiyama
    • Journal Title

      Journal of Chemical Engineering of Japan 40

      Pages: 1064-1071

    • NAID

      10020287511

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application of a Microreactor in the Oxidative Dehydrogenation of Propane to Propylene on Calcium Hydroxyapatite and Magnesium ortho-Vanadate Doped and Undoped with Palladium

    • Author(s)
      S. Sugiyama, N. Sugimoto, A. Ozaki, Y. Furukawa, K. Nakagawa, K.-I. Sotowa
    • Journal Title

      Journal of Chemical Engineering of Japan (in press)

    • NAID

      10027373076

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] he Effect of Carbon Monoxide on the Hydrogen Permeability of a Palladium Membrane

    • Author(s)
      M. Katoh, K. Nishihara, K. Kinouchi, K. Chohama, T. Horikawa, T. Tomida, K.-I. Sotowa
    • Journal Title

      International Journal of Modern Physics B (in press)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Presentation] マイクロリアクタによるプロパン酸化脱水素反応への酸化物およびリン酸塩触媒の適応性2010

    • Author(s)
      杉山茂, 他
    • Organizer
      第105回触媒討論会(触媒討論会A)
    • Place of Presentation
      京都テルサ(京都府)
    • Year and Date
      2010-03-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] Highly Selective Production of Propylene from the Oxidative Dehydrogenation of Propane on Hydroxyapatite Using Microreactor2010

    • Author(s)
      S.Sugiyama, et al.
    • Organizer
      11th International Conference on Microreaction Technology
    • Place of Presentation
      京都リサーチパーク(京都府)
    • Year and Date
      2010-03-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] Periodic operation Steady state Highly Selective Production of Propylene from the Oxidative Dehydrogenation of Propane on Dydroxyapatite using Microreactor2010

    • Author(s)
      S. Sugiyama, N. Sugimoto, A. Ozaki, Y. Furukawa, K. Nakagawa, K. -I. Sotowa
    • Organizer
      11th International Conference on Microeaction Technology
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2009 Final Research Report
  • [Presentation] Reaction Kinetics and Conversion of CO Oxidation under Forced Temperature Cycling2009

    • Author(s)
      奥山大輔, 他
    • Organizer
      22th Symposium on Chemical Engineering
    • Place of Presentation
      デジョン・コンベンション・センター(大韓民国)
    • Year and Date
      2009-12-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] Reaction Mechanism and the Effect of Forced Temperature Cycling on the Reactor Performance2009

    • Author(s)
      K.-I.Sotowa, et al.
    • Organizer
      AIChE Annual Meeting 2009
    • Place of Presentation
      ゲイロード・オプリーランド・ホテル(アメリカ合衆国)
    • Year and Date
      2009-11-13
    • Related Report
      2009 Annual Research Report
  • [Presentation] 非定常操作下におけるマイクロリアクタによるプロパンの酸化脱水素反応2009

    • Author(s)
      杉山茂, 他
    • Organizer
      第2回化学工学3支部合同北九州大会
    • Place of Presentation
      西日本総合展示場(福岡県)
    • Year and Date
      2009-10-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] マイクロリアクタによるプロパン酸化脱水素反応2009

    • Author(s)
      杉本直人, 他
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学(広島県)
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] 温度周期操作下における不均に一触媒反応の平均反応速度と素反応の温度依存性の関係2009

    • Author(s)
      外輪健一郎, 他
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学(広島県)
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] PtもしくはNi触媒を充填したPd膜型反応器によるメタンのドライリフォーミング2009

    • Author(s)
      木内浩二, 他
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学(広島県)
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Pd膜型反応器を用いたメタンのドライリフォーミングの最適操作条件の検討2009

    • Author(s)
      西原克矩, 他
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学(広島県)
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] 温度周期操作下におけるCO酸化反応に及ぼす操作条件の影響2009

    • Author(s)
      奥山大輔, 他
    • Organizer
      第3回中四国若手CE合宿
    • Place of Presentation
      かんぽの宿徳島(徳島県)
    • Year and Date
      2009-08-06
    • Related Report
      2009 Annual Research Report
  • [Presentation] Reaction Kinetics and Conversion of CO Oxidation under Forced Temperature Cycling2009

    • Author(s)
      D. Okuyama, K. -I. Sotowa, K. Nakagawa, S. Sugiyama
    • Organizer
      22nd Symposium on Chemical Engineering
    • Place of Presentation
      Daejeon, Korea
    • Related Report
      2009 Final Research Report
  • [Presentation] Oxidative Dehydrogenation of Propane in Microreactor under Steady State and Unsteady State Operations2009

    • Author(s)
      N. Sugimoto, K. Nakagawa, K. -I. Sotowa, S. Sugiyama
    • Organizer
      22nd Symposium on Chemical Engineering
    • Place of Presentation
      Daejeon, Korea
    • Related Report
      2009 Final Research Report
  • [Presentation] Reaction Mechanism and the Effect of Forced Temperature Cycling on the Reactor Performance2009

    • Author(s)
      K. -I. Sotowa, K. Nakagawa, S. Sugiyama
    • Organizer
      AIChE Annual Meeting 2009
    • Place of Presentation
      Nashville, USA
    • Related Report
      2009 Final Research Report
  • [Presentation] 温度周期操作下における不均一触媒反応の平均反応速度と素反応の温度依存性の関係2009

    • Author(s)
      外輪健一郎, 黒田勝也, 奥山大輔, 杉山茂, 中川敬三
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島
    • Related Report
      2009 Final Research Report
  • [Presentation] Effect of feed concentration on CO oxidation under forced temperature cycling2008

    • Author(s)
      Kuroda K., et al.
    • Organizer
      21st Symposium on Chemical Engineering
    • Place of Presentation
      Saga University (Saga)
    • Year and Date
      2008-12-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] Employment of Microreactor to the Oxidative Dehydrogenation of Propane2008

    • Author(s)
      Sugiyama S, et al.
    • Organizer
      21th Symposium on Chemical Engineering
    • Place of Presentation
      Saga University (Saga)
    • Year and Date
      2008-12-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] The Effect of Carbon Monoxide on the Hydrogen Permeability of a Palladium Membrane on Porous Stainless-Steel Support2008

    • Author(s)
      Katoh M, et al.
    • Organizer
      International Conference on Advanced Mate rials, Development and Performance 2008
    • Place of Presentation
      北京航空航天大学(中国・北京)
    • Year and Date
      2008-10-15
    • Related Report
      2008 Annual Research Report
  • [Presentation] The Catalytic Hydrogen Production by Dry-Reforming of Methane over Ni/Al_2O_3 Catalysts using a Pd Membrane Reactor2008

    • Author(s)
      Katoh M, et al.
    • Organizer
      International Conference on Advanced Materials, Development and Performance2008
    • Place of Presentation
      北京航空航天大学(中国・北京)
    • Year and Date
      2008-10-15
    • Related Report
      2008 Annual Research Report
  • [Presentation] The Hydrogen Production by Methane Dry Reforming over Pt/Al_2O_3 Catalysts using Palladium Membrane Reactor on Porous Stainless-Steel Support2008

    • Author(s)
      Katoh M, et al.
    • Organizer
      International Conference on Advanced Mate rials, Development and Performance 2008
    • Place of Presentation
      北京航空航天大学(中国・北京)
    • Year and Date
      2008-10-14
    • Related Report
      2008 Annual Research Report
  • [Presentation] 温度周期操作デバイスの熱的挙動と一酸化炭素の酸化反応への適用2008

    • Author(s)
      石花 健太
    • Organizer
      化学工学会第73年会
    • Place of Presentation
      静岡大学(浜松市)
    • Year and Date
      2008-03-18
    • Related Report
      2007 Annual Research Report
  • [Presentation] パラジウム膜による水素分離への一酸化炭素の影響2008

    • Author(s)
      西原 克矩
    • Organizer
      第10回化学工響牲発表会大阪大会(西日本地区)
    • Place of Presentation
      関西大学(大阪)
    • Year and Date
      2008-03-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] 触媒充填型パラジウム膜反応器によるメタンのドライリフォーミング2008

    • Author(s)
      木内 浩二
    • Organizer
      第10回化学工学会学生発表会大阪大会(西日本地区)
    • Place of Presentation
      関西大学(大阪)
    • Year and Date
      2008-03-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Effect of Feed Concentration on CO Oxidation under Forced Temperature Cycling2008

    • Author(s)
      K. Kuroda, K. -I. Sotowa, S. Sugiyama, K. Nakagawa
    • Organizer
      21st Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Japan
    • Related Report
      2009 Final Research Report
  • [Presentation] Time-Average Reaction rate of CO Oxidation over Pt/Al2O3 Catalyst under Forced Temperature Cycling2008

    • Author(s)
      K. -I. Sotowa, K. Kuroda, K. Nakagawa, S. Sugiyama
    • Organizer
      International Workshop on Process Intensification
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2009 Final Research Report
  • [Presentation] 温度周期操作デバイスの熱的挙動と一酸化炭素の酸化反応への適用2008

    • Author(s)
      石花健太, 外輪健一郎, 黒田勝也, 中川敬三, 杉山茂
    • Organizer
      化学工学会第73年会
    • Place of Presentation
      浜松
    • Related Report
      2009 Final Research Report
  • [Presentation] 温度周期操作下におけるCO酸化反応に及ぼす原料濃度の影響2008

    • Author(s)
      黒田 勝也等
    • Organizer
      化学工学会第40回秋季大会
    • Place of Presentation
      東北大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] Time-average reaction rate of CO oxidation over Pt/Al_2O_3 catalyst under forced temperature cycling2008

    • Author(s)
      Sotowa K. -I., et al.
    • Organizer
      International Workshop on Process Intensification (IWPI)2008
    • Place of Presentation
      Tokyo Institute of Technology (Tokyo)
    • Related Report
      2008 Annual Research Report
  • [Presentation] パラジウム膜型反応器を用いたメタンのドライリフォーミングによる水素製造2008

    • Author(s)
      加藤雅裕等
    • Organizer
      化学工学会第40回秋季大会
    • Place of Presentation
      東北大学(仙台)
    • Related Report
      2008 Annual Research Report
  • [Presentation] Application of Unsteady-state Operation to the Oxidative Dehydrogenation of Propane on Magnesium ortho-Vanadate Doped with Palladium2008

    • Author(s)
      Sugiyama S, et al.
    • Organizer
      14th International Congress on Catalysis
    • Place of Presentation
      COEX, Seoul (Korea)
    • Related Report
      2008 Annual Research Report
  • [Presentation] カルシウム水酸アパタイト薄膜による重金属の回収-溶出特性2008

    • Author(s)
      杉山 茂
    • Organizer
      化学工学会第73年会
    • Place of Presentation
      静岡大学(浜松)
    • Related Report
      2007 Annual Research Report
  • [Presentation] 酸素加圧下における乳酸類の液相脱水素酸化反応2008

    • Author(s)
      上原 裕也
    • Organizer
      化学工学会第73年会
    • Place of Presentation
      静岡大学(浜松)
    • Related Report
      2007 Annual Research Report
  • [Presentation] 各種水酸アパタイト担持バナデート触媒によるプロパンの酸化脱水素反応2008

    • Author(s)
      杉山 茂
    • Organizer
      第101回触媒討論会(触媒討論会A)
    • Place of Presentation
      タワーホール船堀(東京)
    • Related Report
      2007 Annual Research Report
  • [Presentation] Oxidation of Carbon Monoxide under Forced Temperature Cycling2007

    • Author(s)
      K. Kuroda
    • Organizer
      20th Symposium on Chemical Engineering
    • Place of Presentation
      Hanbat University(Korea)
    • Year and Date
      2007-12-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Effects of oxygen on the catalytic conversion of lactate in liquid phase2007

    • Author(s)
      Y. Uehara
    • Organizer
      20th Symposium on Chemical Engineering, Kyushu-Taejon/Chungnam
    • Place of Presentation
      Hanbat University(Korea)
    • Year and Date
      2007-12-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Oxidative dehydrogenation of propane on Mg3V208 doped with palladium2007

    • Author(s)
      Y. Hirata
    • Organizer
      20th Symposium on Chemical Engineering, Kyushu-Taejon/Chungnam
    • Place of Presentation
      Hanbat University(Korea)
    • Year and Date
      2007-12-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Removal and regeneration of aqueous heavy metal cations using thin-layer of calcium hydroxyapatite2007

    • Author(s)
      Y. Shimizu
    • Organizer
      20th Symposium on Chemical Engineering, Kyushu-Taejon/Chungnam
    • Place of Presentation
      Hanbat University(Korea)
    • Year and Date
      2007-12-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Removal of various aqueous anions with boehmite2007

    • Author(s)
      T. Manabe
    • Organizer
      20th Symposium on Chemical Engineering, Kyushu-Taejon/Chungnam
    • Place of Presentation
      Hanbat University(Korea)
    • Year and Date
      2007-12-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Conversion of 6thanol and ethylene on MCM-41 and related catalysts2007

    • Author(s)
      Y. Katoh
    • Organizer
      20th Symposium on Chemical Engineering, Kyushu-Taejon/Chungnam
    • Place of Presentation
      Hanbat University(Korea
    • Year and Date
      2007-12-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] パラジウム膜による水素分離への共存気体の影響2007

    • Author(s)
      長浜 宏一
    • Organizer
      化学工学会第39回秋季大会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2007-09-13
    • Related Report
      2007 Annual Research Report
  • [Presentation] Oxidation of Carbon Monoxide under Forced Temperature Cycling2007

    • Author(s)
      K. Kuroda, K. Ishihana, K. -I. Sotowa, S. Sugiyama, K. Nakagawa
    • Organizer
      20th Symposium on Chemical Engineering
    • Place of Presentation
      Daejeon, Korea
    • Related Report
      2009 Final Research Report
  • [Presentation] Dehydrogenation of cycloalkanes over noble metal catalysts supported on active carbon2007

    • Author(s)
      S. Sugiyama
    • Organizer
      11th Korea-Japan Symposium on Catalysis
    • Place of Presentation
      Yonsei University,Seoul(Korea)
    • Related Report
      2007 Annual Research Report
  • [Presentation] 51V MAS NMR and XAFS evidence on redox nature of Fe-incorporated Mg3V208 for theoxidative dehydrogenation of propane2007

    • Author(s)
      S. Sugiyama
    • Organizer
      11th Korea-Japan Symposium on Catalysis
    • Place of Presentation
      Yonsei University,Seoul(Korea)
    • Related Report
      2007 Annual Research Report
  • [Presentation] 乳酸類の液相酸化脱水素によるピルビン酸類の合成2007

    • Author(s)
      上原 裕也
    • Organizer
      化学工学会第39回秋季大会
    • Place of Presentation
      北海道大学(北海道)
    • Related Report
      2007 Annual Research Report
  • [Presentation] 貴金属導入バナジン酸マグネシウム触媒によるプロパンの酸化脱水素反応2007

    • Author(s)
      平田 祐規
    • Organizer
      化学工学会第39回秋季大会
    • Place of Presentation
      北海道大学(北海道)
    • Related Report
      2007 Annual Research Report
  • [Presentation] リン酸カルシウム類による重金属の回収-溶出特性2007

    • Author(s)
      清水 由佳
    • Organizer
      化学工学会第39回秋季大会
    • Place of Presentation
      北海道大学(北海道)
    • Related Report
      2007 Annual Research Report
  • [Presentation] 第二金属含有マグネシウムピロおよびオルトバナデートによるプロパンの酸化脱水素反応2007

    • Author(s)
      杉山 茂
    • Organizer
      第100回触媒討論会(触媒討論会A)
    • Place of Presentation
      北海道大学(北海道)
    • Related Report
      2007 Annual Research Report
  • [Presentation] ベーマイトによる水溶性リン酸の除去回収技術の開発研究2007

    • Author(s)
      杉山 茂
    • Organizer
      第17回無機リン化学討論会
    • Place of Presentation
      JST研究開発プラザ北海道(北海道)
    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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