Construction of ion conduction channel of hierarchic structure and its application to high power battery materials

• Project/Area Number: 19360438
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Energy engineering
• Research Institution: Kyoto University
• Principal Investigator: YAO Takeshi Kyoto University, エネルギー科学研究科, 教授 (50115953)
• Co-Investigator(Kenkyū-buntansha): HIBINO Mitsuhiro 京都大学, エネルギー科学研究科, 准教授 (20270910)
• Project Period (FY): 2007 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥19,890,000 (Direct Cost: ¥15,300,000、Indirect Cost: ¥4,590,000); Fiscal Year 2008: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2007: ¥14,950,000 (Direct Cost: ¥11,500,000、Indirect Cost: ¥3,450,000)
• Keywords: ハイパワー電池 / リチウムイオン電池 / 燃料電池 / 高イオン伝導 / 複合材料 / コバルトバナジウム酸化物 / バリウムインジウム酸化物 / 一室式燃料電池 / グラファイト層間化合物

Research Abstract

ハイパワー電池材料を得るために様々なイオン伝導チャンネルをもつ構造体の構築を目指した。一次元系サブナノ伝導チャンネル物質CoV3O8 について構造を精密に調べ、リチウム挿入サイトをほぼ決定した。二次元系伝導チャンネル物質のグラファイト層間化合物においてリチウムの挿入過程及び引き抜き過程における構造変化を詳細に調べた。さらに、三相界面に適した複合伝導チャンネル構造を探索し、部分酸化反応とガス拡散とを両立した高い出力特性の燃料極支持型一室式燃料電池を作製した。

Research Products

• [Journal Article] Lithium Intercalation Behavior of Cobalt Vanadium Oxide CoV_3O_8 Studied on the Basis of Rietveld Analysis (2009)
  • Author(s): Shin-nosuke Ichikawa, Mitsuhiro Hibino, and Takeshi Yao
  • Journal Title: Journal of the Electrochemical Society 156
  • Peer Reviewed
• [Journal Article] Lithium Intercalation Behavior of Cobalt Vanadium Oxide CoV308 Studied on the Basis of Rietveld Analysis (2009)
  • Author(s): Shin-nosuke Ichikawa, Mitsuhiro Hibind, Takeshi Yao
  • Journal Title: Journal of the Electrochemical Society 156
  • Peer Reviewed
• [Journal Article] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV_3O_8 (2008)
  • Author(s): Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
  • Journal Title: Solid State Ionics 179 Pages: 1688-1692
  • Peer Reviewed
• [Journal Article] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV308 (2008)
  • Author(s): Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
  • Journal Title: Solid State Ionics 179 Pages: 1688-1692
  • Peer Reviewed
• [Journal Article] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV308 (2008)
  • Author(s): Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
  • Journal Title: Solid State Ionics(19年度中に掲載決定通知を受けている) (未定)
  • Peer Reviewed
• [Journal Article] Reversible and rapid discharge-charge performance of gamma-Fe_2O_3 prepared by aqueous solution method as the cathode for lithium-ion battery (2007)
  • Author(s): Mitsuhiro Hibino, Jumpei Terashima, Takeshi Yao
  • Journal Title: Journal of the electrochemical society 154
  • Peer Reviewed
• [Journal Article] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV_3O_8 (2007)
  • Author(s): Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
  • Journal Title: Journal of the electrochemical society 154
  • Peer Reviewed
• [Journal Article] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV308 (2007)
  • Author(s): Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
  • Journal Title: Journal of the electrochemical society 154
  • Peer Reviewed
• [Journal Article] Reversible and rapid discharge-charge performance of gamma-Fe203 prepared by aqueous solution method as the cathode for lithium-ion battery (2007)
  • Author(s): Mitsuhiro Hibino, Jumpei Terashima, Takeshi Yao
  • Journal Title: Journal of the electrochemical society 154
  • Peer Reviewed
• [Presentation] 遷移金属置換Ba-In系酸化物の導電特性 (2009)
  • Author(s): 小林輝明、長谷坂彰史、高橋景子、日比野光宏、八尾健
  • Organizer: 電気化学秋季大会
  • Place of Presentation: 東工大大岡山
  • Year and Date: 2009-09-19
• [Presentation] バナジウムコバルト酸化物CoV3O8のリチウムインターカレーション特性 (2008)
  • Author(s): 市川慎之介、日比野光宏、八尾健
  • Organizer: 第34回固体イオニクス討論会
  • Place of Presentation: 東京
  • Year and Date: 2008-12-05
• [Presentation] バナジウムコバルト酸化物CoV308のリチウムインターカレーション特性 (2008)
  • Author(s): 市川慎之介, 日比野光宏, 八尾健
  • Organizer: 第34回固体イオニクス討論会
  • Place of Presentation: 東京
  • Year and Date: 2008-12-05
• [Presentation] Electrochemcial Lithiation Property of γ-Fe_2O_3/Carbon (2008)
  • Author(s): Mitsuhiro Hibino, Naomi Okazaki, Hiroshi Kawada and Takeshi Yao
  • Organizer: 第34 回固体イオニクス討論会・Japan-Korea Joint Session
  • Place of Presentation: 東京
  • Year and Date: 2008-12-04
• [Presentation] Electrochemcial Lithiation Property of γ-Fe203/Carbon (2008)
  • Author(s): Mitsuhiro Hibino, Naomi Okazaki, Hiroshi Kawada, Takeshi Yao
  • Organizer: 第34回固体イオニクス討論会・Japan-Korea Joint Session
  • Place of Presentation: 東京
  • Year and Date: 2008-12-04
• [Presentation] γ-Fe_2O_3/炭素複合体リチウムイオン二次電池正極の高速充放電特性 (2008)
  • Author(s): 日比野光宏、岡崎直美、川田浩史、八尾健
  • Organizer: 第49 回電池討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-11-05
• [Presentation] 電気化学的にリチウムイオンを挿入したγ-Fe_2O_3 の結晶構造解析 (2008)
  • Author(s): 山内智、日比野光宏、八尾健
  • Organizer: 第49回電池討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-11-05
• [Presentation] γ-Fe203/炭素複合体リチウムイオン二次電池正極の高速充放電特性 (2008)
  • Author(s): 日比野光宏, 岡崎直美, 川田浩史, 八尾健
  • Organizer: 第49回電池討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-11-05
• [Presentation] 電気化学的にリチウムイオンを挿入した γ-Fe203の結晶構造解析 (2008)
  • Author(s): 山内智, 日比野光宏, 八尾健
  • Organizer: 第49回電池討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-11-05
• [Presentation] Analysis of Fe Valence in Li Inserted γ-Fe_2O_3 by X-ray Absorption Edge Measurement (2008)
  • Author(s): Akifumi Hasesaka, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 214th Electrochemical society Meeting
  • Place of Presentation: ハワイ
  • Year and Date: 2008-10-13
• [Presentation] γ-Fe_2O_3/carbon Composite Synthesized by Aqueous Solution Method as Cathode for Lithium-ion Battery (2008)
  • Author(s): Naomi Okazaki, Jumpei Terashima, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 214th Electrochemical society Meeting
  • Place of Presentation: ハワイ
  • Year and Date: 2008-10-13
• [Presentation] Structure Change Analysis in γ-Fe_2O_3/Carbon Composite in the Process of Electrochemical Lithium Insertion (2008)
  • Author(s): Satoshi Yamauchi, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 214th Electrochemical society Meeting
  • Place of Presentation: ハワイ
  • Year and Date: 2008-10-13
• [Presentation] Development of Single Chamber Solid Oxide Fuel Cell using BaLaIn_2O_<5.5>(BLI)Solid Electrolyte : Introduction of Sublimation Materials as Pore Former in Electrode Preparation (2008)
  • Author(s): Yuwa Chompoobutrgool, Hiroaki Suzuki, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 14th Electrochemical society Meeting
  • Place of Presentation: ハワイ
  • Year and Date: 2008-10-13
• [Presentation] Analysis of Fe Valence in Li Insert γ-Fe203 by X-ray Absorption Edge Measurement (2008)
  • Author(s): Akifumi Hasesaka, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 214th Electrochemical society Meeting
  • Place of Presentation: ハワイ
  • Year and Date: 2008-10-13
• [Presentation] γ-Fe203/carbon Composite Synthesized by Aqueous Solution Method as Cathode for Lithium-ion Battery (2008)
  • Author(s): Naomi Okazaki, Jumpei Terashima, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 214th Electrochemical society Meeting
  • Place of Presentation: ハワイ
  • Year and Date: 2008-10-13
• [Presentation] Structure Change Analysis in γ-Fe203/Carbon Composite in the Process of Electrochemical Lithium (2008)
  • Author(s): Satoshi Yamauchi, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 214th Electrochemical society Meeting
  • Place of Presentation: ハワイ
  • Year and Date: 2008-10-13
• [Presentation] Development of Single Chamber Solid Oxide Fuel Cell using BaLaIn205.5 (BLI) Solid Electrolyte : Introduction of Sublimation Materials as Pore Former in Electrode Preparation (2008)
  • Author(s): Yuwa Chompoobutrgool, Hiroaki Suzuki, Mitsuhiro Hibino Takeshi Yao
  • Organizer: 214th Electrochemical society Meeting
  • Place of Presentation: ハワイ
  • Year and Date: 2008-10-13
• [Presentation] gamma-Fe_2O_3/炭素複合体の合成条件とリチウムイオン二次電池電極特性との関係 (2008)
  • Author(s): 岡崎直美、寺島純平、日比野光宏、八尾健
  • Organizer: 電気化学会第75 回大会
  • Place of Presentation: 山梨大学
  • Year and Date: 2008-03-31
• [Presentation] gamma-Fe_2O_3/炭素複合体のリチウムイオン二次電池正極特性 (2008)
  • Author(s): 日比野光宏、寺島純平、八尾 健
  • Organizer: 電気化学会第75 回大会
  • Place of Presentation: 山梨大学
  • Year and Date: 2008-03-31
• [Presentation] gamma-Fe203/炭素複合体の合成条件とリチウムイオン二次電池電極特性との関係 (2008)
  • Author(s): 岡崎直美、寺島純平、日比野光宏、八尾 健
  • Organizer: 電気化学会第75回大会
  • Place of Presentation: 山梨大学
  • Year and Date: 2008-03-31
• [Presentation] gamma-Fe203/炭素複合体のリチウムイオン二次電池正極特性 (2008)
  • Author(s): 日比野光宏、寺島純平、八尾 健
  • Organizer: 電気化学会第75回大会
  • Place of Presentation: 山梨大学
  • Year and Date: 2008-03-31
• [Presentation] gamma-Fe_2O_3/炭素複合体のリチウムイオン二次電池正極特性 (2007)
  • Author(s): 日比野光宏、寺島純平、八尾 健
  • Organizer: 第33 回固体イオニクス討論会
  • Place of Presentation: 名古屋国際会議場
  • Year and Date: 2007-12-06
• [Presentation] 水溶液法によるコバルト添加酸化マンガンの合成とリチウム電池電極特性 (2007)
  • Author(s): 渡邉真吾、日比野光宏、八尾 健
  • Organizer: 第33回固体イオニクス討論会
  • Place of Presentation: 名古屋国際会議場
  • Year and Date: 2007-12-06
• [Presentation] gamma-Fe203/炭素複合体のリチウムイオン二次電池正極特性 (2007)
  • Author(s): 日比野光宏、寺島純平、八尾 健
  • Organizer: 第33回固体イオニクス討論会
  • Place of Presentation: 名古屋国際会議場
  • Year and Date: 2007-12-06
• [Presentation] Crystal Structure and Electrical Conductivity of BaIn1-xM_2O_<3-δ>(M=Ti, V, Cr, Mn, Fe, Co, Ni, Cu) (2007)
  • Author(s): Teruaki Kobayashi, Akifumi Hasesaka, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: International Symposium on Innovative Materials for Processes in Energy Systems
  • Place of Presentation: 京都リサーチパーク
  • Year and Date: 2007-10-28
• [Presentation] Crystal Structure and Electrical Conductivity of BaInl-xM203-δ (M=Ti, V, Cr, Mn, Fe, Co, Ni, Cu) (2007)
  • Author(s): Teruaki Kobayashi, Akifumi Hasesaka, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: International Symposium on Innovative Materials for Processes in Energy Systems
  • Place of Presentation: 京都リサーチパーク
  • Year and Date: 2007-10-28
• [Presentation] Electrode Property of Gamma-Fe_2O_3 Prepared by Aqueous Solution Method as the Cathode for Lithium-Ion Battery (2007)
  • Author(s): Jumpei Terashima, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 212th Electrochemical Society Meeting
  • Place of Presentation: ワシントンDC
  • Year and Date: 2007-10-12
• [Presentation] Electrode Property of Gamma-Fe203 Prepared by Aqueous Solution Method as the Cathode for Lithium-Ion Battery (2007)
  • Author(s): Jumpei Terashima, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 212th Electrochemical Society Meeting
  • Place of Presentation: ワシントンDC
  • Year and Date: 2007-10-12
• [Presentation] BaLa_2In_<5.5>Electrolyte Single Chamber Fuel Cell Using Ni Cermet Anode : Introduction of Barrier Layer Between the Electrolyte and the Anode (2007)
  • Author(s): Hiroaki Suzuki, Kenichi Kanatani, Naoki Fujita, Teruaki Kobayashi, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 212th Electrochemical Society Meeting
  • Place of Presentation: ワシントンDC
  • Year and Date: 2007-10-10
• [Presentation] BaLa2In5.5 Electrolyte Single Chamber Fuel Cell Using NiCermet Anode: Introduction of Barrier Layer Between the Electrolyte and the Anode (2007)
  • Author(s): Hiroaki Suzuki, Kenichi Kanatani, Naoki Fujita, Teruaki Kobayashi, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 212th Electrochemical Society Meeting
  • Place of Presentation: ワシントンDC
  • Year and Date: 2007-10-10
• [Presentation] BaLaIn_2O_<5.5> 電解質一室型燃料電池へのBa-In 系酸化物カソードの適用 (2007)
  • Author(s): 藤田直樹、鈴木博晶、日比野光宏、八尾健
  • Organizer: 電気化学秋季大会
  • Place of Presentation: 東工大大岡山
  • Year and Date: 2007-09-20
• [Presentation] BaLaIn205.5電解質一室型燃料電池へのBa-In系酸化物カソードの適用 (2007)
  • Author(s): 藤田直樹、鈴木博晶、日比野光宏、八尾 健
  • Organizer: 電気化学秋季大会
  • Place of Presentation: 東京工業大学大岡山キャンパス
  • Year and Date: 2007-09-20
• [Presentation] 水溶液法により合成したgamma-Fe_2O_3/炭素複合体のリチウムイオン二次電池電極特性 (2007)
  • Author(s): 寺島純平、日比野光宏、八尾 健
  • Organizer: 電気化学秋季大会
  • Place of Presentation: 東工大大岡山
  • Year and Date: 2007-09-19
• [Presentation] 水溶液法により合成したgamma-Fe203/炭素複合体のリチウムイオン二次電池電極特性 (2007)
  • Author(s): 寺島純平、日比野光宏、八尾 健
  • Organizer: 電気化学秋季大会
  • Place of Presentation: 東京工業大学大岡山キャンパス
  • Year and Date: 2007-09-19
• [Presentation] 遷移金属置換Ba-In系酸化物の導電特性 (2007)
  • Author(s): 小林輝明、長谷坂彰史、高橋景子、日比野光宏、八尾 健
  • Organizer: 電気化学秋季大会
  • Place of Presentation: 東京工業大学大岡山キャンパス
  • Year and Date: 2007-09-19
• [Presentation] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV3O8 (2007)
  • Author(s): Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 16th International Conference on Solid State Ionics
  • Place of Presentation: 上海
  • Year and Date: 2007-07-05
• [Presentation] Electrode property of transition metal incorporated manganese oxide prepared by aquous solution method (2007)
  • Author(s): Mitsuhiro Hibino, Shingo Watanabe, Takeshi Yao
  • Organizer: 16th International Conference on Solid State Ionics
  • Place of Presentation: 上海
  • Year and Date: 2007-07-05
• [Presentation] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV308 (2007)
  • Author(s): Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
  • Organizer: 16th International Conference on Solid State Ionics
  • Place of Presentation: 上海
  • Year and Date: 2007-07-05
• [Presentation] 水溶液法によるコバルト添加酸化マンガンの合成とリチウム電池電極特性 (2007)
  • Author(s): 渡邉真吾、日比野光宏、八尾 健
  • Organizer: 第33 回固体イオニクス討論会
  • Place of Presentation: 名古屋国際会議場
• [Remarks]
  • URL: http://fssc.energy.kyoto-u.ac.jp/index.htm
• [Remarks] 受賞テクノ愛'08大学の部・アイデア賞「昇華性物質混合による高機能多孔性燃料電池電極の形成」Yuwa Chompoobutrgool
• [Remarks]
  • URL: http://fssc.energy.kyoto-u.ac.jp/index.htm
• [Remarks]
  • URL: http://fssc.energy.kyoto-u.ac.jp/index.htm