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Rheology and Onion structure control by the complex spatial confinement effect

Research Project

Project/Area Number 19740258
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Biophysics/Chemical physics
Research InstitutionNagaoka University of Technology

Principal Investigator

FUJI Shuji  Nagaoka University of Technology (40401781)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,350,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥150,000)
Fiscal Year 2008: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2007: ¥2,700,000 (Direct Cost: ¥2,700,000)
Keywordsソフトマターの物理 / 界面活性剤 / ラメラ相 / ゲスト成分 / オニオン / 構造転移 / レオロジー / コロイド微粒子 / 波うちゆらぎ / 空間拘束効果 / 流動誘起構造転移 / 多層膜ベシクル / 流動小角光散乱
Research Abstract

本研究では、流動場により誘起されるラメラ-多層膜ベシクル構造転移における高分子鎖の添加効果を粘弾性測定、流動小角光散乱、そして流動小角中性子散乱により調べた。高分子である3元ブロック共重合体を界面活性剤と混合した複合ラメラ相の構造転移は高分子濃度に敏感であり、高分子鎖間の反発作用により、転移が促進、あるいは抑制されることが分かった。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (40 results)

All 2009 2008 2007 Other

All Journal Article (10 results) (of which Peer Reviewed: 5 results) Presentation (29 results) Remarks (1 results)

  • [Journal Article] Influence of a triblock copolymer on phase behavior and shear induced topologies of a surfactant lamellar phase2009

    • Author(s)
      S. Fujii, S. Koschoreck, P. Lindner, W. Richtering
    • Journal Title

      Langmuir 25

      Pages: 5476-5483

    • Related Report
      2008 Final Research Report
  • [Journal Article] Discontinuous Growth of Onion Structure under Shear2009

    • Author(s)
      S. Fujii
    • Journal Title

      Prog. Colloid Polym. Sci., in press

    • Related Report
      2008 Final Research Report
  • [Journal Article] Multilamellar vesicles ("onions") under shear quench: pathway of discontinuous size growth2009

    • Author(s)
      S. Koschoreck, S. Fujii, P. Linder, W. Richtering
    • Journal Title

      Rheol. Acta 48

      Pages: 231-241

    • Related Report
      2008 Final Research Report
  • [Journal Article] Multilamellar vesicles("onions") under shear quench : pathway of discontinuous size growth2009

    • Author(s)
      S. Koschoreck, S. Fujii, P. Lindner, W. Richtering
    • Journal Title

      Rheologica Acta 48

      Pages: 231-241

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Discontinuous growth of onion structure under shear2009

    • Author(s)
      S. Fujii
    • Journal Title

      Progress in Colloid and Polymer Sciences (In press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of a triblock copolymer on phase behavior and shear induced topologies of a surfactant lamellar phase2009

    • Author(s)
      S. Fujii, S. Koschoreck, P. Lindner, W. Richtering
    • Journal Title

      Langmuir (In press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Shear-Induced Structures in Lamellar Systems2008

    • Author(s)
      S. Koschoreck, S. Fujii, W. Richtering
    • Journal Title

      Prog. Theor. Phys. 175

      Pages: 154-165

    • Related Report
      2008 Final Research Report
  • [Journal Article] Viscoelasticity of Onion phase composed of Complex Surfactant Bilayers2008

    • Author(s)
      Fujii, M. Konno, and Y. Isono
    • Journal Title

      Trans. MRS-J 33

      Pages: 425-426

    • Related Report
      2008 Final Research Report
  • [Journal Article] Shear-induced structures in lamellar phase2008

    • Author(s)
      S. Koschoreck, S.Fujii, W. Richtering
    • Journal Title

      Progress of Theoretical Physics 175

      Pages: 154-165

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Viscoelasticity of Onion Phase Composed of Complex Surfactant Bilayers2008

    • Author(s)
      S. Fujii, M. Konno, Y. Isono
    • Journal Title

      Trans. MRS-J (In press)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] スメクチック液晶の非線形レオロジー2009

    • Author(s)
      藤井修治、好村滋行
    • Organizer
      第64 回日本物理学会年会
    • Place of Presentation
      立教大学 (東京都)
    • Year and Date
      2009-03-27
    • Related Report
      2008 Final Research Report
  • [Presentation] スメクチック液晶の零線形レオロジー2009

    • Author(s)
      藤井修治、好村滋行
    • Organizer
      日本物理学会年会
    • Place of Presentation
      立教大学
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] ずり流動下における多層膜ベシクルのサイズ変化2008

    • Author(s)
      藤井修治、五十野善信
    • Organizer
      第57 回高分子北陸支部会
    • Place of Presentation
      福井大学 (福井県)
    • Year and Date
      2008-11-16
    • Related Report
      2008 Final Research Report
  • [Presentation] ずり流動下における多層膜ベシクルのサイズ変化2008

    • Author(s)
      藤井修治、五十野善信
    • Organizer
      高分子学会北陸支部会
    • Place of Presentation
      福井大学
    • Year and Date
      2008-11-16
    • Related Report
      2008 Annual Research Report
  • [Presentation] Kinetic pathway in the size change of multilamellar vesicles under shear flow2008

    • Author(s)
      S. Fujii, S. Kawahara, Y. Isono
    • Organizer
      nternational Rubber Conference 2008
    • Place of Presentation
      Kuala Lumpur (Malaysia)
    • Year and Date
      2008-10-20
    • Related Report
      2008 Final Research Report
  • [Presentation] Shear-induced multilamellar vesicle formation of polymer-doped surfactant2008

    • Author(s)
      T. Araki, S. Fujii, S. Kawahara, Y . Isono
    • Organizer
      International Rubber Conference 2008
    • Place of Presentation
      Kuala Lumpur (Malaysia)
    • Year and Date
      2008-10-20
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Kinetic pathway in the size change of multilamellar vesicles under shear flow2008

    • Author(s)
      S. Fujii, S. Kawahara, Y. Isono
    • Organizer
      International Rubber Conference 2008
    • Place of Presentation
      Kuala Lumpur (Malaysia)
    • Year and Date
      2008-10-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] ずり速度変化による多層膜ベシクル構造成長のダイナミクス2008

    • Author(s)
      藤井修治、五十野善信
    • Organizer
      第56 回日本レオロジー討論会
    • Place of Presentation
      朱鷺メッセ (新潟県)
    • Year and Date
      2008-10-08
    • Related Report
      2008 Final Research Report
  • [Presentation] ずり速度変化による多層膜ベシクル構造成長のダイナミクス2008

    • Author(s)
      藤井修治、五十野善信
    • Organizer
      第56回日本レオロジー討論会
    • Place of Presentation
      朱鷺メッセ(新潟)
    • Year and Date
      2008-10-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] ずり流動下における多層膜ベシクルの構造変化2008

    • Author(s)
      藤井修治、五十野善信
    • Organizer
      第57 回高分子討論会
    • Place of Presentation
      大阪市立大学 (大阪府)
    • Year and Date
      2008-09-26
    • Related Report
      2008 Final Research Report
  • [Presentation] ずり流動下における多層膜ベシクルの構造変化2008

    • Author(s)
      藤井修治、五十野善信
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2008-09-26
    • Related Report
      2008 Annual Research Report
  • [Presentation] ずり流動変化によるオニオン構造の不連続的成長2008

    • Author(s)
      藤井修治
    • Organizer
      田中豊一シンポジウム
    • Place of Presentation
      アルカディア市谷 (東京)
    • Year and Date
      2008-09-11
    • Related Report
      2008 Final Research Report
  • [Presentation] ずり流動変化によるオニオン構造の不連続的成長2008

    • Author(s)
      藤井修治
    • Organizer
      田中豊一記念シンポジウム
    • Place of Presentation
      アルカディア市谷(東京)
    • Year and Date
      2008-09-11
    • Related Report
      2008 Annual Research Report
  • [Presentation] Viscoelasticity of triblock copolymer-doped surfactant lamellar phases under shear2008

    • Author(s)
      S. Fujii, M. Konno, Y. Isono
    • Organizer
      7th Liquid Matter Conference
    • Place of Presentation
      Lund (Sweden)
    • Year and Date
      2008-06-27
    • Related Report
      2008 Final Research Report
  • [Presentation] Viscoelasticity of triblock copolymer-doped surfactant lamellar phases under shear2008

    • Author(s)
      S. Fujii, M. Konno, Y. Isono
    • Organizer
      7^<th> Liquid Matter Conference
    • Place of Presentation
      Lund (Sweden)
    • Year and Date
      2008-06-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] Shear-induced structures in lamellar systems2008

    • Author(s)
      S. Koschoreck, S. Fujii, W. Richt ering
    • Organizer
      International Symposium on Non-equilibrium Soft Matter
    • Place of Presentation
      京都
    • Year and Date
      2008-06-05
    • Related Report
      2008 Final Research Report
  • [Presentation] Shear-induced structures in lamellar systems2008

    • Author(s)
      S. Koschoreck, S. Fujii, W. Richtering
    • Organizer
      International Symposium on Non-equilibrium Soft Matter
    • Place of Presentation
      Shiran Kaikan, Kyoto
    • Year and Date
      2008-06-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] Influence of triblock copolymer on the onion formation of surfactant lamellar phase under shear2008

    • Author(s)
      S. FUJII, M. Konno, Y. Isono
    • Organizer
      International Symposium on Non-equilibrium Soft Matter
    • Place of Presentation
      京都
    • Year and Date
      2008-06-02
    • Related Report
      2008 Final Research Report
  • [Presentation] Influence of triblock copolymer on the onion formation of surfactant lamellar phase under shear2008

    • Author(s)
      S. Fujii, M. Konno, Y. Isono
    • Organizer
      International Symposium on Non-equilibrium Soft Matter
    • Place of Presentation
      Shiran Kaikan, Kyoto
    • Year and Date
      2008-06-02
    • Related Report
      2008 Annual Research Report
  • [Presentation] Viscoelasticity of Onion Phase Composed of Complex Surfactant Bilayers2007

    • Author(s)
      S. Fujii, M. Konno, Y. Isono
    • Organizer
      第18 回日本MRS 学術シンポジウム
    • Place of Presentation
      日本大学理工学部駿河台校舎(東京)
    • Year and Date
      2007-12-08
    • Related Report
      2008 Final Research Report
  • [Presentation] Viscoelasticity of Onion Phase Composed of Complex Surfactant Bilayers2007

    • Author(s)
      S. Fujii, M. Konno, Y. Isono
    • Organizer
      第18回日本MRS学術シンポジウム
    • Place of Presentation
      日本大学理工学部駿河台校舎
    • Year and Date
      2007-12-08
    • Related Report
      2007 Annual Research Report
  • [Presentation] 複合二分子膜系のオニオン相形成と破壊課程の粘弾性2007

    • Author(s)
      藤井修治, 今野美代子, 五十野善信
    • Organizer
      第55 回日本レオロジー討論会
    • Place of Presentation
      金沢大学 (石川県)
    • Year and Date
      2007-11-01
    • Related Report
      2008 Final Research Report
  • [Presentation] 複合二分子膜系のオニオン相形成と破壊過程の粘弾性2007

    • Author(s)
      藤井修治, 今野美代子, 五十野善信
    • Organizer
      第55回日本レオロジー討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2007-11-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Viscoelastic Effect on Confinement of Polymer Particle in Lamellar Phase und er Shear2007

    • Author(s)
      S. Fujii, M. Konno, Y. Isono
    • Organizer
      1st International Soft Matter Conference
    • Place of Presentation
      アーヘン(ドイツ)
    • Year and Date
      2007-10-01
    • Related Report
      2008 Final Research Report
  • [Presentation] Viscoelastic Effect on Confinement of Polymer Particle in Lamellar Phase under Shear2007

    • Author(s)
      S. Fujii, M. Konno, Y. Isono
    • Organizer
      1st International Soft Matter Conference
    • Place of Presentation
      ドイツ アーヘン
    • Year and Date
      2007-10-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Viscoelastic Properties of Spatially Confined Multilamellar Vesicles2007

    • Author(s)
      S. Fujii, Y. Isono
    • Organizer
      4st International Symposium on Advanced Materials in Asia-Pacific Rim
    • Place of Presentation
      朱鷺メッセ (新潟県)
    • Year and Date
      2007-07-14
    • Related Report
      2008 Final Research Report
  • [Presentation] Viscoelastic Properties of Spatially Confined Multilamellar Vesicles2007

    • Author(s)
      S. Fujii, Y. Isono
    • Organizer
      4st International Symposium on Advanced Materials in Asia-Pacific Rim
    • Place of Presentation
      新潟県 朱鷺メッセ
    • Year and Date
      2007-07-14
    • Related Report
      2007 Annual Research Report
  • [Presentation] 非イオン性界面活性剤マルチラメラベシクル相の構造変化と粘弾性挙動2007

    • Author(s)
      藤井修治、五十野善信、W. Richtering
    • Organizer
      第30回バイオレオロジー学会
    • Place of Presentation
      北海道大学 (北海道)
    • Year and Date
      2007-06-14
    • Related Report
      2008 Final Research Report
  • [Presentation] 非イオン性界面活性剤マルチラメラベシクル相の構造変化と粘弾性挙動2007

    • Author(s)
      藤井修治、五十野善信、W. Richtering
    • Organizer
      第30回バイオレオロジー学会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-06-14
    • Related Report
      2007 Annual Research Report
  • [Remarks] 第18 回日本MRS 学術シンポジウムにおいて Award for Encouragement of Research of Materials Science 受賞

    • Related Report
      2008 Final Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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