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Preparation of nano-structured catalysts by the intercalation ofpillar complexes and their application to oxidation reaction

Research Project

Project/Area Number 19560771
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionChiba University

Principal Investigator

SHIMAZU Shogo  Chiba University, 大学院・工学研究科, 教授 (10178957)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2008: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2007: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Keywordsナノ構造触媒 / パラジウム錯体 / 酸化反応 / 層状粘土鉱物 / アルキルアミン配位子 / アニオン交換体 / インターカレーション / 分子状酸素 / アルコール酸化反応 / 粘土鉱物 / 層状無機アニオン交換体
Research Abstract

本研究ではパラジウム(Pd)-アルキルアミン(Ln ; n=4, 8, 12, 16n : アルキル基の炭素数)型錯体を粘土鉱物層間に固定する新規な方法によりナノ構造触媒を創製し、分子状酸素を用いるアルコール酸化反応に応用した。さらに安定なパラウムPd(II)種の固定化を目指し、有機配位子を持たない[Pd(OH)_4]^(2-)を層状無機アニオン交換体層間に固定化して、反応後もPd(II)を保持した再使用可能で安定なPd(II)触媒を開発した。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report

Research Products

(27 results)

All 2009 2008 2007

All Journal Article Presentation Book

  • [Journal Article] Promoting Effect of Iron for theNitriding Process of Niobium Oxide into NbNCatalysts2009

    • Author(s)
      Y. Wakai, T. Hara, K. K. Bando, N. Ichikuni, S. Shimazu
    • Journal Title

      Topics in Catalysis (In press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly Efficient Alcohol Oxidation Catalyzed by Palladium(II)-alkylamine Complexes Using Atmospheric Molecular Oxygen2008

    • Author(s)
      S. Shimazu, T. Uehara, A. Asami, T. Hara, and N. Ichikuni
    • Journal Title

      Journal of Molecular Catalysis A : Chem 282

      Pages: 28-33

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of supported NbC catalysts from peroxoniobic acid and in situ XAFS characterization2008

    • Author(s)
      S. Kodama, N. Ichikuni, K. Bando, T. Hara, and S. Shimazu
    • Journal Title

      Applied Catalysis A : General 343

      Pages: 25-28

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] The influence of metals and acidic oxide specieson the steam reforming of dimethyl ether (DME)2008

    • Author(s)
      T. Fukunaga, N. Ryumon, and S. Shimazu
    • Journal Title

      Applied Catalysis A : General 348

      Pages: 193-200

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 新規アニオン交換性粘土-Pd(II)ナノ複合体触媒による空気を酸化剤とするアルコール酸化反応2008

    • Author(s)
      原孝佳、石川正和、一國伸之、島津省吾
    • Journal Title

      触媒 50(6)

      Pages: 520-522

    • NAID

      10024280161

    • Related Report
      2008 Final Research Report
  • [Journal Article] Highly efficient Alcohol oxidation Catalyzed by Palladium(II)-alkylamine Complexes using Atmospheric Molecular Oxygen2008

    • Author(s)
      S. Shimizu
    • Journal Title

      Journal of Molecular Catalysis A:Chem. 282

      Pages: 28-33

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 新規アニオン交換性粘土-Pd(II)複合体触媒による空気を酸化剤とするアルコール酸化反応2008

    • Author(s)
      原孝佳
    • Journal Title

      触媒 50

      Pages: 520-522

    • Related Report
      2008 Annual Research Report
  • [Journal Article] Preparation of supported NbC catalysts from peroxoniobic acid in situ XAFS characterization2008

    • Author(s)
      S. Kodama
    • Journal Title

      Applied Catalysis A:General 343

      Pages: 25-28

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The influence of metals and acidic oxide species on the steam reforming of dimethyl ether(DME)2008

    • Author(s)
      T. Fukunaga
    • Journal Title

      Applied Catalysis A:General 348

      Pages: 193-200

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Efficient Alcohol Oxidation Catalyzed by Palladium(II)-alkylamine Complexes Using Atmospheric Molecular Oxygen2008

    • Author(s)
      S. Shimazu
    • Journal Title

      Journal of Molecular Catalysis A : Chem 282

      Pages: 28-33

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective Ring Opening Reactions of Oxiranes with Acrylic Acid by Clay Supported Zirconium β-diketonate Catalysts2007

    • Author(s)
      S. Shimazu, H. Zou, T. Hara, and N. Ichikuni
    • Journal Title

      Journal of Ion Exchange 18(4)

      Pages: 548-589

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Co addition for carburizing process of Ti-oxide/SiO_2 into TiC/SiO_22007

    • Author(s)
      Y. Iwama, N. Ichikuni, K. Bando, and S. Shimazu
    • Journal Title

      Applied Catalysis, A : General 323

      Pages: 104-109

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective Ring Opening Reactions of Oxiranes with Acrylic Acid by Clay Supported Zirconium β-diketonate Catalysts2007

    • Author(s)
      S. Shimazu
    • Journal Title

      Journal of Ion Exchange 18(4)

      Pages: 548-589

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 無機イオン交換体を利用したナノ構造体触媒の創製2007

    • Author(s)
      島津省吾
    • Journal Title

      日本イオン交換学会誌 18(2)

      Pages: 60-67

    • NAID

      130004162399

    • Related Report
      2007 Annual Research Report
  • [Presentation] 層状アニオン交換性複塩基性塩固定化Pd(II)錯体触媒の合成とグリーンなアルコール酸化反応への応用2008

    • Author(s)
      原 孝佳、石川正和、一國伸之、島津省吾
    • Organizer
      24回日本イオン交換研究発表会
    • Place of Presentation
      上智大学(I-106)
    • Year and Date
      2008-10-11
    • Related Report
      2008 Final Research Report
  • [Presentation] 新規アニオン交換性粘土-Pd(II)ナノ複合体触媒による空気を酸化剤とするアルコール酸化反応2008

    • Author(s)
      島津省吾
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] Creation of Clay-Palladium(II) Nanocomposite Catalyst for Green Alcohol Oxidation2008

    • Author(s)
      T. Hara, M. Ishikawa, N. Ichikuni, S. Shimazu
    • Organizer
      3^<rd> Indonesia-Japan Joint Scientific Symposium
    • Place of Presentation
      Chiba University(201)
    • Year and Date
      2008-09-10
    • Related Report
      2008 Final Research Report
  • [Presentation] Creation of Clay-Palladium(II) Nanocomposite Catalyst for Green Alcohol Oxidation2008

    • Author(s)
      S. Shimizu
    • Organizer
      3^<rd> Indonesia-Japan Joint Scientific Symposium
    • Place of Presentation
      千葉大学
    • Year and Date
      2008-09-10
    • Related Report
      2008 Annual Research Report
  • [Presentation] Development of Clay-Palladium(II) Nanocomposite Catalyst for Green Alcohol Oxidation2008

    • Author(s)
      S. Shimizu
    • Organizer
      5^<th> International Conference on Envirionmental Catalysis
    • Place of Presentation
      Belfast, UK
    • Year and Date
      2008-09-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] Development of novel clay-palladium nanocomposite catalyst for aerobic alcoholoxidation2008

    • Author(s)
      T. Hara, M. Ishikawa, N. Ichikuni, and S. Shimazu
    • Organizer
      the 14^<th> International Conference on Catalysis
    • Place of Presentation
      Seoul(PIII-53-40)
    • Year and Date
      2008-07-17
    • Related Report
      2008 Final Research Report
  • [Presentation] Development of novel clay-palladium nanocomposite catalyst for aerobic alcohol oxidation2008

    • Author(s)
      S. Shimizu
    • Organizer
      the 14^<th> International Conference on Catalysis
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2008-07-17
    • Related Report
      2008 Annual Research Report
  • [Presentation] Development of Clay-Palladium(II) Nanocomposite Catalyst for Green Alcohol Oxidation2008

    • Author(s)
      T. Hara, M. Ishikawa, N. Ichikuni, and S. Shimazu
    • Organizer
      5^<th> International Conference on Envirionmental Catalysis
    • Place of Presentation
      Belfast, UK(364)
    • Related Report
      2008 Final Research Report
  • [Presentation] Development of Novel Clay-Palladium Nanocomposites as an Aerobic Alcohol Oxidation Catalyst2007

    • Author(s)
      M. Ishikawa, T. Hara, N. Ichikuni, and S. Shimazu
    • Organizer
      The 4th International Conference on Ion Exchange ICIE '07
    • Place of Presentation
      Chiba University(337)
    • Year and Date
      2007-10-17
    • Related Report
      2008 Final Research Report
  • [Presentation] アニオン交換を利用した粘土-Pd ナノ複合体触媒によるアルコール酸化反応2007

    • Author(s)
      原 孝佳、石川 正和、一國 伸之、島津 省吾
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      北海道大学(4F13)
    • Year and Date
      2007-09-20
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation of Clay-Palladium Nanocomposite Catalyst and Application forAerobic Alcohol Oxidation2007

    • Author(s)
      M. Ishikawa, T. Hara, N. Ichikuni, and S. Shimazu
    • Organizer
      14^<th> International Symposium on Intercalation Compounds (ISIC)
    • Place of Presentation
      Seoul, Republic of Korea(O9TH-7, 50)
    • Year and Date
      2007-07-14
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation of Clay-Palladium Nanocomposite Catalyst and Application for Aerobic Alcohol Oxidation2007

    • Author(s)
      S. Shimazu
    • Organizer
      14^<th> International Symposium on Intercalation Compounds
    • Place of Presentation
      Seoul, Republic of Korea
    • Year and Date
      2007-06-14
    • Related Report
      2007 Annual Research Report
  • [Book] 第3章高度認識・分離技術編3-15触媒、工業調査2009

    • Author(s)
      原孝佳, 島津省吾
    • Publisher
      図解最先端イオン交換技術のすべて
    • Related Report
      2008 Final Research Report

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Published: 2007-03-31   Modified: 2016-04-21  

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