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Novel Classes of Living Radical Polymerization controlled by non-transition metal catalysts and light

Research Project

Project/Area Number 19750093
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer chemistry
Research InstitutionKyoto University

Principal Investigator

GOTO Atsushi  Kyoto University, 化学研究所, 助教 (20335219)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,700,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2007: ¥2,400,000 (Direct Cost: ¥2,400,000)
Keywordsリビングラジカル重合 / 非遷移金属触媒 / 可逆移動触媒重合 / リン触媒 / 窒素触媒 / 酸素触媒 / 光重合 / 光アンテナ / 非遷移金属 / 窒素化合物 / 酸素化合物 / ゲルマニウム / リン
Research Abstract

リン、窒素、および酸素化合物を触媒とするリビングラジカル重合に成功し、スチレンおよび各種の機能性メタクリレートの単独重合、ランダム共重合、およびブロック共重合を制御することができた。触媒には、亜リン酸エステル類、イミド類、およびフェノール類等が利用でき、特に、これらが汎用の化合物である点は特色である。さらに、フェニルフルオレン基およびキノリン基を光吸収アンテナとして用いた光誘起型リビングラジカル重合を開発した。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (46 results)

All 2009 2008 2007

All Journal Article (18 results) (of which Peer Reviewed: 17 results) Presentation (21 results) Patent(Industrial Property Rights) (7 results) (of which Overseas: 4 results)

  • [Journal Article] アルコールなどを触媒とする新しいタイプのリビングラジカル重合2009

    • Author(s)
      後藤淳
    • Journal Title

      化学工業 60(2)

      Pages: 1-7

    • Related Report
      2008 Final Research Report
  • [Journal Article] Reversible Chain Transfer Catalyzed Polymerization (RTCP) with Alcohol Catalysts2009

    • Author(s)
      A. Goto, N. Hirai, T. Wakada, K. Nagasawa, Y. Tsujii, T. Fukuda
    • Journal Title

      ACS Symp. (印刷中)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Chain Transfer Catalyzed Polymerization (RTCP) with Alcohol Catalysts2009

    • Author(s)
      Goto, A. Hirai, N. ; Wakada, T. ; Nagasawa, K. ; Tsujii, Y. ; Fukuda, T.
    • Journal Title

      ACS Symp. Ser. (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] アルコールなどを触媒とする新しいタイプのリビンクラジル重合2009

    • Author(s)
      後藤淳
    • Journal Title

      化学工業 60(2)

      Pages: 1-7

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Chain Transfer Catalyzed Polymerization (RTCP) : A New Class of Living Radical Polymerization2008

    • Author(s)
      A. Goto, Y. Tsujii, T. Fukuda
    • Journal Title

      Polymer 49(Feature article)

      Pages: 5177-5185

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Living Radical Polymerization with Nitrogen Catalyst - Reversible Chain Transfer Catalyzed Polymerization (RTCP) with N-Iodosuccinimide2008

    • Author(s)
      A. Goto, N. Hirai, T. Wakada, K. Nagasawa, Y. Tsuj ii, T. Fukuda
    • Journal Title

      Macromolecuels 41

      Pages: 6261-6264

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Transfer Catalyzed Polymerizations (RTCPs) of Styrene and Methyl Methacrylate with Phosphorus Catalysts2008

    • Author(s)
      A. Goto, N. Hirai, Y. Tsujii, T. Fukuda
    • Journal Title

      Macromol. Symp. 261

      Pages: 18-22

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Living Radical Polymerization with Nitrogen Catalyst - Reversible Chain Transfer Catalyzed Polymerization (RTCP) with N-Iodosuccinimide2008

    • Author(s)
      Goto, A. ; Zushi, H. ; Hirai, N. ; Wakada, T. ; Tsujii, Y. ; Fukuda, T.
    • Journal Title

      Macromolecules 41

      Pages: 6261-6263

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Chain Transfer Catalyzed Polymerization (RTCP) : A New Class of Living Radical Polymerization2008

    • Author(s)
      Goto, A. ; Tsujii, Fukuda, T.
    • Journal Title

      Polymer 49

      Pages: 5177-5185

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Transfer Catalyzed Polymerizations (RTCPs) of Styrene and Methyl Methacrylate wit Phosphorus Catalysts2008

    • Author(s)
      Goto, A.; Hirai, N.; Tsujii, Y.; Fukuda, T.
    • Journal Title

      Macromol. Symp. 261

      Pages: 18-22

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Substituent Effects of Radical-Mediated Organotellanyl Group Transfer Reactions. Optimization of Promoters for Highly Controlled Living Radical Polymerizations2008

    • Author(s)
      Kayahara, E.; Yamago, S.; Kwak, Y.; Goto, A.; Fukuda, T.
    • Journal Title

      Macromolecules 41

      Pages: 527-529

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Living Radical Polymerizations with Germanium, Tin. and Phosphorus Catalysts - Reversible Chain Transfer Catalyzed Polymerizations (RTCPs)2007

    • Author(s)
      A. Goto, H. Zushi, N. Hirai, T. Wakada, Y. Tsujii, T. Fukuda
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 13347-13354

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photolysis of an Alkoxyamine Using Intramolecular Energy Transfer from a Quinoline Antenna - Towards Photo-Induced Living Radical Polymerization2007

    • Author(s)
      A. Goto, J. C. Scaiano, L. Maretti
    • Journal Title

      Photochem. Photobio. Sci. 6

      Pages: 833-835

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Germanium- and Tin-Catalyzed Living Radical Polymerizations of Styrene and Methacrylates2007

    • Author(s)
      Goto, A.; Zushi, H.; Hirai, N.; Wakada, T.; Kwak, Y.; Fukuda, T.
    • Journal Title

      Macromol. Symp. 248

      Pages: 126-131

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Size-Exclusion Effect and Protein Repellency of Concentrated Polymer Brushes Prepared by Surface-Initiated Living Radical Polymerization2007

    • Author(s)
      Yoshikawa, C.; Goto, A.; Ishizuka, N.; Nakanishi, K.; Kishida, A.; Tsujii, Y.; Fukuda, T.
    • Journal Title

      Macromol. Symp. 248

      Pages: 189-198

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photolysis of an Alkoxyamine Using Intramolecular Energy Transfer from a Quinoline Antenna - Towards Photo-Induced Living Radical Polymerization2007

    • Author(s)
      Goto, A.; Scaiano, J. C.; Maretti, L.
    • Journal Title

      Photochem. Photobio. Sci. 6

      Pages: 833-835

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface Interaction of Well-Defined, Concentrated Poly (2-hydroxyethyl methacrylate) Brushes with Proteins2007

    • Author(s)
      Yoshikawa, C.; Goto, A.; Tsujii, Y.; Ishizuka, N.; Nakanishi, K.; Fukuda, T.
    • Journal Title

      J. Polym. Sci. Part A, Polym. Chem. 45

      Pages: 4795-4803

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Living Radical Polymerizations with Germanium, Tin, and Phosphorus Catalysts - Reversible Chain Transfer Catalyzed Polymerizations (RTCPs)2007

    • Author(s)
      Goto, A.; Zushi, H.; Hirai, N.; Wakada, T.; Tsujii, Y.; Fukuda, T.
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 13347-13354

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Reversible Chain-Transfer Catalyzed Polymerizations (RTCPs) with Ge, Sn, P, N, and O Catalysts2009

    • Author(s)
      A. Goto, Y. Tsujii, T. Fukuda
    • Organizer
      Materials of the Future, Science of Today : Radical Polymerization - The Next Stage
    • Place of Presentation
      豪国Victoria州Melbourne(招待)
    • Year and Date
      2009-02-17
    • Related Report
      2008 Final Research Report
  • [Presentation] Reversible Chain-Transfer Catalyzed Polymerizations (RTCPs) with Ge, Sn, P, N, and 0 Catalysts2009

    • Author(s)
      Atsushi Goto
    • Organizer
      Materials of the Future, Science of Today : Radical Polymerization - The Next Stage
    • Place of Presentation
      豪国Melbourne
    • Year and Date
      2009-02-17
    • Related Report
      2008 Annual Research Report
  • [Presentation] アルコールおよび炭化水素を触媒とするリビングラジカル重合-可逆移動触媒重合2008

    • Author(s)
      長澤浩司、後藤淳、辻井敬亘、福田猛
    • Organizer
      第57回高分子学会討論会
    • Place of Presentation
      大阪市立大学(大阪)
    • Year and Date
      2008-09-25
    • Related Report
      2008 Final Research Report
  • [Presentation] アルコールおよび炭化水素を触媒とするリビングラジカル重合-可逆移動触媒重合2008

    • Author(s)
      長澤浩司、後藤淳、辻井敬亘、福田猛
    • Organizer
      第57回高分子学会討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] Reversible Chain Transfer Catalyzed Polymerization (RTCP) : A New Family of Living Radical Polymerization with Germanium, Tin, Phosphorus, and Nitrogen Compound Catalysis2008

    • Author(s)
      A. Goto, Y. Tsujii, T. Fukuda
    • Organizer
      236th American Chemical Society National Meeting
    • Place of Presentation
      米国Pennsylvania州 Philadelphia
    • Year and Date
      2008-08-17
    • Related Report
      2008 Final Research Report
  • [Presentation] Reversible Chain Transfer Catalyzed Polymerization (RTCP) : A New Family of Living Radical Polymerization with Germanium, Tin, Phosphorus, and Nitrogen Compound Catalysis2008

    • Author(s)
      Atsushi Goto, Yoshinobu Tsujii, Takeshi Fukuda
    • Organizer
      236th American Chemical Society National Meeting
    • Place of Presentation
      米国Philadelphia
    • Year and Date
      2008-08-17
    • Related Report
      2008 Annual Research Report
  • [Presentation] 典型元素を触媒として利用する新しい型のリビングラジカル重合-可逆移動触媒重合-の開発2008

    • Author(s)
      後藤淳
    • Organizer
      第54回高分子学会高分子研究発表会(ヤングサイエンティスト講演・講演賞)
    • Place of Presentation
      兵庫県中央労働センター(神戸)
    • Year and Date
      2008-07-18
    • Related Report
      2008 Final Research Report
  • [Presentation] 典型元素を触媒として利用する新しい型のリビングラジカル重合-可逆移動触媒重合-の開発2008

    • Author(s)
      後藤淳
    • Organizer
      第54回高分子学会高分子研究発表会
    • Place of Presentation
      神戸
    • Year and Date
      2008-07-18
    • Related Report
      2008 Annual Research Report
  • [Presentation] 窒素化合物を触媒として用いたリビングラジカル重合-可逆移動触媒重合2008

    • Author(s)
      後藤淳、平井規晋、若田務、辻井敬亘、福田猛
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜(横浜)
    • Year and Date
      2008-05-28
    • Related Report
      2008 Final Research Report
  • [Presentation] 窒素化合物を触媒として用いたリビンクラジカル重合-可逆移動触媒重合2008

    • Author(s)
      後藤淳、平井規晋、若田務、辻井敬亘、福田猛
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2008-05-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] ゲルマニウムおよびリン化合物を触媒として用いた新しいリビングラジカル重合2007

    • Author(s)
      後藤淳、平井規晋、若田務、辻井敬亘、福田猛
    • Organizer
      第56回高分子学会討論会
    • Place of Presentation
      名古屋工業大学(名古屋)
    • Year and Date
      2007-09-19
    • Related Report
      2008 Final Research Report
  • [Presentation] ゲルマニウムおよびリン化合物を触媒として用いたリビングラジカル重合の反応速度論的研究2007

    • Author(s)
      若田務、後藤淳、辻井敬亘、福田猛
    • Organizer
      第56回高分子学会討論会
    • Place of Presentation
      名古屋工業大学(名古屋)
    • Year and Date
      2007-09-19
    • Related Report
      2008 Final Research Report
  • [Presentation] ゲルマニウムおよびリン化合物を触媒として用いた新しいリビングラジカル重合2007

    • Author(s)
      後藤淳、平井規晋、若田務、辻井敬亘、福田猛
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] リン化合物を用いたリビングラジカル重合2007

    • Author(s)
      平井規晋、後藤淳、辻井敬亘、福田猛
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] ゲルマニウムおよびリン化合物を触媒として用いたリビングラジカル重合の反応速度論的研究2007

    • Author(s)
      若田務、後藤淳、辻井敬亘、福田猛
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] Germanium-, Tin-, and Phosphorus-Catalyzed Living Radical Polymerizations of Styrene and Methacrylates2007

    • Author(s)
      A. Goto, N. Hirai, T. Wakada, H. Zushi, Y. Tsujii, T. Fukuda
    • Organizer
      ICRIS'07
    • Place of Presentation
      京都大学(京都)
    • Year and Date
      2007-06-12
    • Related Report
      2008 Final Research Report
  • [Presentation] Germanium-, Tin-, and Phosphorus-Catalyzed Living Radical Polymerization of Styrene and Methacrylatess2007

    • Author(s)
      Goto, A.; Hirai, N.; Wakada, T.; Zushi, H.; Tsujii, Y.; Fukuda, T.
    • Organizer
      Institute for Chemical Research InternationalSymposium (ICRIS'07)
    • Place of Presentation
      京都
    • Year and Date
      2007-06-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] ゲルマニウムおよびリンを触謀として用いたリビングラジカル重合2007

    • Author(s)
      平井規晋、後藤淳、福田猛
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      京都
    • Year and Date
      2007-05-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] ゲルマニウムを触媒として用いたリビングラジカル重合の反応速度論的研究2007

    • Author(s)
      若田務、後藤淳、福田猛
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      京都
    • Year and Date
      2007-05-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] Germanium-, Tin-, and Phosphorus-Catalyzed Living Radical Polymerizations of Styrene and Methacrylates2007

    • Author(s)
      A. Goto, Y. Tsujii, T. Fukuda
    • Organizer
      Hangzhou International Polymer Forum
    • Place of Presentation
      中国浙江省Hangzhou(招待)
    • Year and Date
      2007-05-13
    • Related Report
      2008 Final Research Report
  • [Presentation] Germanium-, Tin-, and Phosphorus-Catalyzed Living Radical Polymerizations of Styrene and Methacrylates2007

    • Author(s)
      Goto, A.; Fukuda, T.
    • Organizer
      Hangzhou International Polymer Forum
    • Place of Presentation
      Hangzhou (中国)
    • Year and Date
      2007-05-13
    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] アルコールを触媒として用いた新規リビングラジカル重合法2009

    • Inventor(s)
      後藤淳、福田猛、辻井敬亘
    • Industrial Property Rights Holder
      国立大学法人京都大学
    • Filing Date
      2009-02-06
    • Related Report
      2008 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] アルコールを触媒として用いた新規リビングラジカル重合法2009

    • Inventor(s)
      後藤淳、福田猛、辻井敬亘
    • Industrial Property Rights Holder
      国立大学法人京都大学
    • Filing Date
      2009-02-06
    • Related Report
      2008 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] アルコールを触媒として用いた新規リビングラジカル重合法2008

    • Inventor(s)
      後藤淳、福田猛、辻井敬亘
    • Industrial Property Rights Holder
      国立大学法人京都大学
    • Industrial Property Number
      2008-123817
    • Filing Date
      2008-05-09
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Patent(Industrial Property Rights)] リン化合物または窒素化合物を触媒として用いた新規リビングラジカル重合法2008

    • Inventor(s)
      後藤淳、福田猛、辻井敬亘
    • Industrial Property Rights Holder
      国立大学法人京都大学
    • Filing Date
      2008-05-02
    • Related Report
      2008 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] リン化合物または窒素化合物を触媒として用いた新規リビングラジカル重合法2008

    • Inventor(s)
      後藤淳、福田猛、辻井敬亘
    • Industrial Property Rights Holder
      国立大学法人京都大学
    • Filing Date
      2008-05-02
    • Related Report
      2008 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] リン化合物を触媒として用いた新規リビングラジカル重合法2007

    • Inventor(s)
      後藤淳、福田猛、辻井敬亘
    • Industrial Property Rights Holder
      国立大学法人京都大学
    • Industrial Property Number
      2007-125099
    • Filing Date
      2007-05-09
    • Related Report
      2008 Final Research Report
  • [Patent(Industrial Property Rights)] リン化合物を触媒として用いた新規なリビングラジカル法2007

    • Inventor(s)
      後藤淳、福田猛、辻井敬亘
    • Industrial Property Rights Holder
      国立大学法人京都大学
    • Industrial Property Number
      2007-125099
    • Filing Date
      2007-05-09
    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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