Modulation for electronic structures of One-dimensional Chain Complexes Containing Platinum and Hetero-metals

• Project/Area Number: 19750048
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Inorganic chemistry
• Research Institution: Yamaguchi University
• Principal Investigator: UEMURA Kazuhiro Yamaguchi University, 大学院・理工学研究科, 助教 (60386638)
• Project Period (FY): 2007 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥3,460,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥360,000); Fiscal Year 2008: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2007: ¥1,900,000 (Direct Cost: ¥1,900,000)
• Keywords: 錯体合成 / 量子細線 / 導電物性

Research Abstract

ロジウム挿入型白金一次元鎖(-Pt-Rh-Pt4-Rh-Pt-Cl-)の結晶構造をもとに, -Pt-M-Pt4-M-Pt-Cl-(M=異種金属)の繰り返し単位を有する,新規異種金属挿入型白金一次元鎖の合成検討を行った.検討の結果,Pt-Rh部位の補助配位子と架橋配位子を替えた新規ロジウム挿入型白金一次元鎖とロジウム挿入型白金八核錯体の合成,そして、その単結晶X線構造解析に成功した.また,興味深い電荷分布を持つ,新しい白金-異種金属多核錯体の合成に成功した.

Research Products

• [Journal Article] Crystal Structures, and Adsorption Properties of Ultramicroporous Coordination Polymers Constructed from Hexafluorosilicate Ionand Pyrazine (2009)
  • Author(s): K. Uemura, A. Maeda, T. K. Maji, P. Kanoo, H. Kita, Syntheses
  • Journal Title: Eur. J. Inorg. Chem Pages: 2329-2337
  • Peer Reviewed
• [Journal Article] Syntheses, Crystal Structures, and Adsorption Properties of Ultramicroporous Coordination Polymers Constructed from Hexafluorosilicate Ion and Pyrazine (2009)
  • Author(s): Kazuhiro Uemura
  • Journal Title: European Journal of Inorganic Chemistry (印刷中)
  • Peer Reviewed
• [Journal Article] Zipped-up Chain-type Coordination Polymers : Unsymmetrical Amide-Containing Ligands Inducing β-Sheet or Helical Structures (2008)
  • Author(s): K. Uemura, Y. Kumamoto, S. Kitagawa
  • Journal Title: Chem. Eur. J 14 Pages: 9565-9576
  • Peer Reviewed
• [Journal Article] Syntheses and Crystal Structures of Straight or Zigzag One-dimensional Coordination Polymers Based on Cu(II) Square Pyramidal or Cu(I) Tetrahedral Coordination Environments (2008)
  • Author(s): K. Uemura, A. Maeda, H. Kita
  • Journal Title: Polyhedron 27 Pages: 2939-2942
  • Peer Reviewed
• [Journal Article] Syntheses and crystal structures of novel silver(I) coordination polymers based on linear or tetrahedral coordination environments (2008)
  • Author(s): K. Uemura
  • Journal Title: Inorg. Chem. Commun 11 Pages: 741-744
  • Peer Reviewed
• [Journal Article] Characterization of organic solvents adsorption/desorption on hydrophobic porous coordination polymers and their micro-crystals aggregation on mullite support (2008)
  • Author(s): K. Uemura, Y. Komagawa, Y. Yamasaki, H. Kita
  • Journal Title: Desalination 234 Pages: 1-8
  • Peer Reviewed
• [Journal Article] Two-Step Adsorption/Desorption on a Jungle-Gym-Type Porous Coordination Polymer (2008)
  • Author(s): K. Uemura, Y. Yamasaki, Y. Komagawa, K. Tanaka, H. Kita
  • Journal Title: Angew. Chem. Int. Ed 46 Pages: 6662-6665
  • Peer Reviewed
• [Journal Article] Syntheses and Crystal Structures of Straight or Zigzag One-dimensional Coordination Polymers Based on Cu (II) Square Pyramidal or Cu (I) Tetrahedral Coordination Environments (2008)
  • Author(s): Kazuhiro Uemura
  • Journal Title: Polyhedron 27 Pages: 2939-2942
  • Peer Reviewed
• [Journal Article] Zipped-up Chain-type Coordination Polymers : Unsymmetrical Amide-Containing Ligands Inducing β-Sheet or Helical Structures (2008)
  • Author(s): Kazuhiro Uemura
  • Journal Title: Chemistry-A European Journal 14 Pages: 9565-9576
  • Peer Reviewed
• [Journal Article] Characterization of Organic Solvents Adsorption/Desorption on Hydrophobic Porous Coordination Polymers and Their Micro-Crystals Aggregation on Mullite Support (2008)
  • Author(s): Kazuhiro Uemura
  • Journal Title: Desalination (印刷中)
  • Peer Reviewed
• [Journal Article] Syntheses and crystal structures of novel silver(I) coordination polymersbased on linear or tetrahedral coordination enviromnents (2008)
  • Author(s): Kazuhiro Uemura
  • Journal Title: Inorgnic Chemistry Communications (印刷中)
  • Peer Reviewed
• [Journal Article] Synthesis of Amidate-Hanging Platinum Mononuclear Complexes by Base Hydrolysis of Nitriles Complexes (2007)
  • Author(s): K. Uemura, K. Yamasaki, K. Fukui, K. Matsumoto
  • Journal Title: Inorg. Chim. Acta 360 Pages: 2623-2630
  • Peer Reviewed
• [Journal Article] Synthesis of Amidate-hanging Mononuclear Platinum Complexes by BaseHydrolysis ofNitriles to Amides (2007)
  • Author(s): Kazuhiro Uemura
  • Journal Title: Inorganica Chimica Acta 360 Pages: 2623-2630
  • Peer Reviewed
• [Journal Article] Two-Step Adsorption/Desorption on a Jungle-Gym-Type Porous Coordination Polymer (2007)
  • Author(s): Kazuhiro Uemura
  • Journal Title: Angewandte Chemie International Edition 46 Pages: 6662-6665
  • Peer Reviewed
• [Presentation] Stepwise adsorption/desorption via shrunk intermediate state on jungle-gym-type porous coordination polymers (2008)
  • Author(s): K. Uemura, Y. Yamasaki, H. Kita
  • Organizer: 1st International Conference on Metal Organic Frameworks and Open Framework Compounds
  • Place of Presentation: Augsburg
• [Presentation] 架橋性SiF62-アニオンとピラジンを用いた多孔性配位高分子の合成と結晶構造 (2008)
  • Author(s): 植村一広, 前田聡久, 喜多英敏
  • Organizer: 第88春季年会
  • Place of Presentation: 立教大学
• [Presentation] ニトロ基導入による親水性細孔を有する配位高分子の合成 (2008)
  • Author(s): 大西文章
  • Organizer: 第58回錯体化学討論会
  • Place of Presentation: 金沢大学
• [Presentation] 架橋性SiF_6^<2->とピラジンによる多孔性配位高分子の小分子吸着能 (2008)
  • Author(s): 前田聡久
  • Organizer: 第58回錯体化学討論会
  • Place of Presentation: 金沢大学
• [Presentation] 多孔性配位高分子の骨格収縮を経る多段階アルコール吸着挙動 (2008)
  • Author(s): 山崎有加里
  • Organizer: 第2回分子科学討論会
  • Place of Presentation: 福岡国際会議場
• [Presentation] Synthesis, structures, and properties of hexafluorosilicate-bridging metal-pyrazine porous coordination polymers (2008)
  • Author(s): Akihisa Maeda
  • Organizer: 1st International Conference on Metal Organic Frameworks and Open Framework Compounds
  • Place of Presentation: Augsburg
• [Presentation] 架橋性SiF_6^<2->アニオンとピラジンを用いた多孔性配位高分子の合成と結晶構造 (2008)
  • Author(s): 植村一広
  • Organizer: 第88春季年会
  • Place of Presentation: 立教大学
• [Presentation] 新しいジャングルジム型多孔性配位高分子の結晶構造とアルコール吸着 (2008)
  • Author(s): 山崎有加里
  • Organizer: 第88春季年会
  • Place of Presentation: 立教大学
• [Presentation] ランタン型多孔性配位高分子と有機高分子を用いた複合膜の作製 (2008)
  • Author(s): 駒川祐樹
  • Organizer: 第88春平年会
  • Place of Presentation: 立教大学
• [Presentation] 柔らかい多孔性配位高分子結晶のアルコール吸着 (2007)
  • Author(s): 山崎有加里
  • Organizer: 化学工学会山口大会
  • Place of Presentation: 山口大学
  • Year and Date: 2007-11-22
• [Presentation] 不対スピンを有する異種金属混合原子価一次元鎖錯体の合成と性質 (2007)
  • Author(s): 植村一広, 福井孝一, 山崎加奈, 松本和子
  • Organizer: 第57回錯体化学討論会
  • Place of Presentation: 名古屋工業大学
• [Presentation] 柔軟な疎水性多孔性配位高分子の特異的なアルコール吸着挙動 (2007)
  • Author(s): 植村一広, 山崎有加里, 駒川祐樹, 田中一宏, 喜多英敏
  • Organizer: 化学工学会第39秋季年会
  • Place of Presentation: 北海道大学
• [Presentation] Stepwise Alcohol Adsorption on a Jungle-Gym-Analog Hydrophobic Porous Coordination Polymer (2007)
  • Author(s): K. Uemura, Y. Yamasaki, Y. Komagawa, K. Tanaka, H. Kita
  • Organizer: The 4th Conference of Aseanian Membrane Society
  • Place of Presentation: Taipei
• [Presentation] Mixed-Valent Platinum and Rhodium Octanuclear One-dimensional Complexes Having Unpaired Electrons (2007)
  • Author(s): K. Uemura, K. Fukui, K. Yamasaki, K. Matsumoto
  • Organizer: The First Asian Conference on Coordination Chemistry
  • Place of Presentation: kazaki
• [Presentation] Mixed-Valent Platinum and Rhodium Octanuclear One-dimensional Complexes Having Unpaired Electrons (2007)
  • Author(s): Kazuhiro Uemura
  • Organizer: The First Asian Conference on Coordination Chemistry
  • Place of Presentation: Okazaki
• [Presentation] Stepwise Alcohol Adsorption on a Jungle-Gym-Analog Hydrophobic Porous Coordination Polymer (2007)
  • Author(s): Kazuhiro Uemura
  • Organizer: The 4th Conference ofAseanian Membrane Society
  • Place of Presentation: Taipei
• [Presentation] 疎水性細孔を有する配位高分子の構造相転移を伴う多段階吸着挙動 (2007)
  • Author(s): 山崎有加里
  • Organizer: 第57回錯体化学討論会
  • Place of Presentation: 名古屋工業大学
• [Book] 有機貯蔵材料とナノ技術-水素社会に向けて (2007)
  • Author(s): 北川進, 植村一広
  • Publisher: シーエムシー出版
• [Book] 水素社会に向けての有機貯蔵材料とナノ技術 (2007)
  • Author(s): 北川進
  • Total Pages: 15
  • Publisher: シーエムシー出版