• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Dynamics of photophysical properties in organic solid material depending on molecular arrangements

Research Project

Project/Area Number 19750114
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionOsaka University

Principal Investigator

TOHNAI Norimitsu  Osaka University, 大学院工学研究科, 准教授 (30346184)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,560,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2007: ¥2,000,000 (Direct Cost: ¥2,000,000)
Keywords光物性 / 結晶工学 / 超分子化学 / 包接化学 / 発光物性 / 自己組織化 / π系分子 / 単結晶X線構造解析 / 有機塩 / 分子集合 / 発光変調材料 / 包接ホスト / 単結晶X線構造析
Research Abstract

本研究では多環式芳香族などのπ系分子を超分子化し、様々な分子集合に応じた発光物性の変化を解き明かす「自己組織化に基づくπ系分子の配列制御と、有機固体発光ダイナミクスの解明」を目指している。結晶状態において化学・物理情報によりその分子集合をプログラムに沿って変化させ、ダイナミックに発光挙動を変調する発光材料の創製と固相状態における発光挙動とその分子集合・分子配列の相関を明らかとし、固体状態における発光化学を系統的に解き明かすことができた。得られた物質について光物性、熱物性などの物理物性の観察を行い、計算化学的手法を用いて物理物性と構造の相関について検討した。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (46 results)

All 2009 2008 2007 Other

All Journal Article (34 results) (of which Peer Reviewed: 34 results) Presentation (9 results) Book (3 results)

  • [Journal Article] Systematic Investigation of Molecular Arrangements and Solid-State Fluorescence Properties by Using Organic Salts of Anthracene-2,6-disulfonic Acid with Aliphatic Primary Amines2009

    • Author(s)
      Y. Mizobe, T. Hinoue, A. Yamamoto, I. Hisaki, M. Miyata, Y. Hasegawa, N. Tohnai
    • Journal Title

      Chem. Eur. J. (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of steric complementarity on solid-state optical properties of ternary CT complexes ; BPDS, aliphatic amines and TCNQ2009

    • Author(s)
      N. Tohnai, M. Kurata, H. Nakajima, A. Yamamoto, T. Hinoue, Y. Mizobe, I. Hisaki, M. Miyata
    • Journal Title

      J. Phys. Chem. C (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Octadehydrodibenzo[12]annulene-Based Organogels : Substituted Two Methyl Ester Groups Prevent Crystallization and Promote Gelation2009

    • Author(s)
      I. Hisaki, H. Shigemitsu, Y. Sakamoto, Y. Hasegawa, Y. Okajima, K. Nakano, N. Tohnai, M. Miyata
    • Journal Title

      Angew. Chem. Int. Ed. (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structures of Brucinium Cholate : Bile Acid and Strychnine Derivatives Meet in the Crystals2009

    • Author(s)
      I. Hisaki, N. Shizuki, K. Aburaya, M. Katsuta, N. Tohnai, M. Miyata
    • Journal Title

      Cryst. Grwoth Des. 9

      Pages: 1280-1283

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Transformation and Fluorescence Modulation in Polymorphic Crystals of n-Butylammonium 2-Naphthalenesulfonate2009

    • Author(s)
      A. Yamamoto, M. Matsumoto, T. Hinoue, Y. Mizobe, I. Hisaki, M. Miyata, N. Tohnai
    • Journal Title

      Synthetic Metals. (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Conformational Polymorphism of Octadehydrodibenzo-[12]annulene with Methyl Phthalate Moieties2009

    • Author(s)
      I. Hisaki, Y. Sakamoto, H. Shigemitsu, N. Tohnai, M. Miyata
    • Journal Title

      Cryst. Growth Des. 9

      Pages: 414-420

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Solid Solutions with Steric Complementary Pairing from the Binary Mixtures of 1-Naphthylmethylammonium Alkanoates2009

    • Author(s)
      Katsunari Inoue
    • Journal Title

      Cryst. Growth Des 9

      Pages: 1072-1076

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conformational Polymorphism of Octadehydrodibenzo-[12] annulene with Methyl Phthalate Moieties2009

    • Author(s)
      Ichiro Hisaki
    • Journal Title

      Cryst Growth Des 9

      Pages: 414-420

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Efficient Enantioresolution of 2,2-Dimethyl-3-hexanol with Cholamide Crystals on the Basis of Intercalation and Bilayer Inversion2008

    • Author(s)
      K. Aburaya, T. Murai, I. Hisaki, N. Tohnai, M. Miyata
    • Journal Title

      Chem. Lett. 37

      Pages: 1224-1225

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Modulation of Solid-state Luminescence Quantum Efficiency Based on CH-O Intermolecular Interaction2008

    • Author(s)
      T. Hinoue, Y. Mizobe, I. Hisaki, M. Miyata N. Tohnai
    • Journal Title

      Chem. Lett. 37

      Pages: 642-643

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Superstructure-Dependent Optical and Electrical Properties of Unusual Face-to-Face pi-Stacked One-Dimensional Assembly of Dehydrobenzo[12]annulene in Crystalline State2008

    • Author(s)
      I. Hisaki, Y. Sakamoto, H. Shigemitsu, N. Tohnai, M. Miyata, S. Seki, A. Saeki, S. Tagawa
    • Journal Title

      Chem. Eur. J. 14

      Pages: 4178-4187

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Topological Classification and Supramolecular Chirality of 21-Helical Ladder-type Hydrogen-Bond Networks Composed of Primary Ammonium Carboxylates : Bundle Controls in 21-Helical Assemblies2008

    • Author(s)
      T. Yuge, T. Sakai, N. Kai, I. Hisaki, M. Miyata, N. Tohnai
    • Journal Title

      Chem. Eur. J. 14

      Pages: 2984-2993

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Importance of Weak Hydrogen bonds in the Formation of Cholamide Inclusion Crystals with Aromatic Guests2008

    • Author(s)
      K. Aburaya, K. Nakano, K. Sada, N. Yoswathananont, M. Shigesato, I., Hisaki, N. Tohnai, M. Miyata
    • Journal Title

      Cryst. Growth Des. 8

      Pages: 1013-1022

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Guest-Induced Topological Polymorphism of Pseudo-Cubic Hydrogen Bond Networks - Robust and Adaptable Supramolecular Synthon2008

    • Author(s)
      T. Yuge, I. Hisaki, M. Miyata, N. Tohnai
    • Journal Title

      CrystEngComm 10

      Pages: 263-266

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Tilt Chirality in Crystals of Steroids and Alkaloids2008

    • Author(s)
      I. Hisaki, N. Tohnai, M. Miyata
    • Journal Title

      Chirality 20

      Pages: 330-336

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Topological Classification and Supramolecular Chirality of 21-Helical Ladder-type Hydrogen-Bond Networks Composed of Primary Ammoniurn Carboxylates : Bundle Controls in 21-Helical Assemblies2008

    • Author(s)
      Tetsuharu Yuge
    • Journal Title

      Chem. Eur J 14

      Pages: 2984-2993

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Superstructure-Dependent Optical and Electrical Properties of Unusual Face-to-Face pi-Stacked One-Dimensional Assembly of Dehydrobenzo [12] annulene in Crystalline State2008

    • Author(s)
      Ichiro Hisaki
    • Journal Title

      Chem. Eur. J 14

      Pages: 4178-4187

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Importance of Weak Hydrogen bonds in the Formation of Cholamide Inclusion Crystals with Aromatic Guests2008

    • Author(s)
      Kazuaki Aburaya
    • Journal Title

      Cryst. Growth Des 8

      Pages: 1013-1022

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Guest-Induced Topological Polymorphism of Pseudo-Cubic Hydrogen Bond Networks - Robust and Adaptable Supramolecular Synthon2008

    • Author(s)
      Tetsuharu Yuge
    • Journal Title

      Cryst Eng Comm 10

      Pages: 263-266

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Modulation of Solid-state Luminescence Quantum Efficiency Based on CH-O Intermolecular Interaction2008

    • Author(s)
      Tomoaki Hinoue
    • Journal Title

      Chem. Lett 37

      Pages: 642-643

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Topologically Different Two Pseudo-Decahedral Hydrogen Bond Networks Composed of Triphenylmethylammonium Phosphonates2007

    • Author(s)
      T. Yuge, N. Kai, I. Hisaki, M. Miyata, N. Tohnai
    • Journal Title

      Chem. Lett. 36

      Pages: 1390-1391

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dependence of the Enantioselectivity on Reversion of Layer Directions in Cholamide Inclusion Compounds2007

    • Author(s)
      K. Aburaya, I. Hisaki, N. Tohnai, M. Miyata
    • Journal Title

      Chem. Commun.

      Pages: 4257-4259

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Chirality in Crystalline Assemblies of Bile Acids and Their Derivatives ; Three-Axial, Tilt, Helical, and Bundle Chirality2007

    • Author(s)
      M. Miyata, N. Tohnai, I. Hisaki
    • Journal Title

      Molecules 12

      Pages: 1973-2000

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystalline Host-guest Assemblies of Steroidal and Related Molecules : Diversity, Hierarchy and Supramolecular Chirality2007

    • Author(s)
      M. Miyata, N. Tohnai, I. Hisaki
    • Journal Title

      Acc. Chem. Res. 40

      Pages: 694-702

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Topological Study of Pseudo-Cubic Hydrogen Bond Networks in a Binary System Composed of Primary Ammonium Carboxylates : An Analogue of Ice Cube2007

    • Author(s)
      T. Yuge, N. Tohnai, T. Fukuda, I. Hisaki, M. Miyata
    • Journal Title

      Chem. Eur J 13

      Pages: 4163-4168

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Guest-dependent Distinct Changes in Arrangements of Anthracene and the Corresponding Fluorescence Characteristics in Ternary System : Transcription and Translation of Guest Molecular Information2007

    • Author(s)
      Y. Mizobe, T. Hinoue, M. Miyata, I. Hisaki, Y. Hasegawa, N. Tohnai
    • Journal Title

      Bull. Chem. Soc. Jpn. 80

      Pages: 1162-1172

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Well-Designed Supramolecular Clusters Comprising Triphenylmethylamine and Various Sulfonic Acids.2007

    • Author(s)
      N. Tohnai, Y. Mizobe, M. Doi, S. Sukata, T. Hinoue, T. Yuge, I. Hisaki, Y. Matsukawa, M. Miyata
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 2220-2223

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Topologically Different Two Pseudo-Decahedral Hydrogen Bond Networks Composed of Triphenylmethylammonium Phosphonates2007

    • Author(s)
      Tetsuharu Yuge
    • Journal Title

      Chem. Lett 36

      Pages: 1390-1391

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dependence of the Enantionselectivity on Reversion of Layer Directions in Cholamide Inclusion Compounds2007

    • Author(s)
      Kazuaki Aburaya,
    • Journal Title

      Chem. Commun

      Pages: 4257-4259

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Guest-dependent Distinct Changes in Arrangements of Anthracene and the Corresponding Fluorescence Characteristics in Ternary System: Transcription and Translation of Guest Molecular Information2007

    • Author(s)
      Yuji Mizobe
    • Journal Title

      Bull. Chem. Soc. Jpn., 80

      Pages: 1162-1172

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Topological Study of Pseudo-Cubic Hydrogen Bond Networks in a Binary System Composed of Primary Ammonium Carboxylates. An Analogue of Ice Cube2007

    • Author(s)
      Tetsuhary Yuge
    • Journal Title

      Chem. Eur J, 13

      Pages: 4163-4168

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Transformation and Fluorescence Modulation in Polymorphic Crystals of n-Butylammonium 2-Naphthalenesulfonate

    • Author(s)
      Atsushi Yamamoto
    • Journal Title

      Synthetic Metals (in press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Topological Classification and Supramolecular Ghirality of 21-Helical Ladder-type Hydrogen-Bond Networks Composed of Primary Ammonium Carboxylates: Bundle Controls in 21-Helical Assemblies

    • Author(s)
      Tetsuharu Yuge
    • Journal Title

      Chem. Eur. J. in press

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Guest-Induced Topological Polymorphism of Pseudo-Cubic Hydrogen Bond Networks - Robust and Adaptable Supramoleculat Synthon

    • Author(s)
      Tetsuharu Yuge
    • Journal Title

      CrystEngComm in press

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] アントラセンジスルホン酸アンモニウム塩とTCNBからなる非共有結合性分子集合体の構造制御とそれに起因する光電気物性2008

    • Author(s)
      中島裕美・藤内謙光・久木一朗・宮田幹二
    • Organizer
      高分子討論会
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] 水素結合性クラスターの連結による高次超分子構造体の構築と機能化2008

    • Author(s)
      藤内謙光・久木一朗・宮田幹二
    • Organizer
      高分子討論会
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2008-09-23
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] アントラセンジスルホン酸アンモニウム塩とTCNBからなる電荷移動錯体の積層様式の異なる結晶構造に起因した固体発光挙動2008

    • Author(s)
      中島裕美・藤内謙光・久木一朗・宮田幹二
    • Organizer
      光化学討論会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2008-09-13
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Tunable solid-state luminescent colors based on molecular arrangements of ammonium anthracenedisulfonates2008

    • Author(s)
      Tomoaki Hinoue, Norimitsu Tohnai, Ichiro Hisaki, Mikiji Miyata
    • Organizer
      Joint International Symposium on Macrocyclic & Supramolecular Chemistry
    • Place of Presentation
      Las Vegas, Nevada, USA
    • Year and Date
      2008-07-16
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] アントラセンジスルホン酸アンモニウム塩を用いた特異的配列に基づく多様な固体発光挙動2007

    • Author(s)
      樋上友亮・藤内謙光・久木一朗・宮田幹二
    • Organizer
      光化学討論会
    • Place of Presentation
      信州大学
    • Year and Date
      2007-09-28
    • Related Report
      2008 Final Research Report
  • [Presentation] アットラセッジスルホゾ酸アンモニウム塩を用いた特異的配列に基づく多様な固体発光挙動2007

    • Author(s)
      樋上友亮
    • Organizer
      光化学討論会
    • Place of Presentation
      信州大学
    • Year and Date
      2007-09-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] Creation of the Supramolecular Chirality in [4+4] Cubic Ion-Pair Cluster2007

    • Author(s)
      Norimitsu Tohnai, Ichiro Hisaki, Mikiji Miyata
    • Organizer
      International Conference Chirality at the Nanoscale
    • Place of Presentation
      シッチェス・スペイン
    • Year and Date
      2007-09-18
    • Related Report
      2008 Final Research Report
  • [Presentation] Creation of the Supramolecular Chirality in [4+4] Cubic Ion-Pair Cluster2007

    • Author(s)
      Norimitsu Tohnai
    • Organizer
      International Conference Chirality at the Nanoscale
    • Place of Presentation
      シッチェス.スペイン
    • Year and Date
      2007-09-18
    • Related Report
      2007 Annual Research Report
  • [Presentation] ビフェニルアントラセン誘導体のゲスト依存的蛍光変調と動的挙動2007

    • Author(s)
      藤内謙光
    • Organizer
      有機結晶シンポジウム
    • Place of Presentation
      千葉大学
    • Year and Date
      2007-09-07
    • Related Report
      2008 Final Research Report 2007 Annual Research Report
  • [Book] 「次世代共役ポリマーの超階層制御と革新機能」超分子ポリマーの階層的構築および機能性ナノ空間に基づく革新的機能の創出と応用展開2009

    • Author(s)
      藤内謙光
    • Total Pages
      7
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Annual Research Report
  • [Book] Bottom-Up Nanofabrication」 Inclusion Compounds of Steroidal Molecules : Molecular Information and Their Expression Through Molecular Assemblie2009

    • Author(s)
      藤内謙光
    • Total Pages
      24
    • Publisher
      Amer, Sci. Pub
    • Related Report
      2008 Annual Research Report
  • [Book] 「次世代共役ポリマーの超階層制御と革新機能」超分子ポリマーの階層的構築および機能性ナノ空間に基づく革新的機能の創出と応用展開

    • Author(s)
      藤内謙光、久木一朗、宮田幹二
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Final Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi