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Development of novel synthesis reactions based on radicals

Research Project

Project/Area Number 19590005
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Chemical pharmacy
Research InstitutionHyogo University of Health Sciences

Principal Investigator

MIYABE Hideto  Hyogo University of Health Sciences, 薬学部, 教授 (10289035)

Co-Investigator(Kenkyū-buntansha) KOHTANI Shigeru  兵庫医療大学, 薬学部, 講師 (00242529)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2007: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywordsラジカル / 薬学 / 有機化学 / 合成化学 / 触媒・化学プロセス / ラジカル化学 / 光触媒
Research Abstract

Strategies involving cascade process offer the advantage of multiple carbon-carbon bond formations in a single operation. At first, we developed the radical cascade reaction of substrates having two different radical acceptors. Additionally, cascade reaction involving hydroxylation with molecular oxygen was also developed. Next, several reactions using catalysts were investigated. From the standpoint of sustainable chemistry, these developed catalyst-mediated reactions would be desirable tools for preparing organic compounds.

Report

(5 results)
  • 2009 Annual Research Report   Self-evaluation Report ( PDF )   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (87 results)

All 2009 2008 2007 Other

All Journal Article (44 results) (of which Peer Reviewed: 43 results) Presentation (37 results) Book (1 results) Remarks (5 results)

  • [Journal Article] Enantioselective Radical Cyclization for the Synthesis of Cyclic Compounds2009

    • Author(s)
      Eito Yoshioka, Shigeru Kohtani, Hideto Miyabe
    • Journal Title

      Heterocycles 79(1)

      Pages: 229-242

    • NAID

      40016543056

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Aerobic Hydroxylation of N-Borylenamine : Triethylborane-mediated Hydroxyalkylation of α,β-Unsaturated Oxime Ether2009

    • Author(s)
      Masafumi Ueda, Hideto Miyabe, Takahiro Kimura, Eiko Kondoh, Takeaki Naito, Okiko Miyata
    • Journal Title

      Org, Lett. 11(20)

      Pages: 4632-4635

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Chiral Oxime Ethers Based on Regio- and Enantioselective Allylic Substitution Catalyzed by Iridium-Pybox Complex2009

    • Author(s)
      Hideto Miyabe, Akira Matsumura, Kazumasa Yoshida, Yoshiji Takemoto
    • Journal Title

      Tetrahedron 65(23)

      Pages: 4464-4470

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Carbon Radical Addition to N-Sulfonylimines Mediated by Triethylborane or Zinc2009

    • Author(s)
      Masafumi Ueda, Hideto Miyabe, Okiko Miyata, Takeaki Naito
    • Journal Title

      Tetrahedron 65(7)

      Pages: 1321-1326

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular Carbon Radical Addition to Cyclic Nitrone2009

    • Author(s)
      Masafumi Ueda, Hideto Miyabe, Nami Nonoguchi, Okiko Miyata, Osamu Tamura, Takeaki Naito
    • Journal Title

      Heterocycles 79(1)

      Pages: 739-751

    • NAID

      40016543103

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Synthesis of 4-Substituted 2,6-Dioxopiperidine-3-carbonitrile by Using Thiourea-Catalyzed Asymmetric Michael Addition2009

    • Author(s)
      Tsubasa Inokuma, Yuuki Nagamoto, Shota Sakamoto, Hideto Miyabe, Kiyosei Takasu, Yoshiji Takemoto
    • Journal Title

      Heterocycles 79(1)

      Pages: 565-571

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Palladium or Iridium-Catalyzed Allylic Substitution of Guanidines : Convenient and Direct Modification of Guanidines2009

    • Author(s)
      Hideto Miyabe, Kazumasa Yoshida, Valluru Krishna Reddy, Yoshiji Takemoto
    • Journal Title

      J.Org.Chem. 74(1)

      Pages: 305-311

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Radical Cyclization for the Synthesis of Cyclic Compounds2009

    • Author(s)
      E. Yoshioka, S. Kohtani, H. Miyabe
    • Journal Title

      Heterocycles 79 (1)

      Pages: 229-242

    • NAID

      40016543056

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Aerobic Hydroxylation of N-Borylenamine : Triethylborane-mediated Hydroxyalkylation of α, β-Unsaturated Oxime Ether2009

    • Author(s)
      M. Ueda, H. Miyabe, T. Kimura, E. Kondoh, T. Naito, O. Miyata
    • Journal Title

      Org, Lett. 11 (20)

      Pages: 4632-4635

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Chiral Oxime Ethers Based on Regio- and Enantioselective Allylic Substitution Catalyzed by Iridium-Pybox Complex2009

    • Author(s)
      H. Miyabe, A. Matsumura, K. Yoshida, Y. Takemoto
    • Journal Title

      Tetrahedron 65 (23)

      Pages: 4464-4470

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Carbon Radical Addition to N-Sulfonylimines Mediated by Triethylborane or Zinc2009

    • Author(s)
      M. Ueda, H. Miyabe, O. Miyata, T. Naito
    • Journal Title

      Tetrahedron 65 (7)

      Pages: 1321-1326

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Palladium or Iridium-Catalyzed Allylic Substitution of Guanidines : Convenient and Direct Modification of Guanidines2009

    • Author(s)
      H. Miyabe, K. Yoshida, V. K. Reddy, Y. Takemoto
    • Journal Title

      J. Org. Chem. 74 (1)

      Pages: 305-311

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Radical Cyclization for the Synthesis of Cyclic Compounds2009

    • Author(s)
      E.Yoshioka, S.Kohtani, H.Miyabe
    • Journal Title

      Heterocycles 79

      Pages: 229-242

    • NAID

      40016543056

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aerobic Hydroxylation of N-Borylenamine : Triethylborane-mediated Hydroxyalkylation of α, β-Unsaturated Oxime Ether2009

    • Author(s)
      M.Ueda, H.Miyabe, T.Kimura, E.Kondoh, T.Naito, O.Miyata
    • Journal Title

      Org, Lett. 11

      Pages: 4632-4635

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Chiral Oxime Ethers Based on Regio-and Enantio-selective Allylic Substitution Catalyzed by Iridium-Pybox Complex2009

    • Author(s)
      H.Miyabe, A.Matsumura, K.Yoshida, Y.Takemoto
    • Journal Title

      Tetrahedron 65

      Pages: 4464-4470

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Carbon Radical Addition to N-Sulfonylimines Mediated by Triethylborane or Zinc2009

    • Author(s)
      M.Ueda, H.Miyabe, O.Miyata, T.Naito
    • Journal Title

      Tetrahedron 65

      Pages: 1321-1326

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium or Iridium-Catalyzed Allylic Substitution of Guanidines : Convenient and Direct Modification of Guanidines2009

    • Author(s)
      H.Miyabe, K.Yoshida, V.K.Reddy, Y.Takemoto
    • Journal Title

      J.Org.Chem. 64

      Pages: 305-311

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Loading Effects of Silver Oxides Upon Generation of Reactive Oxygen Species in Semiconductor Photocatalysis2008

    • Author(s)
      Shigeru Kohtani, Kazuhiro Yoshida, Toshiyasu Maekawa, Akihide Iwase, Akihiko Kudo, Hideto Miyabe, Ryoichi Nakagaki
    • Journal Title

      Phys.Chem.Chem.Phys. 10(20)

      Pages: 2986-2992

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] RegioselectiveHydroxysulfenylation of α,β-Unsaturated Imines : Enhanced Stability of an Intermediate Radical2008

    • Author(s)
      Masafumi Ueda, Hideto Miyabe, Hidenori Shimizu, Hisako Sugino, Okiko Miyata, Takeaki Naito
    • Journal Title

      Angew.Chem., Int.Ed 47(30)

      Pages: 5600-5604

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Synthesis of [1,2]-Oxazinone Scaffolds and [1,2]-Oxazine Core Structures of FR9004822008

    • Author(s)
      Valluru Krishna Reddy, Hideto Miyabe, Masashige Yamauchi, Yoshiji Takemoto
    • Journal Title

      Tetrahedron 64(6)

      Pages: 1040-1048

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Discovery and Application of Asymmetric Reaction by Multi-Functional Thioureas2008

    • Author(s)
      Hideto Miyabe, Yoshiji Takemoto
    • Journal Title

      Bull.Chem.Soc.Jpn. 81(7)

      Pages: 785-795

    • NAID

      10021076415

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Loading Effects of Silver Oxides Upon Generation of Reactive Oxygen Species in Semiconductor Photocatalysis2008

    • Author(s)
      S. Kohtani, K. Yoshida, T. Maekawa, A. Iwase, A. Kudo, H. Miyabe, R. Nakagaki
    • Journal Title

      Phys. Chem. Chem. Phys. 10 (20)

      Pages: 2986-2992

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Regioselective Hydroxysulfenylation of α, β-Unsaturated Imines : Enhanced Stability of an Intermediate Radical2008

    • Author(s)
      M. Ueda, H. Miyabe, H. Shimizu, H. Sugino, O. Miyata, T. Naito
    • Journal Title

      Angew. Chem., Int. Ed. 47 (30)

      Pages: 5600-5604

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Discovery and Application of Asymmetric Reaction by Multi-Functional Thioureas.2008

    • Author(s)
      H. Miyabe, Y. Takemoto
    • Journal Title

      Bull. Chem. Soc. Jpn. 81

      Pages: 785-795

    • NAID

      10021076415

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Loading Effects of Silver Oxides Upon Generation of Reactive Oxygen Species in Semiconductor Photocatalysis.2008

    • Author(s)
      S. Kohtani, K. Yoshida, T. Maekawa, A. Iwase, A. Kudo, H. Miyabe, R. Nakasaki.
    • Journal Title

      Phys. Chem. Chem. Phys. 10

      Pages: 2986-2992

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective Hydroxysulfenylation of α, β-Unsaturated Imines : Enhanced Stability of an Intermediate Radical.2008

    • Author(s)
      M. Ueda, H. Miyabe, H. Shimizu, H. Sugino, O. Miyata, T. Naito.
    • Journal Title

      Angew. Chem., Int. Ed. 47

      Pages: 5600-5604

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Synthesis of [1, 2]-Oxazinone Scaffolds and [1, 2]-Oxazine Core Structures of FR9004822008

    • Author(s)
      V. K. Reddy, H. Miyabe, M. Yamauchi, Y. Takemoto.
    • Journal Title

      Tetrahedron 64

      Pages: 1040-1048

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gold-Catalyzed Cyclization Reaction of Alkynyl tert-Butylcarbamates2007

    • Author(s)
      Hideto Miyabe, Yuichi Sami, Takeaki Naito, Yoshiji Takemoto
    • Journal Title

      Heterocycles 73(1)

      Pages: 187-190

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chiral-Thiourea-Catalyzed Direct Mannich Reactions2007

    • Author(s)
      Yousuke Yamaoka, Hideto Miyabe, Yoshizumi Yasui, Yoshiji Takemoto
    • Journal Title

      Synthesis 16

      Pages: 2571-2575

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] One-PotAmidation of Olefins through Pd-Catalyzed Coupling of Alkylboranes and Carbamoyl Chlorides2007

    • Author(s)
      Yoshizumi Yasui, Sayo Tuchida, Hideto Miyabe, Yoshiji Takemoto
    • Journal Title

      J.Org.Chem. 72(15)

      Pages: 5898-5900

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Cascade Radical Addition-Cyclization of Oxime Ethers2007

    • Author(s)
      Hideto Miyabe, Akira Toyoda, Yoshiji Takemoto
    • Journal Title

      Synlett 12

      Pages: 1885-1888

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Enantioselective Petasis-Type Reaction of Quinolines Catalyzed by a Newly Designed Thiourea Catalyst2007

    • Author(s)
      Yousuke Yamaoka, Hideto Miyabe, Yoshiji Takemoto
    • Journal Title

      J.Am.Chem.Soc. 129(21)

      Pages: 6686-6687

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Radical Cyclizations : A New Approach to Stereocontrol of Cascade Reactions2007

    • Author(s)
      Hideto Miyabe, Yoshiji Takemoto,
    • Journal Title

      Chem.Eur.J. 13(26)

      Pages: 7280-7286

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Amino Thiourea-Catalyzed Asymmetric Nucleophilic Reactions.2007

    • Author(s)
      Yoshiji Takemoto, Hideto Miyabe
    • Journal Title

      Chimia 61(5)

      Pages: 269-275

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Cascade Radical Addition-Cyclization of Oxime Ethers2007

    • Author(s)
      H. Miyabe, A. Toyoda, Y. Takemoto
    • Journal Title

      Synlett 12

      Pages: 1885-1888

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Radical Cyclizations : A New Approach to Stereocontrol of Cascade Reactions2007

    • Author(s)
      H. Miyabe, Y. Takemoto
    • Journal Title

      Chem. Eur. J. 13 (26)

      Pages: 7280-7286

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Radical Cyclizations:A New Approach to Stereocontrol of CascadeReactions2007

    • Author(s)
      H. Miyabe, Y. Takemoto.
    • Journal Title

      Chem.Eur.J. 13

      Pages: 7280-7286

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Amino Thiourea-Catalyzed Asymmetric Nucleophilic Reactions2007

    • Author(s)
      Y. Takemoto, H. Miyabe.
    • Journal Title

      Chimia 61

      Pages: 269-275

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gold-Catalyzed Cyclization Reaction of Alkynyl tert-Butylcarbamates2007

    • Author(s)
      H. Miyabe, Y. Sami, T. Naito, Y. Takemoto.
    • Journal Title

      Heterocycles 73

      Pages: 187-190

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Thiourea-catalyzed Direct Mannich Reactions2007

    • Author(s)
      Y. Yamaoka, H. Miyabe, Y. Yasui, Y. Takemoto.
    • Journal Title

      Synthesis

      Pages: 2571-2575

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-Pot Amidation of Olefins through Pd-Catalyzed Coupling of Alkylboranes and Carbamoyl Chlorides2007

    • Author(s)
      Y. Yasui, S. Tuchida, H. Miyabe, Y. Takemoto.
    • Journal Title

      J.Org.Chem. 72

      Pages: 5898-5900

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Cascade Radical Addition-Cyclization of Oxime Ethers2007

    • Author(s)
      H. Miyabe, A. Toyoda, Y. Takemoto.
    • Journal Title

      Synlett

      Pages: 1885-1888

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Enantioselective Petasis-type Reaction of Quinolines Catalyzed by a NewlyDesigned Thiourea Catalyst2007

    • Author(s)
      Y. Yamaoka, H. Miyabe, Y. Takemoto.
    • Journal Title

      J.Am.Chem.Soc. 129

      Pages: 6686-6687

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Enantioselective Petasis-Type Reaction:Design for Bifunctional Organocatalyst2007

    • Author(s)
      Y. Takemoto, H. Miyabe.
    • Journal Title

      SYNFORM

    • Related Report
      2007 Annual Research Report
  • [Presentation] ベンザインからのo-二置換ベンゼン類の合成2009

    • Author(s)
      吉岡英斗、甲谷繁、宮部豪人
    • Organizer
      第35回反応と合成の進歩シンポジウム
    • Place of Presentation
      金沢市文化ホール(金沢市)
    • Year and Date
      2009-11-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] アルキニルオキシムエーテル類の銀触媒閉環反応によるイソキサゾール合成2009

    • Author(s)
      上田昌史、佐藤あおい、宮部豪人、内藤猛章、宮田興子
    • Organizer
      第59回日本薬学会近畿支部総会大会
    • Place of Presentation
      東大阪
    • Year and Date
      2009-10-24
    • Related Report
      2009 Final Research Report
  • [Presentation] 酸化チタンによる芳香族ケトン類の光触媒的還元反応(第二報)2009

    • Author(s)
      甲谷繁、吉岡英斗、宮部豪人
    • Organizer
      第59回日本薬学会近畿支部総会大会
    • Place of Presentation
      東大阪
    • Year and Date
      2009-10-24
    • Related Report
      2009 Final Research Report
  • [Presentation] Enantioselective Cascade Radical Iodoperfluoroalkylation Reactions2009

    • Author(s)
      Eito Yoshioka, Kentefu, Shigeru Kohtani, Hideto Miyabe
    • Organizer
      第59回日本薬学会近畿支部総会大会
    • Place of Presentation
      東大阪
    • Year and Date
      2009-10-24
    • Related Report
      2009 Final Research Report
  • [Presentation] ベンザインを利用したベンゾオキセテン類の形成とo-二置換ベンゼン類への変換2009

    • Author(s)
      吉岡英斗、甲谷繁、宮部豪人
    • Organizer
      第59回日本薬学会近畿支部総会大会
    • Place of Presentation
      東大阪
    • Year and Date
      2009-10-24
    • Related Report
      2009 Final Research Report
  • [Presentation] 酸化チタンによる芳香族ケトン類の光触媒的還元反応 (第二報)2009

    • Author(s)
      甲谷繁, 吉岡英斗, 宮部豪人
    • Organizer
      第59回日本薬学会近畿支部総会大会
    • Place of Presentation
      近畿大学 東大阪
    • Year and Date
      2009-10-24
    • Related Report
      2009 Self-evaluation Report
  • [Presentation] Enantioselective Cascade Radical Iodoperfluoroalkylation Reactions2009

    • Author(s)
      E. Yoshioka, Kentefu, S. Kohtani, H. Miyabe
    • Organizer
      第59回日本薬学会近畿支部総会大会
    • Place of Presentation
      近畿大学 東大阪
    • Year and Date
      2009-10-24
    • Related Report
      2009 Self-evaluation Report
  • [Presentation] アルキニルオキシムエーテル類の銀触媒閉環反応によるイソキサゾール合成2009

    • Author(s)
      上田昌史、佐藤あおい、宮部豪人、内藤猛章、宮田興子
    • Organizer
      第59回日本薬学会近畿支部総会大会
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      2009-10-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] 酸化チタンによる芳香族ケトン類の光触媒的還元反応(第二報)2009

    • Author(s)
      甲谷繁、吉岡英斗、宮部豪人
    • Organizer
      第59回日本薬学会近畿支部総会大会
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      2009-10-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] Enantioselective Cascade Radical Iodoperfluoroalkylation Reactions2009

    • Author(s)
      E.Yoshioka, Kentefu, S.Kohtani, H.Miyabe
    • Organizer
      第59回日本薬学会近畿支部総会大会
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      2009-10-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] ベンザインを利用したベンゾオキセテン類の形成とo-二置換ベンゼン類への変換2009

    • Author(s)
      吉岡英斗、甲谷繁、宮部豪人
    • Organizer
      第59回日本薬学会近畿支部総会大会
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      2009-10-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] 酸化チタンによる芳香族ケトンからアルコールへの高効率還元反応2009

    • Author(s)
      甲谷繁、吉岡英斗、宮部豪人
    • Organizer
      2009年光化学討論会
    • Place of Presentation
      桐生市民文化会館(桐生市)
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] ベンザインを利用したベンゾオキセテン類の形成と反応2009

    • Author(s)
      吉岡英斗, 甲谷繁, 宮部豪人
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] 酸化チタンによる芳香族ケトン類の光触媒的還元反応(第一報)2009

    • Author(s)
      甲谷繁, 吉岡英斗, 宮部豪人
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] アルキニルオキシムエーテル類への位置および立体選択的共役付加反応2009

    • Author(s)
      上田昌史, 赤羽昌明, 香川真理子, 宮田興子, 内藤猛章, 宮部豪人, 松原浩
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2009-03-26
    • Related Report
      2008 Annual Research Report
  • [Presentation] ベンザインからのo-二置換ベンゼン類の合成2009

    • Author(s)
      吉岡英斗、甲谷繁、宮部豪人
    • Organizer
      第35回反応と合成の進歩シンポジウム
    • Place of Presentation
      金沢
    • Related Report
      2009 Final Research Report
  • [Presentation] 酸化チタンによる芳香族ケトンからアルコールへの高効率還元反応2009

    • Author(s)
      甲谷繁、吉岡英斗、宮部豪人
    • Organizer
      2009年光化学討論会
    • Place of Presentation
      桐生
    • Related Report
      2009 Final Research Report
  • [Presentation] ベンザインを利用したベンゾオキセテン類の形成と反応2009

    • Author(s)
      吉岡英斗、甲谷繁、宮部豪人
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      京都
    • Related Report
      2009 Final Research Report
  • [Presentation] 酸化チタンによる芳香族ケトン類の光触媒的還元反応(第一報)2009

    • Author(s)
      甲谷繁、吉岡英斗、宮部豪人
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      京都
    • Related Report
      2009 Final Research Report
  • [Presentation] アルキニルオキシムエーテル類への位置および立体選択的共役付加反応2009

    • Author(s)
      上田昌史、赤羽昌明、香川真理子、宮田興子、内藤猛章、宮部豪人、松原浩
    • Organizer
      日本薬学会第129年会
    • Place of Presentation
      京都
    • Related Report
      2009 Final Research Report
  • [Presentation] ベンザインからのo-二置換ベンゼン類の合成2009

    • Author(s)
      吉岡英斗, 甲谷繁, 宮部豪人
    • Organizer
      第35回反応と合成の進歩シンポジウム
    • Place of Presentation
      金沢市文化ホール(金沢)
    • Related Report
      2009 Self-evaluation Report
  • [Presentation] 酸化チタンによる芳香族ケトンからアルコールへの高効率還元反応2009

    • Author(s)
      甲谷繁, 吉岡英斗, 宮部豪人
    • Organizer
      2009年光化学討論会
    • Place of Presentation
      桐生市民文化会館 桐生
    • Related Report
      2009 Self-evaluation Report
  • [Presentation] 新規な可視光応答型光触媒の化学的特性2008

    • Author(s)
      甲谷繁、吉岡英斗、工藤昭彦、宮部豪人
    • Organizer
      日本防菌防黴学会2008年度若手の会
    • Place of Presentation
      神戸
    • Year and Date
      2008-11-29
    • Related Report
      2009 Final Research Report
  • [Presentation] 新規な可視光応答型光触媒の化学的特性2008

    • Author(s)
      甲谷繁, 吉岡英斗, 工藤昭彦, 宮部豪人
    • Organizer
      日本防菌防黴学会2008年度若手の会
    • Place of Presentation
      神戸兵庫医療大学
    • Year and Date
      2008-11-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] アルキニルオキシムエーテル類への位置特異的共役付加反応の開発2008

    • Author(s)
      上田昌史, 吉田勤一, 池田祐紀, 宮田興子, 内藤猛章, 宮部豪人
    • Organizer
      第34回反応と合成の進歩シンポジウム
    • Place of Presentation
      京都テルサ
    • Year and Date
      2008-11-04
    • Related Report
      2008 Annual Research Report
  • [Presentation] 共役オキシムエーテル類への位置選択的ラジカル付加反応:水酸基導入反応への展開2008

    • Author(s)
      上田昌史、木村隆浩、宮田興子、内藤猛章、宮部豪人
    • Organizer
      第58回日本薬学会近畿支部総会大会
    • Place of Presentation
      神戸
    • Year and Date
      2008-10-25
    • Related Report
      2009 Final Research Report
  • [Presentation] 共役オキシムエーテル類への位置選択的ラジカル付加反応 : 水酸基導入反応への展開2008

    • Author(s)
      上田昌史, 木村隆浩, 宮田興子, 内藤猛章, 宮部豪人
    • Organizer
      第58回日本薬学会近畿支部総会大会
    • Place of Presentation
      神戸薬科大学 神戸
    • Year and Date
      2008-10-25
    • Related Report
      2009 Self-evaluation Report
  • [Presentation] 共役オキシムエーテル類への位置選択的ラジカル付加反応 : 水酸基導入反応への展開2008

    • Author(s)
      上田昌史, 木村隆浩, 宮田興子, 内藤猛章, 宮部豪人
    • Organizer
      第58回日本薬学会近畿支部総会大会
    • Place of Presentation
      神戸薬科大学
    • Year and Date
      2008-10-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] N-アルコキシイミドイルブロミド類のクロスカップリング反応の開発とイソキサゾール合成への応用2008

    • Author(s)
      上田昌史, 池田祐紀, 宮田興子, 内藤猛章, 宮部豪人
    • Organizer
      第58回日本薬学会近畿支部総会大会
    • Place of Presentation
      神戸薬科大学
    • Year and Date
      2008-10-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] 炭素ラジカル付加反応を用いたPenmacric acid類の全合成2008

    • Author(s)
      上田昌史、宮部豪人、中尾大、小野彩子、宮田興子、内藤猛章
    • Organizer
      第38回複素環化学討論会
    • Place of Presentation
      福山
    • Related Report
      2009 Final Research Report
  • [Presentation] 光触媒からの活性酸素発生に対する酸化銀種の担持効果2008

    • Author(s)
      甲谷繁、吉田宗弘、前川敏康、岩瀬顕秀、工藤昭彦、宮部豪人、中谷良
    • Organizer
      日本薬学会第128年会
    • Place of Presentation
      横浜
    • Related Report
      2009 Final Research Report 2007 Annual Research Report
  • [Presentation] 共役イミン類への求電子的な炭素ラジカル付加反応の開発研究2008

    • Author(s)
      上田昌史、岩定絵里、宮田興子、内藤猛章、宮部豪人
    • Organizer
      日本薬学会第128年会
    • Place of Presentation
      横浜
    • Related Report
      2009 Final Research Report 2007 Annual Research Report
  • [Presentation] 共役オキシムエーテル類のヒドロキシアルキル化反応2008

    • Author(s)
      上田 昌史、木村 隆浩、宮田 興子、内藤 猛章、宮部 豪人
    • Organizer
      日本薬学会第128年会
    • Place of Presentation
      横浜
    • Related Report
      2007 Annual Research Report
  • [Presentation] Penmacric acid類の合成研究2008

    • Author(s)
      上田 昌史、中尾 大、小野 彩子、宮田 興子、内藤 猛章、宮部 豪人
    • Organizer
      日本薬学会第128年会
    • Place of Presentation
      横浜
    • Related Report
      2007 Annual Research Report
  • [Presentation] 多機能性チオウレア触媒を用いたキノリン類の不斉ペタシスボロン酸-マンニッヒ反応2007

    • Author(s)
      山岡庸介、宮部豪人、竹本佳司
    • Organizer
      第27回有機合成若手セミナー
    • Place of Presentation
      京都
    • Year and Date
      2007-11-15
    • Related Report
      2009 Final Research Report 2007 Annual Research Report
  • [Presentation] イミン類のα位炭素ラジカルの化学:共役イミン類のHydroxysulfenylation反応2007

    • Author(s)
      上田昌史、清水秀憲、宮田興子、内藤猛章、宮部豪人
    • Organizer
      第57回日本薬学会近畿支部総会大会
    • Place of Presentation
      高槻
    • Year and Date
      2007-10-27
    • Related Report
      2009 Final Research Report 2007 Annual Research Report
  • [Presentation] イミン類のα位炭素ラジカルの化学 : 共役イミン類の Hydroxysulfenylation 反応2007

    • Author(s)
      上田昌史, 清水秀憲, 宮田興子, 内藤猛章, 宮部豪人
    • Organizer
      第57回日本薬学会近畿支部総会大会
    • Place of Presentation
      大阪薬科大学 高槻
    • Year and Date
      2007-10-27
    • Related Report
      2009 Self-evaluation Report
  • [Book] Methyl, Ethyl, and tert-Buty1-2-[(diphenylmethylene)amino]-2-propenate in e-EROS(Electronic Encyclopedia of Reagents for Organic Synthesis)2007

    • Author(s)
      H. Miyabe
    • Total Pages
      2
    • Publisher
      John Wiley&Sons:UK
    • Related Report
      2007 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://www2.huhs.ac.jp/~h070012h/

    • Related Report
      2009 Final Research Report
  • [Remarks] ホームページ

    • URL

      http://www2.huhs.ac.jp/~h070012h/

    • Related Report
      2009 Self-evaluation Report
  • [Remarks]

    • URL

      http://www2.huhs.ac.jp/~h070012h/

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www2.huhs.ac.jp/~h070012h/

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.huhs.ac.jp/pharm/staff/yakustaff/miyabe.pdf

    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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