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Construction of Functional Supramolecular Hybrids Using Macrocyclic Host Molecules

Research Project

Project/Area Number 19750110
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionKanazawa University

Principal Investigator

OGOSHI Tomoki  Kanazawa University, 物質化学系, 助教 (00447682)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,790,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥390,000)
Fiscal Year 2008: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2007: ¥2,100,000 (Direct Cost: ¥2,100,000)
KeywordsSWNT / CD / カリックスアレーン / ククルビツリル / ホスト-ゲスト包接錯体 / ナノ材料 / カーボンナノチューブ / シクロデキストリン / 超分子化学 / 環状化合物 / ホストーゲスト包接錯体
Research Abstract

環状ホスト分子であるシクロデキストリン(CD)を用いて単層カーボンナノチューブ(SWNT)の可溶化を行った。CDのみ、もしくはゲスト分子のみでは、SWNTを溶解させることができなかったが、CD-ゲスト包接錯体を用いた場合、SWNTを可溶化できることが分かった。また、ククルビツリル、水溶性カリックスアレーン、ピレン基を導入したCD誘導体を利用し、SWNTの周りに環状ホスト分子を導入した超分子複合体を得ることにも成功した。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (33 results)

All 2009 2008 2007 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (7 results) Book (4 results) Remarks (2 results)

  • [Journal Article] Columnar Stacks of Starand Tadpole-Shaped Polyoxazolines Having Triphenylene Moiety and Their Applications for Synthesis of Wire-Assembled Gold Nanoparticles2009

    • Author(s)
      Ogoshi, T.; Hiramitsu, S.; Yamagishi, T.; Nakamoto, Y.
    • Journal Title

      Macromolecules (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Solubilization of Single-Walled Carbon Nanotubes by Entanglements between Them and Hyperbranched Phenolic Polymer2009

    • Author(s)
      Ogoshi, T.; Saito, T.; Yamagishi, T.; Nakamoto, Y.
    • Journal Title

      Carbon 47

      Pages: 117-123

    • NAID

      120001008418

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Solubilization of Single-Walled Carbon Nanotubes by Entanglements between Them and Hyperbranched Phenolic Polymer2009

    • Author(s)
      生越友樹、斉藤貴之、山岸忠明、中本義章
    • Journal Title

      Carbon 47

      Pages: 117-123

    • NAID

      120001008418

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Columnar Stacks of Star- and Tadpote-Shaped Polyoxazolines Having Triphenylene Moiety and Their Applications for Synthesis of Wire-Assembled Gold Nanoparticles2009

    • Author(s)
      生越友樹、平光さち、山岸忠朋、中本義章
    • Journal Title

      Macromolecules (印刷中)(掲載確定)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Green Polymerization of Phenol in Ionic Liquids2008

    • Author(s)
      Ogoshi, T.; Onodera, T.; Yamagishi, T.; Nakamoto, Y.
    • Journal Title

      Macromolecules 41

      Pages: 8533-8536

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of Water-Solubility of Single-Walled Carbon Nanotubes by Formation of Host-Guest Complexes of Cyclodextrins with Various Guest Molecules2008

    • Author(s)
      Ogoshi, T.; Ikeya, M.; Yamagishi, T.; Nakamoto, Y.; Harada, A.
    • Journal Title

      J. Phys. Chem. C 112

      Pages: 13079-13083

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Phenolic Polymer-Coated Gold Nanoparticles2008

    • Author(s)
      Ogoshi, T.; Umeda, K.; Yamagishi, T.; Nakamoto, Y.
    • Journal Title

      Polym. J. 40

      Pages: 942-943

    • NAID

      10024341843

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] para-Bridged Symmetrical Pillar[5]arenes: Their Lewis Acid-Catalyzed Synthesis and Host-Guest Property2008

    • Author(s)
      Ogoshi, T.; Kanai, S.; Fujinami, S.; Yamagishi, T.; Nakamoto, Y.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 5022-5023

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Defection-Selective Solubilization and Chemically-Responsive Solubility Switching of Single-Walled Carbon Nanotubes with Cucurbit[7]uril2008

    • Author(s)
      Ogoshi, T.; Inagaki, A.; Yamagishi, T.; Nakamoto, Y.
    • Journal Title

      Chem. Commun.

      Pages: 2245-2247

    • NAID

      120001130310

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Phenolic Polymer-Coated Gold Nanoparticles2008

    • Author(s)
      生越友樹、梅田謙治、山岸忠明、中本義章
    • Journal Title

      Polym. J. 40

      Pages: 942-943

    • NAID

      10024341843

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of Water-Solubility of Singlc-Walled Carbon Nanotubes by Formation of Host-Guest Complexes of Cyclodextrins with Various Guest Molecules2008

    • Author(s)
      生越友樹、池谷光博、山岸忠明、中本義章、原田明
    • Journal Title

      J. Phys. Chem. C 112

      Pages: 13079-13083

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemical Sensors Based on Cyclodextrin2008

    • Author(s)
      生越友樹、原田明
    • Journal Title

      Sensors 8

      Pages: 4961-4982

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Green Polymerization of Phenol in Ionic Liquids2008

    • Author(s)
      生越友樹、梅田謙治、山岸忠明、中本義章
    • Journal Title

      Macromolecules 41

      Pages: 8533-8536

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Single-Walled Carbon Nanotubes (SWCNTs) Network Polymer Made by Hybrids of SWCNTs and Water Soluble Calix[8]arenes2007

    • Author(s)
      Ogoshi, T.; Yamagishi, T.; Nakamoto, Y.
    • Journal Title

      Chem. Commun.

      Pages: 4776-4778

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Water Soluble Single-Walled Carbon Nanotubes Using Inclusion Complex of Cyclodextrin with an Adamantane Derivative2007

    • Author(s)
      Ogoshi, T.; Yamagishi, T.; Nakamoto, Y.; Harada, A.
    • Journal Title

      Chem. Lett. 36

      Pages: 1026-1027

    • NAID

      10019744294

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chemically-Responsive Sol-Gel Transition of Supramolecular Single-Walled Carbon Nanotubes (SWNTs) Hydrogel Made by Hybrids of SWNTs and Cyclodextrins (CDs)2007

    • Author(s)
      Ogoshi, T.; Takashima, Y.; Yamaguchi, H.; Harada, A.
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 4878-4879

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Single-walled Carbon Nanotubes (SWCNTs) Network Polymer Made by Hybrids of SWCNTs and Water SolubleCalix[8]arenes2007

    • Author(s)
      生越 友樹
    • Journal Title

      Chem. Commun.

      Pages: 4776-4778

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Water Soluble Single-walled Carbon Nanotubes Using Inclusion Complex of Cyclodextrin with an Adamantane Derivative2007

    • Author(s)
      生越 友樹
    • Journal Title

      Chem. Lett. 36

      Pages: 1026-1027

    • NAID

      10019744294

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Defection-Selective Solubilization and Chemically-Responsive Solubility Switching of Single-Walled Carbon Nanotubes with Cucurbit[7]uril

    • Author(s)
      生越 友樹
    • Journal Title

      Chem. Commun. (印刷中)

    • NAID

      120001130310

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] para-Bridged Symmetrical Pillar[5]arenes: Their Lewis Acid-Catalyzed Synthesis and Host-Guest Property

    • Author(s)
      生越 友樹
    • Journal Title

      J. Am. Chem. Soc. (印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] 環状ホスト分子を利用した単層カーボンナノチューブ超分子材料の創成2009

    • Author(s)
      生越 友樹
    • Organizer
      第89会春季日本化学会年会(若い世代の特別講演会)
    • Place of Presentation
      千葉・船橋市
    • Year and Date
      2009-03-28
    • Related Report
      2008 Final Research Report
  • [Presentation] 環状ホスト分子を利用した単層カーボンナノチューブ超分子材料の創成2009

    • Author(s)
      生越友樹
    • Organizer
      第89会春季日本化学会年会
    • Place of Presentation
      千葉・船橋市
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Synthesis and Host-Guest Property of para-Bridged "Pillar[5]arene"2008

    • Author(s)
      Ogoshi, T.; Kanai, S.; Fujinami, S.; Yamagishi, T.; Nakamoto, Y.
    • Organizer
      LXII Yamada Conference 2008
    • Place of Presentation
      兵庫・淡路島
    • Year and Date
      2008-09-03
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Enhancement of Water-Solubility of Single-Walled Carbon Nanotubes by Formation of Host-Guest Complexes of Cyclodextrins with Various Guest Molecules2008

    • Author(s)
      Ogoshi, T.; Ikeya, M.; Yamagishi, T.; Nakamoto, Y.; Harada, A.
    • Organizer
      14th International Cyclodextrins Symposium
    • Place of Presentation
      京都・京都市
    • Year and Date
      2008-05-10
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] ホスト分子被覆π共役高分子・超分子の創成2007

    • Author(s)
      生越 友樹
    • Organizer
      平成19年度北陸地区高分子若手研究会(若手招待講演)
    • Place of Presentation
      富山・富山市
    • Year and Date
      2007-11-16
    • Related Report
      2008 Final Research Report
  • [Presentation] Chemistry-Responsive Sol-Gel Transition of Supramolecular Single-Walled Carbon Nanotubes (SWNTs) Hydrogel Made by Hybrids of SWNTs-Cyclodextrins Hybrids2007

    • Author(s)
      Ogoshi, T.; Yamagishi, T.; Nakamoto, Y.; Harada, A.
    • Organizer
      2nd International Symposium on Macrocyclic and Supramolecular Chemistry
    • Place of Presentation
      イタリア・Salice Terme
    • Year and Date
      2007-06-26
    • Related Report
      2008 Final Research Report
  • [Presentation] Chemically-Responsive Sol-Gel Transition of Supramolecular Single-Walled Carbon Nanotubes (SWNTs) Hydrogel Made by SWNTs-Cyclodextrins Hybrids2007

    • Author(s)
      生越 友樹
    • Organizer
      2nd International Symposium on Macrocyclic and Supramolecular Chemistry
    • Place of Presentation
      イタリア、Salice Terme
    • Year and Date
      2007-06-26
    • Related Report
      2007 Annual Research Report
  • [Book] 環状ホスト分子を利用したカーボンナノチューブ超分子材料の創成, カーボンナノチューブの表面処理・分散処理技術(分担執筆)2009

    • Author(s)
      生越 友樹、山岸 忠明、中本 義章、原田 明
    • Publisher
      (掲載確定)
    • Related Report
      2008 Final Research Report
  • [Book] 藻状ホスト分子を利用した単層カーボンナノチューブ超分子材料の創成2009

    • Author(s)
      生越友樹
    • Publisher
      技術情報協会(印刷中)掲載確定)
    • Related Report
      2008 Annual Research Report
  • [Book] 環状ホスト分子を利用したカーボンナノチューブの可溶化と応用、有機分散系の分散・凝集技術(分担執筆)2008

    • Author(s)
      生越 友樹、山岸 忠明、中本 義章、原田 明
    • Related Report
      2008 Final Research Report
  • [Book] 環状ホスト分子を利用した単層カーボンナノチューブの可溶化と応用2008

    • Author(s)
      生越友樹
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Annual Research Report
  • [Remarks] ホームページアドレス

    • URL

      http://kohka.ch.t.kanazawa-u.ac.jp/lab3/lab3.html

    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://kohka.ch.t.kanazawa-u.ac.jp/lab3/lab3.html

    • Related Report
      2008 Annual Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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