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Structural Tuning and Template Effect of Surface Nanospace by using Planer π-Conjugated Molecules

Research Project

Project/Area Number 19750033
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionOsaka University

Principal Investigator

TAHARA Kazukuni  Osaka University, 大学院・基礎工学研究科, 助教 (40432463)

Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥600,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2007: ¥1,300,000 (Direct Cost: ¥1,300,000)
Keywords自己組織化 / 走査型プローブ顕微鏡 / 有機化学 / 表面・界面物性 / 固液界面 / 走査プローブ顕微鏡
Research Abstract

To the surface nanospace of 2D porous molecular network formed by π-conjugated molecules at a liquid/solid interface, we investigated an expansion by insertion of spacer molecule, fixation via covalent bonding by chemical reaction on the surface, and formation of multi-component alignment by guest co-adsorption. As a result, in the former two projects, important results toward the final goal of these projects were obtained. We also achieved the construction of multi-component alignment. These results are very important for the development in field of nanotechnology.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (45 results)

All 2010 2009 2008 2007 Other

All Journal Article (13 results) (of which Peer Reviewed: 12 results) Presentation (30 results) Book (1 results) Remarks (1 results)

  • [Journal Article] 2D Networks of Rhombic-Shaped Fused Dehydrobenzo[12]annulenes: Structural Variations under Concentration Control2009

    • Author(s)
      Tahara, K., Okuhata, S., Adisoejoso, J., Lei, S., Fujita, T., De Feyter, S., Tobe, Y.
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 17583-17590

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 2D Crystal Engineering: a Four-Component Archtecture at a Liquid-Solid Interface2009

    • Author(s)
      Adisoejoso, J., Tahara, K., Okuhata, S., Lei, S., Tobe, Y., De Feyter, S.
    • Journal Title

      Angew. Chem. Int. Ed. 48

      Pages: 7353-7357

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Two-Dimensional Crystal Engineering : A Four-Component Architecture at a Liquid-Solid Interface2009

    • Author(s)
      Jinne Adisoejoso, et al.
    • Journal Title

      Angewandte Chemie International Edition 48

      Pages: 7353-7357

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 有機分子を固体表面に並べて作る幾何学模様2009

    • Author(s)
      戸部義人
    • Journal Title

      機能材料 29

      Pages: 6-15

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Programmable Hierarchical Three-Component 2D Assembly at a Liquid-Solid Interface: Recognition, Selection, and Transformation2008

    • Author(s)
      Lei, S., Surin, M., Tahara, K., Adisoejoso, J., Lazzaroni, R., Tobe, Y., De Feyter, S.
    • Journal Title

      Nano Lett. 8

      Pages: 2541-2546

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Giant Molecular Wheels in Giant Voids; Two-Dimensional Molecular Self-Assembly Goes Big2008

    • Author(s)
      Tahara, K., Lei, S., Mossinger, D., Kozuma, S., Inukai, K., De Schryver, F.C., Hoger, S., Tobe, Y., De Feyer, S.
    • Journal Title

      Chem. Commun.

      Pages: 3897-3899

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Clusters in Two-Dimensional Surface-Confined Nanoporous Molecular Networks: Structure Rigidity and Dynamics2008

    • Author(s)
      Lei, S., Tahara, K., Feng, X., Furukawa, S., De Schryver, F.C., Mullen, K., Tobe, Y., De Feyter, S.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 7119-7129

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Site-Selective Guest Inclusion in Molecular Networks of Butadiyne-Bridged Pyridino and Benzo Square Macorcycles on a Surface2008

    • Author(s)
      Tahara, K., Lei, S., Mamdouh, W., Yamaguchi, Y., Ichikawa, T., Uji-i, H., Sonoda, M., Hirose, K., De Schryver, F.C., De Feyter, S., Tobe, Y.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 7119-7129

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] One Building Block, Two Different Supramolecular Surface-Confined Patterns: Concentration in Control at the Solid/liquid Interface2008

    • Author(s)
      Lei, S., Tahara, K., De Schryver, F.C., Van der Auweraer, M., Tobe, Y., De Feyter, S.
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 2964-2968

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Site-Selective Guest Inclusion in Molecular Networks of Butadiyne-Bridged Pyridino and Benzeno Square Macrocycles on a Surface2008

    • Author(s)
      Tahara Kazukuni, et.al.
    • Journal Title

      Journal of American Chemical Society 130

      Pages: 6666-6667

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Clusters in Two-Dimensional Surface-Confined Nanoporous Molecular Networks : Structure, Rigidity, and Dynamics2008

    • Author(s)
      Lei Shengbin, et.al.
    • Journal Title

      Journal of American Chemical Society 130

      Pages: 7119-7129

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Giant Molecular Spoked Wheels in Giant Voids : Two-Dimensional Molecular Self-Assembly Goes Big2008

    • Author(s)
      Tahara Kazukuni, et.al.
    • Journal Title

      Chemical Communication

      Pages: 3897-3899

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One Building Block, Two Different Supramolecular Surface-Confined Patterns: Concentration in Control at the Solid/liquid Interface2008

    • Author(s)
      Lei. S., et. al.
    • Journal Title

      Angew. Chem. Int. Ed. In press

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] アゾベンゼン部位を含むデヒドロベンゾ[12]アヌレン誘導体の多孔性2次元ネットワーク:ゲスト共吸着に及ぼすアゾベンゼン部位の影響2010

    • Author(s)
      犬飼晃司, 田原一邦, Steven De Feyter, 戸部義人
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      東大阪
    • Year and Date
      2010-03-26
    • Related Report
      2009 Final Research Report
  • [Presentation] ブタジイン架橋四角形マクロサイクルのモジュール式分子ネットワーク形成2010

    • Author(s)
      後藤田潤, 田原一邦, Steven De Feyter, 戸部義人
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      東大阪
    • Year and Date
      2010-03-26
    • Related Report
      2009 Final Research Report
  • [Presentation] 2D Crystal Engineering : a Four-Component Architecture at a Liquid-Solid Interface2009

    • Author(s)
      Kazukuni Tahara
    • Organizer
      GCOE Symposium, International Symposium on Bio-Enviromental Chemistry
    • Place of Presentation
      吹田市(大阪府)
    • Year and Date
      2009-12-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] Modular Molecular Networks of Butadiyne-Bridged Macrocycles2009

    • Author(s)
      Kazukuni Tahara, Jun Gotoda, Calden N. Stimpson, Jinne Adisoejoso, Steven De Feyter, Yoshito Tobe
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2009-11-10
    • Related Report
      2009 Final Research Report
  • [Presentation] ブタジイン架橋マクロサイクルのモジュール式分子ネットワーク形成2009

    • Author(s)
      後藤田潤, Calden N. Stimpson, 田原一邦, 戸部義人
    • Organizer
      第20回基礎有機討論会
    • Place of Presentation
      桐生
    • Year and Date
      2009-09-28
    • Related Report
      2009 Final Research Report
  • [Presentation] アゾベンゼンユニットを側鎖に含むデヒドロベンゾ[12]アヌレン誘導体の固液界面における2次元分=Fネットワーク2009

    • Author(s)
      犬飼晃司
    • Organizer
      第20回基礎有機討論会
    • Place of Presentation
      群馬大学(群馬県)
    • Year and Date
      2009-09-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 固液界面における複雑2次元分子配列の構築2009

    • Author(s)
      田原一邦
    • Organizer
      表面科学技術協会 第120回講演大会
    • Place of Presentation
      幕張メッセ(千葉)
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] Engineering of Multi-Component 2D Crystals at a Liquid-Solid Interface2009

    • Author(s)
      Kazukuni Tahara
    • Organizer
      China-Japan Joint Symposium on Functional Supramolecular Architectures
    • Place of Presentation
      札幌市(北海道)
    • Year and Date
      2009-08-03
    • Related Report
      2009 Annual Research Report
  • [Presentation] 2D Crystal Engineering: a Four-Component Architecture at a Liquid-Solid Interface2009

    • Author(s)
      Kazukuni Tahara, Jinne Adisoejoso, Satoshi Okuhata, Shengbin Lei, Steven De Feyter, Yoshito Tobe
    • Organizer
      13th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Luxembourg, Luxembourg
    • Year and Date
      2009-07-20
    • Related Report
      2009 Final Research Report
  • [Presentation] Formation of Modular Molecular Networks of Butaiyne-Bridged Macrocycles2009

    • Author(s)
      Jun Gotoda, Kazukuni Tahara, Yoshito Tobe
    • Organizer
      13th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Luxembourg, Luxembourg
    • Year and Date
      2009-07-20
    • Related Report
      2009 Final Research Report
  • [Presentation] 2D Crystal Engineering : a Four-Component Architecture at a Liquid-Solid Interface2009

    • Author(s)
      Kazukuni Tahara
    • Organizer
      13th International Symposium of Novel Aromatic Compounds
    • Place of Presentation
      ルクセンブルク市(ルクセンブルク)
    • Year and Date
      2009-07-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] ブタジイン架橋マクロサイクルのモジュール式分子ネットワーク形成に関する研究2009

    • Author(s)
      後藤田潤, 田原一邦, 戸部義人
    • Organizer
      第5回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      宇都宮
    • Year and Date
      2009-05-31
    • Related Report
      2009 Final Research Report
  • [Presentation] 固液界面における4成分分子ネットワークの構築2009

    • Author(s)
      田原一邦
    • Organizer
      第5回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      宇都宮大学(栃木県)
    • Year and Date
      2009-05-31
    • Related Report
      2009 Annual Research Report
  • [Presentation] 異なるアルコキシ基により置換された非対称デヒドロベンゾ[12]アヌレンの形成する単層膜2009

    • Author(s)
      田原一邦, Shengbin Lei, 犬飼晃司, Steven De Feyter, Frans C. De Schryver, 戸部義人
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-30
    • Related Report
      2009 Final Research Report
  • [Presentation] 多孔性分子ネットワークによる4成分2次元配列制御2009

    • Author(s)
      奥畑智, Jinne Adisoejoso, Shengbin Lei, 田原一邦, Frans C. De Schryver, Steven De Feyter, 戸部義人
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-30
    • Related Report
      2009 Final Research Report
  • [Presentation] ブタジイン架橋デヒドロベンゾ[12]アヌレンの固液界面における分子配列と反応性2009

    • Author(s)
      犬飼晃司, 原典孝, 田原一邦, Charles A. Johnson II, Michael M. Haley, 戸部義人
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-29
    • Related Report
      2009 Final Research Report
  • [Presentation] パイ共役分子のコアの形状ならびにアルキル鎖の置換様式が与える2次元分子ネットワーク形成への影響2009

    • Author(s)
      松下稔, 片山直浩, 田原一邦, Charles A. Johnson II, Michael M. Haley, 戸部義人
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-29
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 菱形の形状を有する縮環型デヒドロベンゾ[12]アヌレンの多孔性2次元分子ネットワーク:構造とゲスト共吸着2008

    • Author(s)
      田原一邦, 奥畑智, Shengbin Lei, Jinne Adisoejoso, Frans C. De Schryver, Steven De Feyter, 戸部義人
    • Organizer
      第19回基礎有機化学討論会
    • Place of Presentation
      吹田
    • Year and Date
      2008-10-04
    • Related Report
      2009 Final Research Report
  • [Presentation] 共有結合で結ばれた2次元分子ネットワークの合成に向けて2008

    • Author(s)
      犬飼晃司, Shengbin Lei, 田原一邦, Frans C. De Schryver, Steven De Feyter, 戸部義人
    • Organizer
      第19回基礎有機化学討論会
    • Place of Presentation
      吹田
    • Year and Date
      2008-10-03
    • Related Report
      2009 Final Research Report
  • [Presentation] 菱形ピリジノファンの固液界面における二次元分子ネットワークの形成とゲスト分子の共吸着2008

    • Author(s)
      片山直浩, 田原一邦, 戸部義人
    • Organizer
      第3回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2008-06-01
    • Related Report
      2009 Final Research Report
  • [Presentation] 菱形の形状を有する縮環型デヒドロベンゾ[12]アヌレンの固液界面における自己集合2008

    • Author(s)
      奥畑智, 田原一邦, 藤田匠, Shengbin Lei, Jinne Adisoejoso, Frans C. De Schryver, Steven De Feyter, 戸部義人
    • Organizer
      第3回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2008-06-01
    • Related Report
      2009 Final Research Report
  • [Presentation] 菱形の形状を有する縮環型デヒドロベンゾ[12]アヌレンの固液界面における自己集合2008

    • Author(s)
      奥畑智, 藤田匠, Shengbin Lei, Yihong Lu, 田原一邦, Frans C. De Schryver, Steven De Feyter, 戸部義人
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-28
    • Related Report
      2009 Final Research Report
  • [Presentation] 共有結合により結ばれた2次元分子ネットワークの合成に向けて2008

    • Author(s)
      戸部 義人
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] 菱形ピリジノファンの固液界面における2次元分子ネットワーク2008

    • Author(s)
      戸部 義人
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] 共有結合で結ばれた2次元分子ネットワークの合成に向けて2008

    • Author(s)
      犬飼晃司, Lei, Shengbin, 田原一邦, De Schryver, Frans C., De Feyter, Steven, 戸部義人
    • Organizer
      第19回基礎有機化学討論会
    • Place of Presentation
      大阪
    • Related Report
      2008 Annual Research Report
  • [Presentation] 菱形の形状を有する縮環型デヒドロベンゾ[12]アヌレンの固液界面における自己集合2008

    • Author(s)
      片山直浩, 田原一邦, 戸部義人
    • Organizer
      第3回ホストゲスト化学シンポジウム
    • Place of Presentation
      東京
    • Related Report
      2008 Annual Research Report
  • [Presentation] 菱形ピリジノファンの合成と固液界面における分子ネットワークの形成2007

    • Author(s)
      片山直浩, 奥畑智, 藤田匠, 田原一邦, 戸部義人
    • Organizer
      第1回有機π電子系シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2007-12-08
    • Related Report
      2009 Final Research Report
  • [Presentation] Substituent Effect on the Formation of the Kagome Network of Bis(dehydrobenzoannulene)s at the Solid-Liquid Interface2007

    • Author(s)
      Satoshi Okuhata, Takumi Fujita, Kazukuni Tahara, Yoshito Tobe
    • Organizer
      International Symposium on Green Sustainable Biological and Chemical Processes
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2007-11-16
    • Related Report
      2009 Final Research Report
  • [Presentation] Cotroll of Spacing Arrangement of Guest Molecule on Two-Dimensional Molecular Network of Butadiyne-Bridged Square Macrocycle2007

    • Author(s)
      Kazukuni Tahara, Weal Mamdouh, Yui Yamaguchi, Hiroshi Uji-i, Ichikawa Tomoyuki, Motohiro Sonoda, Keiji Hirose, Steven De Feyter, Frans C. De Schryver, Yoshito Tobe
    • Organizer
      12th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Awaji, Japan
    • Year and Date
      2007-07-24
    • Related Report
      2009 Final Research Report
  • [Presentation] Substituent Effect on the Formation of the Kagome Network of Bis(dehydrobenzoannulene)s at the Solid-Liquid Interface2007

    • Author(s)
      Satoshi Okuhata, Takumi Fujita, Kazukuni Tahara, Yoshito Tobe
    • Organizer
      12th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Awaji, Japan
    • Year and Date
      2007-07-23
    • Related Report
      2009 Final Research Report
  • [Book] 有機分子を固体表面に並べて作る幾何学模様, 機能材料2009

    • Author(s)
      戸部義人, 田原一邦
    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://www.supra.chem.es.osaka-u.ac.jp/

    • Related Report
      2009 Final Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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