Development of Binder-Free Carbon Nanotube Fibers Designed with High Strength and Electric Conductivity

• Project/Area Number: 19686038
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Inorganic materials/Physical properties
• Research Institution: Tohoku University
• Principal Investigator: SATO Yoshinori Tohoku University, 大学院環境科学研究科, 助教 (30374995)
• Research Collaborator: MAURICIO Terrones IPICyT (Mexico), Advanced Materials Department, Professor ; 橋口 慎二 ステラケミファ株式会社, 主任研究員
• Project Period (FY): 2007 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000); Fiscal Year 2008: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2007: ¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000)
• Keywords: カーボンナノチューブ / カーボン材料 / バインダーフリー / 繊維 / 固化体 / 高強度 / 高弾性 / 高導電率

Research Abstract

放電プラズマ焼結法による温度(1000℃)・圧力(80MPa)の条件下で、フッ素で修飾された多層カーボンナノチューブ(MWCNTs)を焼結し、脱フッ素により活性化した「炭素」を持つナノチューブ同士を結合させることにより、MWCNT固化体の作製を行った。その物性は3点曲げ強度125MPa、ヤング率15GPa(市販のグラファイトの4倍)、電気導電率2.1×102 S/cmであり、脱フッ素による炭素同士の結合が、高強度のMWCNT集合体を作製することに有効であることを世界ではじめて明らかにした。

Research Products

• [Journal Article] Characterization of Silver Nanoparticle-Decorated Single-Walled Carbon Nanotube Films (2009)
  • Author(s): M. Namura, *Y. Sato, Naoki Sashida, Shin-ichi Ogino, Kenichi Motomiya, Balachandran Jeyadevan, and Kazuyuki Tohji
  • Journal Title: Fullerenes, Nanotubes, and Carbon Nanostructures (in press)
  • Peer Reviewed
• [Journal Article] Preparation and characterization of lanthanum carbide encapsulated carbon nanocapsule / lanthanum hexaboride nanocomposites (2009)
  • Author(s): M. Namura, I. Waki, *Y. Sato, G. Yamamoto, A. Okubo, H. Kimura, N. Osaka, K. Motomiya, T. Hashida, B. Jeyadevan, K. Tohji
  • Journal Title: Materials Letters 63 Pages: 1307-1310
  • Peer Reviewed
• [Journal Article] カーボンナノチューブ-バイオインターフェース (2009)
  • Author(s): *佐藤義倫、田路和幸、湯田坂雅子
  • Journal Title: 表面科学 30 Pages: 202-206
  • Peer Reviewed
• [Journal Article] Preparation and characterization of lanthanum carbide encapsulated carbon nanocapsule / lanthanum hexaboride nanocomnosites (2009)
  • Author(s): M. Namura, I. Waki, Y. Sato, et.al.
  • Journal Title: Materials Letters 63 Pages: 1307-1310
  • Peer Reviewed
• [Journal Article] カーボンナノチューブ-バイオインターフェース (2009)
  • Author(s): 佐藤義倫、田路和幸、湯田坂雅子
  • Journal Title: 表面化学 30 Pages: 202-206
  • Peer Reviewed
• [Journal Article] Characterization of Silver NanoparticleDecorated SingleWalled Carbon Nanotube Films (2009)
  • Author(s): M. Namura, Y. Sato, et.al.
  • Journal Title: Fullerenes, Nanotubes, and Carbon Nanostructures 17(印刷中)
  • Peer Reviewed
• [Journal Article] In vivo rat subcutaneous tissue response of binder-free multi-walled carbon nanotube blocks cross-linked by de-fluorination (2008)
  • Author(s): *Y. Sato, A. Yokoyama, T. Kasai, S. Hashiguchi, M. Ootsubo, S. Ogino, N. Sashida, M. Namura, K. Motomiya, B. Jeyadevan, K. Tohji
  • Journal Title: Carbon 46 Pages: 1927-1934
  • Peer Reviewed
• [Journal Article] Reinforcement of rubber using radial single-walled carbon nanotube soot and its shock dampening properties (2008)
  • Author(s): *Y. Sato, K. Hasegawa, Y. Nodasaka, K. Motomiya, M. Namura, N. Ito, B. Jeyadevan, K. Tohji
  • Journal Title: Carbon 46 Pages: 1509-1512
  • Peer Reviewed
• [Journal Article] Super-Robust, Lightweight, Conducting Carbon Nanotube Blocks Cross-Linked by De-fluorination (2008)
  • Author(s): *Y. Sato, M. Ootsubo, G. Yamamoto, G. Van Lier, M. Terrones, S. Hashiguchi, H. Kimura, A. Okubo, K. Motomiya, B. Jeyadevan, T. Hashida, K. Tohji
  • Journal Title: ACS Nano 2 Pages: 348-356
  • Peer Reviewed
• [Journal Article] In vivo rat subcutaneous tissue response of binder-free multiwalled carbon nanotube blocks crosslinked by defluorination (2008)
  • Author(s): Yoshinori Sato, et.al.
  • Journal Title: Carbon 46 Pages: 1927-1934
  • Peer Reviewed
• [Journal Article] Reinforcement of rubber using radial singlewalled carbon nanotube soot and its sshock dampening properties (2008)
  • Author(s): Yoshinori Sato, et.al.
  • Journal Title: Carbon 46 Pages: 1509-1512
  • Peer Reviewed
• [Journal Article] Super-Robust, Lightweight, Conducting Carbon Nanotube Blocks Cross-Linked by De-Fluorination (2008)
  • Author(s): Yoshinori Sato, et. al.
  • Journal Title: ACS Nano 2 Pages: 348-356
  • Peer Reviewed
• [Journal Article] Novel method to evaluate the carbon network of single-walled carbon nanotubes by hydrogen physisorption (2007)
  • Author(s): S. Iwata, *Y. Sato, K. Nakai, S. Ogura, T. Okano, M. Namura, A. Kasuya, K. Tohji, K. Fukutani
  • Journal Title: Journal of Physical Chemistry C 111 Pages: 14937-14941
  • Peer Reviewed
• [Journal Article] Novel method to evaluate the carbon network of single-walled carbon nanotubes by hydrogen physisorption (2007)
  • Author(s): Shinya Iwata, et. al.
  • Journal Title: The Journal of Physical Chemistry C 111 Pages: 14937-14941
  • Peer Reviewed
• [Presentation] Binder-free Carbon Nanotube Blocks Cross-Linked by De-fluorination (2008)
  • Author(s): Y. Sato, G. Yamamoto, G. Van Lier, M. Terrones, S. Hashiguchi, A. Okubo, K. Motomiya, B. Jeyadevan, T. Hashida, K. Tohji
  • Organizer: The 10th International Symposium on Multiscale, Multifunctional and Functionally Graded Materials, Book of Abstract P53
  • Place of Presentation: Sendai, Japan
  • Year and Date: 2008-09-23
• [Presentation] Binder-free Carbon Nanotube Blocks CrossLinked by Defluorination (2008)
  • Author(s): Yoshinori Sato
  • Organizer: The 10th Intetnational Symposium on Multiscale, Multifunctional and Functionally Graded Materials
  • Place of Presentation: Sendai, Japan
  • Year and Date: 2008-09-23
• [Presentation] in vivoによるラット軟組織に対する脱フッ素化法による多層カーボンナノチューブブロックの組織反応 (2008)
  • Author(s): 佐藤義倫、横山敦郎、笠井孝夫、橋口慎二、本宮憲一、B. ジャヤデワン、田路和幸
  • Organizer: 第35回フラーレン・ナノチューブ総合シンポジウム講演要旨集、P204
  • Place of Presentation: 東京都、目黒区
  • Year and Date: 2008-08-29
• [Presentation] in vivoによるラット軟組織に対する脱フッ素化法による多層カーボンナノチューブブロックの組織反応 (2008)
  • Author(s): Yoshinori Sato
  • Organizer: 第35回フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 東京都、目黒区
  • Year and Date: 2008-08-29
• [Presentation] Robust, Lightweight, Conducting Multi-Walled Carbon Nanotube Blocks Cross-Linked by De-fluorination (2008)
  • Author(s): Y. Sato, M. Ootsubo, G. Yamamoto, G. Van Lier, M. Terrones, S. Hashiguchi, H. Kimura, A. Okubo, K. Motomiya, B. Jeyadevan, T. Hashida, K. Tohji
  • Organizer: NT08 : 9th International Conference on the Science and Application of Nanotubes, Abstract P445
  • Place of Presentation: Montpellier, France
  • Year and Date: 2008-07-04
• [Presentation] Robust, Lightweight, Conducting MultiWalled Carbon Nanotube Blocks Cross-Linked by Defluorination (2008)
  • Author(s): Yoshinori Sato
  • Organizer: NT08 : 9th International Conference on the Science and Application of Nanotubes
  • Place of Presentation: Montpellier, France
  • Year and Date: 2008-07-04
• [Presentation] Tissue response of multi-walled carbon nanotube blocks cross-linked by de-fluorination against subcutaneous tissue of rats in vivo (2008)
  • Author(s): Y. Sato, A. Yokoyama, T. Kasai, S. Hashiguchi, B. Jeyadevan, K. Tohji
  • Organizer: CNBMT08 Satellite Symposium : 1st Carbon Nanotube Biology, Medicine & Toxicology, Abstract P11
  • Place of Presentation: Montpellier, France
  • Year and Date: 2008-06-28
• [Presentation] Tissue response of multiwalled carbon nanotube blocks crosslinked by de-fluorin ation against subcutaneous tissue of rats in vivo (2008)
  • Author(s): Yoshinori Sato
  • Organizer: 1st Carbon Nanotube Biology, Medicine & Toxicology
  • Place of Presentation: Montpellier, France
  • Year and Date: 2008-06-28
• [Presentation] Multi-walled carbon nanotube blocks cross-linked by de-fluorination (2008)
  • Author(s): Y. Sato, N. Sashida, M. Namura, S. Hashiguchi, K. Motomiya, B. Jeyadevan, K. Tohji
  • Organizer: International Symposium on Nanotoxicology Assessment and Biomediacal, Environmental Application of Fine Particles and Nanotubes (ISNT2008), Abstract P71
  • Place of Presentation: Sapporo, Japan
  • Year and Date: 2008-06-16
• [Presentation] Biocompatibility of binder-free multi-walled carbon nanotube blocks cross-linked by de-fluorination against subcutaneous tissue of rats in vivo (2008)
  • Author(s): Y. Sato, A. Yokoyama, T. Kasai, S. Ogino, N. Sashida, S. Hashiguchi, B. Jeyadevan, K. Tohji
  • Organizer: International Symposium on Nanotoxicology Assessment and Biomediacal, Environmental Application of Fine Particles and Nanotubes (ISNT2008), Abstract P33
  • Place of Presentation: Sapporo, Japan
  • Year and Date: 2008-06-16
• [Presentation] Biocompatibility of binder-free multiwalled carbon nanotube blocks crosslinked by defluorination against subcutaneous tissue of rats in vivo (2008)
  • Author(s): Yoshinori Sato
  • Organizer: International Symposium on Nanotoxicology Assessment and Biomediacal, Environmental Application of Fine Particles and Nanotubes
  • Place of Presentation: Sapporo, Japan
  • Year and Date: 2008-06-16
• [Presentation] Multiwalled carbon nanotube blocks crosslinked by defluorination (2008)
  • Author(s): Yoshinori Sato
  • Organizer: International Symposium on Nanotoxicology Assessment and Biomediacal, Environmental Application of Fine Particles and Nanotubes
  • Place of Presentation: Sapporo, Japan
  • Year and Date: 2008-06-16
• [Presentation] Solidification of Lanthanum Carbide-Encapsulating Carbon Nanocapsule/LaB6 composites (2008)
  • Author(s): Y. Sato, I. Waki, M. Namura, K. Motomiya, B. Jeyadevan, K. Tohji
  • Organizer: ChemOnTubes 2008, International meeting on the chemistry of nanotubes : science and applications, Book of abstract P131
  • Place of Presentation: Zaragoza, Spain
  • Year and Date: 2008-04-07
• [Presentation] Carbon Nanotube Blocks Cross-Linked by De-fluorination (2008)
  • Author(s): Y. Sato, M. Ootsubo, G. Yamamoto, G. Van Lier, M. Terrones, S. Hashiguchi, H. Kimura, A. Okubo, K. Motomiya, B. Jeyadevan, T. Hashida, K. Tohji
  • Organizer: ChemOnTubes 2008, International meeting on the chemistry of nanotubes: science and applications, Book of abstract P129
  • Place of Presentation: Zaragoza, Spain
  • Year and Date: 2008-04-07
• [Presentation] Carbon Nanotube Blocks CrossLinked by Defluorination (2008)
  • Author(s): Yoshinori Sato
  • Organizer: ChemOnTubes 2008
  • Place of Presentation: Zaragoza, Spain
  • Year and Date: 2008-04-07
• [Presentation] あなたの使っているカーボンナノチューブの完全性は大丈夫? (2008)
  • Author(s): 佐藤義倫
  • Organizer: 日本金属学会 2008年春季大会 、P307
  • Place of Presentation: 東京都、千代田区
  • Year and Date: 2008-03-24
• [Presentation] Preparation and Properties of Rubber Filled with Radial Single-walled Carbon Nanotubes (2007)
  • Author(s): Y. Sato, K. Hasegawa, N. Ito, K. Motomiya, B. Jeyadevan, K. Tohji
  • Organizer: 2007 MRS Fall Meeting, Program & Exhibit Guide P321
  • Place of Presentation: Boston, Massachusetts, US
  • Year and Date: 2007-11-29
• [Presentation] LaC2内包カーボンナノカプセル固化体の作製 (2007)
  • Author(s): 佐藤義倫、脇 一平、名村 優、大久保 昭、木村久道、本宮憲一、バラチャンドラン ジャヤデワン、田路和幸
  • Organizer: 第4回「ナノトキシコロジーアセスと微粒子・ナノチューブのバイオ応用」、P19
  • Place of Presentation: 東京都、江戸川区
  • Year and Date: 2007-08-01
• [Presentation] 放射状単層カーボンナノチューブを補強材としたゴムの調製と特性 (2007)
  • Author(s): 佐藤義倫、長谷川研二、伊藤信幸、本宮憲一、B. ジャヤデワン、田路和幸
  • Organizer: 第33回フラーレン・ナノチューブ総合シンポジウム、P219
  • Place of Presentation: 福岡県、福岡市
  • Year and Date: 2007-07-13
• [Presentation] Relation of the Number of Cross-links and Mechanical Properties of Multi-Walled Carbon Nanotube Films Formed by a Dehydration Condensation Reaction (2007)
  • Author(s): Yoshinori Sato
  • Organizer: 2007 MRS Spring Meeting (Materials Research Society)
  • Place of Presentation: San Francisco, CA, USA
  • Year and Date: 2007-04-10
• [Patent(Industrial Property Rights)] 導電性材料およびその製造方法 (2008)
  • Inventor(s): 佐藤義倫、田路和幸、名村優
  • Industrial Property Rights Holder: 国立大学法人東北大学、DOWAホールディングス
  • Industrial Property Number: 特許,2008-232877
  • Filing Date: 2008-09-11
• [Patent(Industrial Property Rights)] カーボンナノチューブおよびその製造方法 (2008)
  • Inventor(s): 佐藤義倫、田路和幸、小倉正平、福谷克之、名村優
  • Industrial Property Rights Holder: 国立大学法人東北大学、財団法人生産技術研究奨励会、DOWAホールディングス
  • Industrial Property Number: 特許,2008-072799(国内優先2009-059208 )
  • Filing Date: 2008-03-21
• [Patent(Industrial Property Rights)] カーボンナノチューブの評価方法 (2008)
  • Inventor(s): 佐藤義倫、田路和幸、小倉正平、福谷克之、名村優
  • Industrial Property Rights Holder: 国立大学法人東北大学、国立大学法人東京大学、DOWAホールディングス
  • Industrial Property Number: 特許,2008-064126(国内優先2009-059160)
  • Filing Date: 2008-03-13