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Development of Near-infrared Emissive Material by Ring-fusion Method

Research Project

Project/Area Number 19750036
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionKyushu University

Principal Investigator

TOGANOH Motoki  Kyushu University, 大学院・工学研究院, 助教 (80372754)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,530,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥330,000)
Fiscal Year 2008: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2007: ¥2,100,000 (Direct Cost: ¥2,100,000)
Keywordsポルフィリン / 近赤外色素 / 発光材料 / 遷移金属錯体 / 有機金属錯体 / 水中挙動 / ポルフイリン / レニウム錯体 / 触媒反応
Research Abstract

様々な骨格融合種の合成に成功し、骨格融合法という有機パイ共役系分子の新たな分子設計の概念を発展させた。すなわち、アヌレン環内部に多重結合を融合させることで、分子骨格のむやみな巨大化・複雑化なしに有機近赤外色素を合成することに成功した。また、水溶性誘導体を合成し、水中での骨格融合種の基本的性質を明らかとした。さらに、関連する遷移金属錯体を種々合成し、その構造及び性質を明らかとした。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (52 results)

All 2009 2008 2007 Other

All Journal Article (28 results) (of which Peer Reviewed: 28 results) Presentation (22 results) Remarks (2 results)

  • [Journal Article] Synthesis and protonation behavior of a water-soluble N-fused porphyrin : Conjugation with an oligoarginine by click chemistry2009

    • Author(s)
      Ikawa, Y. ; Harada, H. ; Toganoh, M ; Furuta, H
    • Journal Title

      Bioorg. Med. Chem. Lett 19

      Pages: 2448-2452

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Programmed Asymmetrical Trimer Formation of β-alkyk N-confused Porphyrin Zinc (II) Complexes2009

    • Author(s)
      Toganoh, M. ; Ogawa, H. ; Morimoto, T. ; Furuta, H.
    • Journal Title

      Supramol. Chem 21

      Pages: 324-330

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Novel Azo-embedded N-Confused Tetraphenylporphyrin2009

    • Author(s)
      Toganoh, M. ; Hihara, T. ; Yonekura K. ; Ishikawa, Y. ; Furuta, H.
    • Journal Title

      J. Porphyrins Phthalocyanines 13

      Pages: 215-222

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Novel Azo-embedded N-Confused Tetraphenylporphyrin2009

    • Author(s)
      Toganoh, M. ; Hihara, T. ; Yonekura K. ; Ishikawa, Y ; Furuta, H
    • Journal Title

      J. Porphyrins Phthalocyanines (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Programmed Asymmetrical Trimer Formation of β-alkyl N-confused Porphyrin Zinc (II) Complexes2009

    • Author(s)
      Toganoh, M. ; Ogawa, H. ; Morimoto T. ; Furuta, H
    • Journal Title

      Supramol. Chem (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and protonation behavior of a water-soluble N-fused porphyrin : Conjugation with an oligoarginine by click chemistry2009

    • Author(s)
      Ikawa, Y. ; Harada, H. ; Toganoh, M. ; Furuta, H
    • Journal Title

      Bioorg. Med. Chem. Lett (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of N-Confused Tetraphenylporphyrin Rhodium Complexes Having Versatile Metal Oxidation States2008

    • Author(s)
      Srinivasan, A. ; Toganoh, M. ; Niino, T. ; Osuka, A. ; Furuta, H.
    • Journal Title

      Inorg. Chem 47

      Pages: 11305-11313

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Endocyclic Extension of Porphyrin Tr-System by Interior Functionalization of N-Confused Porphyrins2008

    • Author(s)
      Toganoh, M. ; Kimura, T. ; Furuta, H.
    • Journal Title

      Chem. Eur. J 14

      Pages: 10585-10594

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Doubly N-Fused Porphyrin2008

    • Author(s)
      Toganoh, M. ; Kimura, T. ; Uno, H. ; Furuta, H.
    • Journal Title

      Angew. Chem. Int. Ed 47

      Pages: 8913-8916

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen-bonding Network in New Scorpionate-type Ligand Composed of Pyridine/Pyrrole Hybrid and Anion-binding Behavior of the Corresponding Rhodium Complexes in Alkyne Cyclotrimerization Reaction2008

    • Author(s)
      Toganoh, M. ; Harada, N. ; Furuta, H.
    • Journal Title

      J. Organomet. Chem 693

      Pages: 3141-3150

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Luminescent gold (III) Organometallic Complex of N-Confused Tetraphenylporphyrin2008

    • Author(s)
      Toganoh, M. ; Niino, T. ; Furuta, H.
    • Journal Title

      Chem. Commun

      Pages: 4070-4072

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Near-infrared Luminescence of Bis-Pt (II) Complexes of Doubly N-Confused Calix[6]phyrins (1.1.1.1.1.1)2008

    • Author(s)
      Won, D.-H. ; Toganoh, M. ; Terada, Y. ; Fukatsu, S. ; Uno, H. ; Furuta, H.
    • Journal Title

      Angew. Chem. Int. Ed 47,

      Pages: 5438-5441

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Substitution, Dimerization, Metallation, and Ring-opening Reactions of N-Fused Porphyrins2008

    • Author(s)
      Ishizuka, T. ; Ikeda, S. ; Toganoh, M. ; Yoshida, I. ; Ishikawa, Y. ; Osuka, A. ; Furuta, H.
    • Journal Title

      Tetrahedron 64

      Pages: 4037-4050

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] N-Confused and N-Fused meso-Aryl Sapphyrins2008

    • Author(s)
      Gupta, I. ; Srinivasan, A. ; Morimoto, T. ; Toganoh, M. ; Furuta, H.
    • Journal Title

      Angew. Chem. Int. Ed 47

      Pages: 4563-4567

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Deoxygenation of Pyridine N-Oxide with N-Fused Porphyrin Rhenium Complexes2008

    • Author(s)
      Toganoh, M. ; Fujino, K. ; Ikeda, S. ; Furuta, H.
    • Journal Title

      Tetrahedron Lett 49

      Pages: 1488-1491

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Endocyc1ic Extension of Porphyrin π-System in Etheno-bridged N-Confused Tetraphenylporphyrin2008

    • Author(s)
      Toganoh, M. ; Kimura, T. ; Furuta, H.
    • Journal Title

      Chem. Commun

      Pages: 102-104

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Near-infrared Luminescence of Bis-Pt (II) Complexes of Doubly N-Confused Calix[6]phyrins (1. 1. 1. 1. 1. 1)2008

    • Author(s)
      Won, D. -H. ; Toganoh, M. ; Terada, Y ; Fukatsu, S. ; Uno, H. ; Furuta, H
    • Journal Title

      Angew. Chem. Int. Ed 47

      Pages: 5438-5441

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Luminescent gold (III) Organometallic Complex of N-Confused Tetraphenylporphyrin2008

    • Author(s)
      Toganoh, M. ; Niino, T. ; Furuta, H
    • Journal Title

      Chem. Commun

      Pages: 4070-4072

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen-bonding Network in New Scorpionate-type Ligand Composed of Pyridine/Pyrrole Hybrid and Anion-binding Behavior of the Corresponding Rhodium Complexes in Alkyne Cyclotrimerization Reaction2008

    • Author(s)
      Toganoh, M.; Harada, N.; Furuta, H
    • Journal Title

      J. Organomet. Chem 693

      Pages: 3141-3050

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Doubly N-Fused Porphyrin2008

    • Author(s)
      Toganoh, M. ; Kimura, T. ; Uno, H. ; Furuta, H
    • Journal Title

      Angew. Chem. Int. Ed 47

      Pages: 8913-8916

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Endocyclic Extension of Porphyrin π-System by Interior Functionalization of N-Confused Porphyrins2008

    • Author(s)
      Toganoh, M. ; Kimura, T. ; Furuta, H
    • Journal Title

      Chem. Eur. J 14

      Pages: 10585-10594

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of N-Confused Tetraphenylporphyrin Rhodium Complexes Having Versatile Metal Oxidation States2008

    • Author(s)
      Srinivasan, A. ; Toganoh, M. ; Niino, T. ; Osuka, A. ; Furuta, H
    • Journal Title

      Inorg. Chem 47

      Pages: 11305-11313

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Endocyclic Extension of Porphyrin π-System in Etheno-bridged N-Confused Tetraphenylporphyrin2008

    • Author(s)
      M., Toganoh, et. al.
    • Journal Title

      Chemical Communications

      Pages: 102-104

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] catalytic Deoxygenation of Pyridine N-Oxide with N-Fused Porphyrin Rhenium Complexes2008

    • Author(s)
      M., Toganoh, et. al.
    • Journal Title

      Tetrahedron Letters 49

      Pages: 1488-1491

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Substitution, Dimerization, Metallation, and Ring-Opening Reactions of N-Fused Porphyrins2008

    • Author(s)
      T., lshizuka・M., Toganoh, et. al.
    • Journal Title

      Tetrahedron 64

      Pages: 4037-4050

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] N-Confused and N-Fused meso-Aryl Sapphyrins2008

    • Author(s)
      I., Gupta・M., Toganoh, et. al.
    • Journal Title

      Angewandte Chemie Intemational Edition (in press)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Reactivity, and Properties of N-Fused Porphyrin Rhenium (I) Tricarbonyl Complexes2007

    • Author(s)
      Toganoh, M. ; Ikeda, S. ; Furuta, H.
    • Journal Title

      Inorg. Chem 46

      Pages: 10003-10015

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Reactivity, and Properties of N-Fused Porphyrin Rhenium(1) Tricarbonyl Complexes2007

    • Author(s)
      M., Toganoh, et. al.
    • Journal Title

      lnorganic Chemistry 46

      Pages: 10003-10015

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] 大環状化合物の環内部化学修飾による有機近赤外発光材料の合成2009

    • Author(s)
      戸叶基樹
    • Organizer
      日本化学会第89春季年会, 第23回若い世代の特別講演会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] 水溶性N-フユーズポルフィリンの合成と水中特性2009

    • Author(s)
      原田紘行, 戸叶基樹, 井川善也, 古田弘幸
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] アセチレン架橋N-混乱ポルフィリン二量体の合成と物性2009

    • Author(s)
      高山拓未, 戸叶基樹, 古田弘幸
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 混乱およびミスマッチ型コロール異性体の合成と物性2009

    • Author(s)
      藤野敬太郎, 戸叶基樹, 古田弘幸
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] ルテノセン型N-フユーズボルフィリン錯体の合成と物性2009

    • Author(s)
      佐藤歩, 戸叶基樹, 古田弘幸
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] 大環状化合物の環内部化学修飾による有機近赤外発光材料の合成2009

    • Author(s)
      戸叶基樹
    • Organizer
      日本化学会第89春季年会,第23回若い世代の特別講演会
    • Place of Presentation
      船橋
    • Related Report
      2008 Final Research Report
  • [Presentation] 多重N-混乱オリゴビロールの位置選択的合成2008

    • Author(s)
      川部泰典, 戸叶基樹, 古田弘幸
    • Organizer
      第20回若手研究者のためのセミナー
    • Place of Presentation
      福岡
    • Year and Date
      2008-12-13
    • Related Report
      2008 Annual Research Report
  • [Presentation] アセチレン架橋N-混乱ポルフィリン二量体の合成と物性2008

    • Author(s)
      高山拓未, 山崎洋揮, 戸叶基樹, 古田弘幸
    • Organizer
      第20回若手研究者のためのセミナー
    • Place of Presentation
      福岡
    • Year and Date
      2008-12-13
    • Related Report
      2008 Annual Research Report
  • [Presentation] N-フユーズポルフィリンルテニウム錯体の合成と物性2008

    • Author(s)
      佐藤歩, 池田慎也, 戸叶基樹, 古田弘幸
    • Organizer
      九州錯体化学談話会創設40周年記念シンポジウム
    • Place of Presentation
      福岡
    • Year and Date
      2008-11-01
    • Related Report
      2008 Annual Research Report
  • [Presentation] Synthesis and coordination chemistry of N-confused and N-fusec porphyrinoids2008

    • Author(s)
      Hiroyuki Furuta, Iti Gupta, Dong-Hoon Won, Tomoyui Kimura, Motoki Toganoh
    • Organizer
      The 3rd International Conference of Cutting-Edge Organic Chemistry in Asia
    • Place of Presentation
      Hangzhou, China
    • Year and Date
      2008-10-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] 環内部にアゾ基を有するN-混乱ポルフィリンの合成および物性2008

    • Author(s)
      日原崇貴, 戸叶基樹, 石川雄一, 古田弘幸
    • Organizer
      第45回化学関連支部合同九州大会
    • Place of Presentation
      北九州
    • Year and Date
      2008-07-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] 親水性基を有するβ-アルキル型N-混乱ポルフィリンの合成及び水溶液挙動2008

    • Author(s)
      青木秀樹, 戸叶基樹, 古田弘幸
    • Organizer
      第45回化学関連支部合同九州大会
    • Place of Presentation
      北九州
    • Year and Date
      2008-07-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] ポルフィリン変異種を配位子とする金属錯体の合成と触媒反応への展開2008

    • Author(s)
      戸叶基樹
    • Organizer
      有機合成化学講演会
    • Place of Presentation
      山口
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] 骨格融合法を基盤とするポルフィリン変異種の創製2008

    • Author(s)
      戸叶基樹
    • Organizer
      万有若手合宿セミナー
    • Place of Presentation
      天草
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Coordination Chemistry of N-Confused and N-Fused Porphyrins2008

    • Author(s)
      Motoki Toganoh, Hiroyuki Furuta
    • Organizer
      236th ACS National Meeting & Exposition
    • Place of Presentation
      Philadelphia, USA
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Synthesis and Properties of Fused Porphyrinoids2008

    • Author(s)
      Motoki Toganoh, Tomoyuki Kimura, Shinya Ikeda, Hiroyuki Furuta
    • Organizer
      The 1st Kyushu University Global COE / CNSI Joint Symposium on Molecular Nanosystems
    • Place of Presentation
      California, USA
    • Related Report
      2008 Final Research Report
  • [Presentation] ピロール環の回転を鍵とする新規縮環型ポルフィリノイドの合成と性質2007

    • Author(s)
      戸叶基樹
    • Organizer
      第19回若手研究者のためのセミナー
    • Place of Presentation
      熊本
    • Related Report
      2008 Final Research Report
  • [Presentation] 特異な縮環構造を有する大環状化合物の合成と性質2007

    • Author(s)
      戸叶基樹,木村智之,池田慎也,藤野敬太郎,古田弘幸
    • Organizer
      第37回構造有機化学討論会
    • Place of Presentation
      札幌
    • Related Report
      2008 Final Research Report
  • [Presentation] Construction of Unique Architectures through Rotation of Pyrrole Rings in Tetrapyrrolic Macrocycles2007

    • Author(s)
      Motoki Toganoh
    • Organizer
      POST ISNA-12 Symposium on Physical Organic Chemistry
    • Place of Presentation
      Fukuoka
    • Related Report
      2008 Final Research Report
  • [Presentation] Twisting [18] annulene through rotation of pyrrole ring in tetrapyrrolic macrocycles2007

    • Author(s)
      Motoki Toganoh, Hiroyuki Furuta
    • Organizer
      12th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Awaji
    • Related Report
      2008 Final Research Report
  • [Presentation] Construction of Unique Architectures through Rotation of Pyrrole Rings in Tetrapyrrolic Macrocycles2007

    • Author(s)
      M., Toganoh
    • Organizer
      POST ISNA-12 Symposium
    • Place of Presentation
      Fukuoka
    • Related Report
      2007 Annual Research Report
  • [Presentation] ピロールの回転を鍵とする新規縮環型ポルフィリノイドの合成と性質2007

    • Author(s)
      戸叶基樹
    • Organizer
      第19回若手研究者のためのセミナー
    • Place of Presentation
      熊本
    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://post2.cstf.kyushu-u.ac.jp/furutalab/

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://post2.cstf.kyushu-u.ac.jp/~furutalab/

    • Related Report
      2007 Annual Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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