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Developmentof photocatalyst with molecular sieve and reactor with hydrogen bond available to photoreaction

Research Project

Project/Area Number 19560773
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionKinki University

Principal Investigator

HASHIMOTO Keiji  Kinki University, 理工学部, シニアサイエンティスト (70425073)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2008: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2007: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords粘土 / 分子篩 / 光触媒 / Potassium zinc aluminum silicate hydroxide / 2-プロパノール / シクロヘキサノール / TiO_2 / 光酸化反応 / 粘土鉱物 / 分子篩機能 / ラングミュアー膜
Research Abstract

亜鉛含有する粘土鉱物を分子篩機能を有する薄膜の前駆体として用い、この薄膜を稀塩酸水溶液で部分的にZnを溶出することにより分子篩機能を持つ細孔を開けた。この細孔の分子篩機能評価を分子サイズの異なる2-プロパノールとシクロヘキサノールの光触媒酸化反応を使って行い、前者の光酸化は起こるが後者の酸化が進行しないことを見出した。この結果、この粘土薄膜で被覆、酸処理することにより、光触媒に分子篩機能を付与できた。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (19 results)

All 2009 2008 2007 Other

All Journal Article (8 results) (of which Peer Reviewed: 4 results) Presentation (10 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article]2009

    • Author(s)
      A. Kamiouji, K. Hashimoto, H. Kominami, S. Ito
    • Journal Title

      Bull. Chem. Soc. Jpn. 82(4)

      Pages: 509-513

    • Related Report
      2008 Final Research Report
  • [Journal Article] Photo-oxidation of nitrogen oxide over titanium (IV) oxide modified with platinum and rhodium chlorides under irradiation of visible light or UV light2009

    • Author(s)
      Keiji Hashimoto
    • Journal Title

      Catal. Today

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rapid Saponification of Fatty Acid Methyl Esters with Aqueous Alkali Hydroxide Solutions Using a Long Narrow Tubular Reactor2009

    • Author(s)
      A. Kamiouji
    • Journal Title

      Topics Catal. (In press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Accelerated saponificat ion of methyl dodecanoate with aqueous sodium in the presence of alcohols in a silicone rubber ubes as a flow-type reactor2009

    • Author(s)
      B. Kamiouji
    • Journal Title

      Bull. Chem. Soc. Jnp. 82 (In press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article]2008

    • Author(s)
      A. Kamiouji, K. Hashimoto, H. Kominami, S. Ito
    • Journal Title

      Ind. Eng. Chem. Res. 47

      Pages: 1464-1464

    • Related Report
      2008 Final Research Report
  • [Journal Article] Continuous Saponification of Methyl Laurate Using Long Narrow Tubes as a Reactor2008

    • Author(s)
      K.Hashimoto
    • Journal Title

      Ind. Eng. Chem. Res 47

      Pages: 1464-1467

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article]

    • Author(s)
      K. Hashimoto, K. Sumida, S. Kitano, K. Yamamoto, N. Kondo, Y. Kera, H. Kominami
    • Journal Title

      Catal. Today DOI:10.1016/j.cattod.2008.12.025

    • Related Report
      2008 Final Research Report
  • [Journal Article]

    • Author(s)
      A. Kamiouji, K. Hashimoto, H. Kominami, S. Ito
    • Journal Title

      Topics Catal DOI 10.1007/sl1244-009-9238-9

    • Related Report
      2008 Final Research Report
  • [Presentation] 芳香族ニトロ化合物の光触媒還元 : 水相-油相分離系の利用-光触媒-2009

    • Author(s)
      今村和也, 岩崎伸一, 前田剛志, 橋本圭司, 古南博
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-28
    • Related Report
      2008 Final Research Report
  • [Presentation] Pd-Ag担持酸化チタン光触媒による水中窒素酸化物イオンの還元無害化-光触媒-2009

    • Author(s)
      月向仁志, 嶋田祐美子, 橋本圭司, 古南博
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-27
    • Related Report
      2008 Final Research Report
  • [Presentation] 可視光応答型光触媒Rh^<3+>/TiO_2による揮発性有機化合物の分解-光触媒-2009

    • Author(s)
      北野翔, 角田勝俊, 西村愛子, 橋本圭司, 古南博
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-27
    • Related Report
      2008 Final Research Report
  • [Presentation] 可視光応答酸化セリウム光触媒による有機化合物の完全無機化-光触媒-2009

    • Author(s)
      田中淳,橋本圭司,古南博
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-27
    • Related Report
      2008 Final Research Report
  • [Presentation] 懸濁擬固定床光触媒反応器の設計と評価-光触媒-2009

    • Author(s)
      中野尚貴, 岩崎伸一, 橋本圭司, 古南博
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-27
    • Related Report
      2008 Final Research Report
  • [Presentation] Photo-oxidation of NO over PtCl_<6-x>/TiO_2 and RhCl_3/TiO_2 under irradiation of visible light or UV2008

    • Author(s)
      K. Hashimoto, K. Sumida, K. Yamamoto, N. Kondo, Y. Kera, H. Kominami
    • Organizer
      5^<th> European Conference on Solar Chemistry & Photocatalysis : Enviro nme ntal Applications
    • Place of Presentation
      Palermo,Italy
    • Related Report
      2008 Final Research Report
  • [Presentation] Photo-oxidation of nitrogen oxide over titanium (IV) oxide modified with platinum and rhodium chlorides under irradiation of visible light or UV light2008

    • Author(s)
      Keiji Hashimoto
    • Organizer
      Organized Committee of 5^<th> European Conference on Solar Chemistry & Photocatalysis : Environmental Application
    • Place of Presentation
      Palermo (Sicilia) -Italy
    • Related Report
      2008 Annual Research Report
  • [Presentation] LTAゼオライトTiO2ナノコンポジット材料の合成と評価2007

    • Author(s)
      橋本 圭司
    • Organizer
      触媒学会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] 無酸素下におけるアミン類の無機化2007

    • Author(s)
      橋本 圭司
    • Organizer
      触媒学会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] チューブ状マイクロリアクターによる無撹搾連続式ケン化反応2007

    • Author(s)
      橋本 圭司
    • Organizer
      触媒学会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 特許2007

    • Inventor(s)
      橋本 圭可
    • Industrial Property Rights Holder
      学校法人近畿大学
    • Industrial Property Number
      2007-235438
    • Filing Date
      2007-10-03
    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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