| Budget Amount *help |
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2009: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2008: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2007: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
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| Research Abstract |
The objective of this research is comprehensive understanding of the chemistry of N-heterocyclic carbenes (NHCs) and that of ionic liquids (ILs), those have recently received much attention but have been independently studied. During the term of this research project, we have succeeded in finding a novel catalytic asymmetric three-component coupling reaction of 1,3-diene, aldehyde, and silanes using a chiral NHC nickel complex. And, we have also established two Rh-catalyzed cyclizations, in which catalyst can be recycled in several times, by using IL as a reaction medium.
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