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Development of high corrosion resistant and wear resistant Ti-Zr alloys for bone substitution

Research Project

Project/Area Number 19592250
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 補綴理工系歯学
Research InstitutionNagasaki University

Principal Investigator

SHIRAISHI Takanobu  Nagasaki University, 大学院・医歯薬学総合研究科, 准教授 (10150468)

Co-Investigator(Kenkyū-buntansha) SHISHIDO Toetsu  東北大学, 金属材料研究所, 准教授 (50125580)
FUJITA Takeshi  長崎大学, 大学院・医歯薬学総合研究科, 助教 (90432971)
TAKUMA Yasuko  長崎大学, 大学院・医歯薬学総合研究科, 教務職員 (60160074)
HISATSUNE Kunihiro  長崎大学, 大学院・医歯薬学総合研究科, 教授 (20037526)
MIURA Eri  長崎大学, 大学院・医歯薬学総合研究科, 助教 (70315258)
Co-Investigator(Renkei-kenkyūsha) SHINOZAKI Nobuya  九州工業大学, 大学院・工学研究科, 准教授 (00136524)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2009: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2008: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2007: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywords生体材料 / チタン合金 / ジルコニウム / ハフニウム / ヤング率 / 耐食性 / 硬さ / 結晶構造 / X線回折 / ポアソン比 / ビッカース硬さ / ボアソン比 / 超音波伝播速度
Research Abstract

The objectives of the current study were to develop a new titanium alloy with low Young's modulus, high corrosion and wear resistances. Zirconium and hafnium which form a continuous solid solution with titanium were chosen as an alloying element. A Ti-60 at.% Zr alloy showed the lowest Young's modulus of 89.5 GPa within all the Ti-Zr and Ti-Hf alloys examined. The addition of Zr and Hf remarkably increased Vickers hardness number, showing marked increases of mechanical strength. This suggests that the wear resistance of the Ti-Zr and Ti-Hf alloys is greatly improved compared to that of pure Ti. The linear sweep voltammetry of all the prepared Ti-Zr and Ti-Hf alloys in a deaerated 0.9% NaCl aqueous solution at 37℃ suggested that additive elements (Zr, Hf) should be restricted up to about 50 at.% for use in a human body.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (34 results)

All 2010 2009 2008 2007 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (22 results) Remarks (4 results)

  • [Journal Article] Optical Properties and microstructures of Pd-free Ag-Au-Pt-Cu dental alloys2009

    • Author(s)
      T.Shiraishi, et al.
    • Journal Title

      Journal of Materials Science 44

      Pages: 2796-2804

    • NAID

      120006983777

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of specular component on color differences of different filler typeresin composites after aging2009

    • Author(s)
      Y.Hosoya, et al.
    • Journal Title

      Journal of Dentistry 37

      Pages: 585-590

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of indium addition to CuAu alloy on phase transformation behaviors2009

    • Author(s)
      K.Hisatsune, et al.
    • Journal Title

      Gold Bulletin 42

      Pages: 190-194

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Effect of Magnesium Oxide Supplementation to Aluminum Oxide Slip on the Jointing of Aluminum Oxide Bars2008

    • Author(s)
      T. Odatsu, et al.
    • Journal Title

      Dental Materials Journal 27

      Pages: 251-257

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spectral reflectance and color of dent in ceramics for all-ceramic restorations2008

    • Author(s)
      D. J. Wood, et al.
    • Journal Title

      Dental Materials 24

      Pages: 1661-1669

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two different types of age-hardening behaviors in commerical dental gold alloys2007

    • Author(s)
      K.Hisatsune, et. al.
    • Journal Title

      Journal of Materials Science: Materials in Medicine 18

      Pages: 577-581

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Variations of color with alloying elements in Pd-free Au-Pt-based high noble dental alloys2007

    • Author(s)
      T.Shiraishi, et. al.
    • Journal Title

      Materials Science and Engineering B 140

      Pages: 147-152

    • NAID

      120006984272

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical Property and Corrosion Resistance Evaluations of Ti-6Al-7Nb Alloy Brazed with Bulk Metallic Glasses2007

    • Author(s)
      E.Miura, et. al.
    • Journal Title

      Materials Transsactions 48

      Pages: 2235-2243

    • NAID

      10019517920

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Tiの弾性率と耐食性に及ぼすHf添加の効果2010

    • Author(s)
      白石孝信, 宍戸統悦, 篠崎信也, 藤田剛史
    • Organizer
      第55回日本歯科理工学会学術講演会
    • Place of Presentation
      東京
    • Related Report
      2009 Final Research Report
  • [Presentation] 動電位分極実験ならびに組織観察によるパラジウム無添加歯科用貴金属合金の耐食性評価2009

    • Author(s)
      藤田剛史, ほか
    • Organizer
      第54回日本歯科理工学会学術講演会
    • Place of Presentation
      鹿児島
    • Year and Date
      2009-10-01
    • Related Report
      2009 Annual Research Report
  • [Presentation] Ag-Au-Pt-Cu系4元合金のリニアスィープボルタンメトリーと光学顕微鏡組織観察2009

    • Author(s)
      藤田剛史, ほか
    • Organizer
      平成21年度日本歯科理工学会九州支部夏期セミナー
    • Place of Presentation
      柳川
    • Year and Date
      2009-08-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] 研磨粗さがエステライトΣクイックの色彩と光沢に及ぼす影響2009

    • Author(s)
      細矢由美子, ほか
    • Organizer
      第53回日本歯科理工学会学術講演会
    • Place of Presentation
      東京
    • Year and Date
      2009-04-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] 弾性率の低い生体硬組織代替用チタン合金の開発2009

    • Author(s)
      白石孝信, 宍戸統悦, 篠崎信也, 藤田剛史, 久恒邦博
    • Organizer
      第31回日本バイオマテリアル学会大会
    • Place of Presentation
      京都
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Effects of Specular Component Mode on Color of Resin Composites2009

    • Author(s)
      Y.Hosoya, et al.
    • Organizer
      2009 Meeting for the Society for Color and Appearance in Dentistry
    • Place of Presentation
      Houston(TX), USA
    • Related Report
      2009 Annual Research Report
  • [Presentation] 微分パルスボルタンメトリーによる歯科用貴金属合金の耐食性評価2008

    • Author(s)
      藤田剛史, ほか
    • Organizer
      第52回日本歯科理工学会学術講演会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] PEMA, およびMMA, EGDMAを成分とする常温重合型硬質リライン材の硬化挙動および機械的性質に及ぼす成分, 粉液比の影響2008

    • Author(s)
      奥山義和, ほか
    • Organizer
      平成20年度日本歯科理工学会九州支部夏期セミナー
    • Place of Presentation
      福津(福岡県)
    • Year and Date
      2008-08-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] 異なる測色モードで比較した光重合型コンポジットレジンの経時的色彩特性2008

    • Author(s)
      細矢由美子, ほか
    • Organizer
      平成20年度第128回日本歯科保存学会春季学術大会
    • Place of Presentation
      新潟
    • Year and Date
      2008-06-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] 分光測色法による歯科用合金の耐変色性の検討2008

    • Author(s)
      詫間康子, ほか
    • Organizer
      第51回日本歯科理工学会学術講演会
    • Place of Presentation
      鶴見
    • Year and Date
      2008-04-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] 超音波パルス法による生体用Ti-Zr合金の弾性率測定2008

    • Author(s)
      白石孝信, 宍戸統悦, 篠崎信也, 久恒邦博
    • Organizer
      第52回日本歯科理工学会学術講演会
    • Place of Presentation
      大阪
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] Cell Activity on and Ion Release from Metal-Ceramic Alloys2008

    • Author(s)
      A. Johnson, et al.
    • Organizer
      Pan European Federat ion of the International Association for Dental Research
    • Place of Presentation
      London (UK)
    • Related Report
      2008 Annual Research Report
  • [Presentation] Spectral Transmittance and Colour of Base Dentine Ceramics for Al1-Ceramic Restorations2008

    • Author(s)
      D. J. Wood, et al.
    • Organizer
      Academy of Dental Materials Annual Meeting 2008
    • Place of Presentation
      Wurzburg (Germany)
    • Related Report
      2008 Annual Research Report
  • [Presentation] Effect of Immersion in Hank's Solution on Bending Stress of Ti-6Al-7Nb Brazed with Pd-based BMG Filler2008

    • Author(s)
      E. Miura-Fujiwara, et al.
    • Organizer
      The IUMRS International Conference in Asia 2008
    • Place of Presentation
      Nagoya
    • Related Report
      2008 Annual Research Report
  • [Presentation] Color Analysis of Oxidized Pd-free Au-Pt-based High Noble Dental Alloys for Porcelain Veneering2007

    • Author(s)
      T.Shiraishi, et. al.
    • Organizer
      International Dental Materials Congress 2007
    • Place of Presentation
      Bangkok,Thailand
    • Year and Date
      2007-11-24
    • Related Report
      2007 Annual Research Report
  • [Presentation] Cyclic Voltammetry of Experimental Pd-free Low-gold Dental Alloys2007

    • Author(s)
      T.Fujita, et. al.
    • Organizer
      International Dental Materials Congress 2007
    • Place of Presentation
      Bangkok,Thailand
    • Year and Date
      2007-11-24
    • Related Report
      2007 Annual Research Report
  • [Presentation] Bending Strength in Hunk's Solution of Ti-based Alloy Joint Brazed by Pd-based Bulk Metallic Glass2007

    • Author(s)
      E.Miura, et. al.
    • Organizer
      International Dental Materials Congress 2007
    • Place of Presentation
      Bangkok,Thailand
    • Year and Date
      2007-11-24
    • Related Report
      2007 Annual Research Report
  • [Presentation] 金属アレルギー患者用矯正ワイヤーの開発2007

    • Author(s)
      北浦 英樹, ほか
    • Organizer
      第66回日本矯正歯科学会大会
    • Place of Presentation
      大阪
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] 光重合型コンポジットレジンの色彩学的特性2007

    • Author(s)
      細矢 由美子, ほか
    • Organizer
      平成19年度第126回日本歯科保存学会春季学術大会
    • Place of Presentation
      大宮
    • Year and Date
      2007-06-08
    • Related Report
      2007 Annual Research Report
  • [Presentation] ガラス浸透アルミナセラミックス用連結材の開発-第2報-破壊靭性試験,線収縮率計測2007

    • Author(s)
      尾立 哲郎, ほか
    • Organizer
      日本補綴歯科学会第116回学術大会
    • Place of Presentation
      神戸
    • Year and Date
      2007-05-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] 赤外線ろう接によるTi-6Al-7Nb/Pd40Cu30Ni10P20金属ガラス接合界面の透過電子顕微鏡観察2007

    • Author(s)
      三浦 永理, ほか
    • Organizer
      第49回日本歯科理工学会学術講演会
    • Place of Presentation
      札幌
    • Year and Date
      2007-05-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] 歯科用金-白金系合金の彩度と色相に及ぼす添加元素の影響2007

    • Author(s)
      白石 孝信, ほか
    • Organizer
      第49回日本歯科理工学会学術講演会
    • Place of Presentation
      札幌
    • Year and Date
      2007-05-12
    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://www.de.nagasaki-u.ac.jp

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://www.mdp.nagasaki-u.ac.jp/

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.mdp.nagasaki-u.ac.jp/

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.mdp.nagasaki-u.ac.jp/

    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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