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Selective Organic Synthesis with Polyorganometallic Reagents

Research Project

Project/Area Number 19750031
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionKyoto University

Principal Investigator

KURAHASHI Takuya  Kyoto University, 大学院・工学研究科, 助教 (50432365)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,780,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥480,000)
Fiscal Year 2008: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2007: ¥1,700,000 (Direct Cost: ¥1,700,000)
Keywords有機金属化学 / 有機金属 / ホウ素 / 亜鉛 / 遷移金属 / 多置換亜鉛 / 多置換オレフィン
Research Abstract

現在の有機合成化学は有機金属化合物なくして成り立たない。炭素-金属結合の多様な反応性が有機合成に革新をもたらしているからである。同一炭素上に複数の金属を有する有機多金属反応剤は従来にない高度分子変換を可能にする事が期待できる。申請者はこれまでの知見を基にして、本研究では有機多金属反応剤の効率的な合成法の確立と、有機多金属反応剤を用いた高度分子変換反応の開発を目的として研究を行った。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (10 results)

All 2009 2008 2007

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (2 results)

  • [Journal Article] Nickel-Catalyzed [4+2] Cycloaddition of Enones with Alkynes2009

    • Author(s)
      Ichiro Koyama, Takuya Kurahashi, and Seijiro Matsubara
    • Journal Title

      J. Am. Chem. Soc. 131巻

      Pages: 1350-1351

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nickel-Catalyzed Decarbonylative Addition of Phthalimides to Alkynes2008

    • Author(s)
      Yuichi Kajita, Takuya Kurahashi, and Seijiro Matsubara
    • Journal Title

      J. Am. Chem. Soc. 130巻

      Pages: 6058-6059

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nickel-Catalyzed Decarbonylative Addition of Anhydrides to Alkynes2008

    • Author(s)
      Yuichi Kajita, Takuya Kurahashi, and Seijiro Matsubara
    • Journal Title

      J. Am. Chem. Soc. 130巻

      Pages: 17226-17227

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nickel-Catalyzed Decarbonylative Addition of Phthalimides to Alkynes2008

    • Author(s)
      Yuichi Kajita, Takuya Kurahashi, and Seijiro Matsubara,
    • Journal Title

      J. Am. Chem. Soc 130

      Pages: 6058-6059

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nickel-Catalyzed Decarbonylative Addition of Anhydrides to Alkynes2008

    • Author(s)
      Yuichi Kajita, Takuya Kurahashi, and Seijiro Matsubara,
    • Journal Title

      J. Am. Chem. Soc 130

      Pages: 17226-17227

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nickel-Catalyzed [4+2] Cycloaddition of Enones with Alkyne2008

    • Author(s)
      Ichiro Koyama, Takuya Kurahashi, and Seijiro Matsubara,
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 1350-1351

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 1, 1'-Linked cyclopropane derivatives: The helical conformation of quinquecyclopropanol2007

    • Author(s)
      Kurahashi, T.; Kozhushkov, S. I.; Schill, H.; Meindl, K.; Ruehl, S.; de Meijere, A
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 6545-6548

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile synthesis and palladium-catalyzed cross-coupling reactions of 2,3-bis (pinacolatoboryl)-l, 3-butadiene2007

    • Author(s)
      Shimizu, M.; Kurahashi, T.; Shimono, K.; Tanaka, K.; Nagao, I.; Kiyomoto, S.; Hiyama, T.
    • Journal Title

      Chem. Asian. J 2

      Pages: 1400-1408

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Synthesis of Heterocyclic Compounds via Nickel-Catalyzed Addition of C-N and C-O Bond to Alkynes2008

    • Author(s)
      倉橋拓也、松原誠二郎
    • Organizer
      第55回有機金属化学討論会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2008-09-29
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Synthesis of Isoquinolones via Nickel-Catalyzed Decarbonylative Carboamination of Alkynes with Phthalimides2007

    • Author(s)
      梶田雄一、倉橋拓也、松原誠二郎
    • Organizer
      第54回有機金属化学討論会
    • Place of Presentation
      広島大学
    • Year and Date
      2007-10-27
    • Related Report
      2008 Final Research Report 2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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