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The formation of μ-TAS by electropolymerization of conducting polymer into porous silicon

Research Project

Project/Area Number 19850012
Research Category

Grant-in-Aid for Young Scientists (Start-up)

Allocation TypeSingle-year Grants
Research Field Functional materials/Devices
Research InstitutionKyoto University

Principal Investigator

FUKAMI Kazuhiro  Kyoto University, エネルギー理工学研究所, 助教 (60452322)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥2,747,000 (Direct Cost: ¥2,390,000、Indirect Cost: ¥357,000)
Fiscal Year 2008: ¥1,547,000 (Direct Cost: ¥1,190,000、Indirect Cost: ¥357,000)
Fiscal Year 2007: ¥1,200,000 (Direct Cost: ¥1,200,000)
Keywords多孔質シリコン / 導電性高分子 / 酵素 / 電析 / 陽極酸化 / 電解重合 / マイクロタス / テンプレート
Research Abstract

多孔質シリコンを電極として導電性高分子を電解重合により充填することにより、ポリピロールのナノファイバー、マイクロチューブの作製に成功した。シリコンの多孔質化と孔内へのポリピロールの電解重合を繰り返すことで、ポリピロール被服多孔質シリコンの多層膜作製に成功した。多孔質シリコン中に作製したポリピロール微細構造を電位印加により駆動するには裸の多孔質シリコン電極を金属で被覆する必要があることが分かり、水溶液中で比較的安定なCu, Pt, Au, Pdの電析を多孔質シリコン電極に行った。孔の形状や電解液の種類、印加電位等により析出する金属の形態を制御できることが明らかになった。Auで被覆した多孔質シリコンにグルコースオキシダーゼを固定化し、活性を測定すると平坦なAu電極上での応答に比べて3倍近い感度を示すことを明らかにした。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (27 results)

All 2009 2008 2007 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (13 results) Remarks (2 results)

  • [Journal Article] Electrodeposition behavior of noble metals in ordered macroporous silicon2009

    • Author(s)
      T. Matsumoto, K. Kobayashi, K. Fukami, T. Sakka, Y.H. Ogata
    • Journal Title

      Phys. Status Solidi C (印刷中)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multistep filling of porous silicon with conductive polymer by electropolymerization2009

    • Author(s)
      K. Fukami, T. Sakka, Y.H. Ogata, T. Yamauchi, N. Tsubokawa
    • Journal Title

      Phys. Status Solidi A 206

      Pages: 1259-1263

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Filling of mesoporous silicon with copper by electrodeposition from an aqueous solution2009

    • Author(s)
      K. Fukami, Y. Tanaka, M.L. Chourou, T. Sakka, Y.H. Ogata
    • Journal Title

      Electrochimica acta 54

      Pages: 2197-2202

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Filling of mesoporous silicon with copper by electrodeposition from an aqueous solution2009

    • Author(s)
      K. Fukami, Y. Tanaka, M. L. Chourou, T. Sakka, Y. H. Ogata
    • Journal Title

      Electrochimica acta 54

      Pages: 2197-2202

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multistep filling of porous silicon with conductive polymer by electropolymerization2009

    • Author(s)
      K. Fukami, T. Sakka, Y. H. Ogata, T. Yamauchi, N. Tsubokawa
    • Journal Title

      Physica Status Solidi A (in press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrodeposition behavior of noble metals in ordered macroporous silicon2009

    • Author(s)
      T. Matsumoto, K. Kobayashi, K. Fukami, T. Sakka, Y. H. Ogata
    • Journal Title

      Physica status Solidi C (in press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electro- deposition of noble metals into ordered macro- pores in p type silicon2008

    • Author(s)
      K. Fukami, K. Kobayashi, T. Matsumoto, Y.L. Kawamura, T. Sakka, Y.H. Ogata
    • Journal Title

      Journal of the Electro- chemical Society 155

      Pages: 443-448

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation mechanism of porous silicon with medium pores : the role of KMnO_42008

    • Author(s)
      K. Fukami, H. Kamakura, T. Sakka, Y.H. Ogata
    • Journal Title

      ECS Transactions 16

      Pages: 125-132

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fine-tuning in size and surface morphology of rod-shaped polypyrrole using porous silicon as template2008

    • Author(s)
      K. Fukami, F. A. Harraz, T. Yamauchi, T. Sakka and Y. H. Ogata
    • Journal Title

      Electro- chemistry Communications 10

      Pages: 56-60

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation mechanism of porous silicon with medium pores : the role of KMnO_42008

    • Author(s)
      K. Fukami, H. Kamakura, T. Sakka, Y. H. Ogata
    • Journal Title

      ECS Transactions 16

      Pages: 125-132

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrodeposition of noble metals into ordered macropores in p-type silicon2008

    • Author(s)
      K. Fukami, K. Kobayashi, T. Matsumoto, Y. L. Kawamura, T. Sakka, Y. H. Ogata
    • Journal Title

      Journal of the Electrochemical Society 155

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fine-tuning in size and surface morphology of rod-shaped polypyrrole using porous silicon as template2008

    • Author(s)
      K. Fukami, F. A. Harraz, T. Yamauchi, T. Sakka, Y. H. Ogata
    • Journal Title

      Electrochemistry Communications 10

      Pages: 56-60

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] シリコンに形成したメソ孔への水溶液からの銅の電析2008

    • Author(s)
      深見一弘, 田中祐輝, モハメドL. シュールー, 作花哲夫, 尾形幸生
    • Organizer
      第10回関西表面技術フォーラム
    • Place of Presentation
      甲南大学, 神戸市
    • Year and Date
      2008-12-02
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] 微細構造を有するシリコンを用いた高分子ゲルの表面構造制御2008

    • Author(s)
      高橋諭史, 山内健, 坪川紀夫, 深見一弘, 作花哲夫, 尾形幸生
    • Organizer
      平成20年北陸地区高分子若手研究会
    • Place of Presentation
      九頭竜, 福井市
    • Year and Date
      2008-11-14
    • Related Report
      2008 Final Research Report
  • [Presentation] 微細孔構造を有するシリコンを用いた高分子ゲルの表面構造制御2008

    • Author(s)
      高橋諭史, 山内健, 坪川紀夫, 深見一弘, 作花哲夫, 尾形幸生
    • Organizer
      平成20年北陸地区高分子若手研究会
    • Place of Presentation
      九頭竜, 福井市
    • Year and Date
      2008-11-14
    • Related Report
      2008 Annual Research Report
  • [Presentation] Formation mechanism of porous silicon with medium pores : the role of KMnO42008

    • Author(s)
      K. Fukami, H. Kamakura, T. Sakka, Y.H. Ogata
    • Organizer
      Pacific rim meeting on electrochemical and solid-state science
    • Place of Presentation
      ホノルル, アメリカ
    • Year and Date
      2008-10-14
    • Related Report
      2008 Final Research Report
  • [Presentation] Formation mechanism of porous silicon with medium pores : the role of KMnO_42008

    • Author(s)
      K. Fukami, H. Kamakura, T. Sakka, Y. H. Ogata
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-state Science
    • Place of Presentation
      ホノルル, ・アメリカ
    • Year and Date
      2008-10-14
    • Related Report
      2008 Annual Research Report
  • [Presentation] p型シリコンに形成したマクロ孔への貴金属電析における置換めっきの影響2008

    • Author(s)
      深見一弘, 松本翼, 小林克敏, 作花哲夫, 尾形幸生
    • Organizer
      表面技術協会第118回講演大会
    • Place of Presentation
      近畿大学, 東大阪市
    • Year and Date
      2008-09-02
    • Related Report
      2008 Final Research Report
  • [Presentation] p型シリコンに形成したマクロ孔への貴金属電析における置換めっきの影響2008

    • Author(s)
      深見一弘, 松本翼, 小林克敏, 作花哲夫, 尾形幸生
    • Organizer
      表面技術協会第118回公演大会
    • Place of Presentation
      近畿大学, 東大阪市
    • Year and Date
      2008-09-02
    • Related Report
      2008 Annual Research Report
  • [Presentation] 多孔質シリコンへのポリピロール電解重合による微細構造形成2008

    • Author(s)
      深見一弘, 作花哲夫, 尾形幸生, 山内健, 坪川紀夫
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨大学, 甲府市
    • Year and Date
      2008-03-31
    • Related Report
      2008 Final Research Report
  • [Presentation] 多孔質シリコンへのポリピロール電解重合による微細構造形成2008

    • Author(s)
      深見一弘, 作花哲夫, 尾形幸夫, 山内健, 坪川紀夫
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨大学,甲府市
    • Year and Date
      2008-03-31
    • Related Report
      2007 Annual Research Report
  • [Presentation] Tsubokawa, Filling of porous silicon with conductive polymer2008

    • Author(s)
      K. Fukami, T. Sakka, Y.H. Ogata, T. Yamauchi, N
    • Organizer
      The 6^<th> international conference of porous semiconductors-science and technology
    • Place of Presentation
      サ・コマ, スペイン
    • Year and Date
      2008-03-11
    • Related Report
      2008 Final Research Report
  • [Presentation] Filling of porous silicon with conductive polymer2008

    • Author(s)
      K. Fukami, T. Sakka, Y. H. Ogata, T. Yamauchi, N. Tsubokawa
    • Organizer
      The 6th International Conference of Porous Semic onductors-Science and Technology
    • Place of Presentation
      サ・コマ、スペイン
    • Year and Date
      2008-03-11
    • Related Report
      2007 Annual Research Report
  • [Presentation] 多孔質シリコンへのポリピロールの電解重合2007

    • Author(s)
      深見一弘, 作花哲夫, 尾形幸生, 山内健
    • Organizer
      第9回関西表面技術フォーラム
    • Place of Presentation
      近畿大学, 東大阪市
    • Year and Date
      2007-12-11
    • Related Report
      2008 Final Research Report
  • [Presentation] 多孔質シリコンへのポリピロールの電解重合2007

    • Author(s)
      深見一弘, 作花哲夫, 尾形幸夫, 山内健
    • Organizer
      第9回関西表面技術フォーラム
    • Place of Presentation
      近畿大学,東大阪市
    • Year and Date
      2007-12-11
    • Related Report
      2007 Annual Research Report
  • [Remarks] K. Fukami, Poster presentation award (V. Lehmann Award) in 6^<th> international conference of porous semiconductors science and technology

    • Related Report
      2008 Final Research Report
  • [Remarks] 深見一弘, 第10回関西表面技術フォーラム優秀講演賞

    • Related Report
      2008 Final Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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