| Project/Area Number |
19F19043
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| Research Category |
Grant-in-Aid for JSPS Fellows
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| Allocation Type | Single-year Grants |
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| Section | 外国 |
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| Review Section |
Basic Section 36020:Energy-related chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
POURNAGHSHBAND I ALI 京都大学, 高等研究院, 外国人特別研究員
POURNAGHSHBAND ISFAHANI ALI 京都大学, 高等研究院, 外国人特別研究員
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| Project Period (FY) |
2019-04-25 – 2021-03-31
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| Project Status |
Completed (Fiscal Year 2020)
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| Budget Amount *help |
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2020: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2019: ¥1,200,000 (Direct Cost: ¥1,200,000)
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| Keywords | Gas separation membrane / MXene / Graphene oxide / H2/CO2 separation / 2D materials / Molecular sieving |
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| Outline of Research at the Start |
1- Synthesis of conductive conjugated polymer: The cyclopolymerization of 1,6-heptadiene derivatives via olefin metathesis reaction is proposed to synthesize the microporous polyacetylene structure.
2- Synthesis and development of MXene 2D nanosheets: Development of MXene structures with excellent electrical conductivity and mechanical flexibility.
3- Preparation and development of membranes (Polymer/MXene mixed matrix membrane, MXene inorganic membranes)
4- Making the setup and testing
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| Outline of Annual Research Achievements |
Ti3C2Tx MXene sheets with high hydrophilicity are being considered for gas separation applications. Herein, we prepared MXene/graphene oxide (GO) composite membranes at different GO concentrations with smaller interlayer spacing and aligned platelets for a better separation performance. The membranes were fabricated by vacuum filtration of MXene/GO suspension at different GO compositions on AAO substrate. The membranes thickness was adjusted between 20 nm to 100 nm with an exact volume of the suspension.
FTIR, XPS spectra revealed the interactions between MXene platelets and GO monolayer through Ti-O-C covalent bonds. Moreover, XPS and UV absorbance indicated the reduction of GO sheets by MXene. X-ray scattering exhibited that the d-spacing of MXene increases from 11.4 A to 13.5 A; at low GO contents, which explained the interlamellar insertion of GO into MXene has occurred. The stability and mechanical properties of the MXene/GO membranes improved compared to the pure MXene due to the Ti-O-C covalent bonding. N2 adsorption measurement showed a decrease in pore volume and gas uptake of MXene membranes by the addition of GO, which was attributed to the Ti-O-C covalent bonds and improvement in the alignment degree. The gas permeance of the composite membranes decreased down to half of its pure MXene value by adding GO because of the smaller pore volume. However, the H2/CO2 selectivity significantly improved from 115 for pure MXene to 536 for MX50GO50, indicating a better sieving ability in the composite membranes.
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| Research Progress Status |
令和2年度が最終年度であるため、記入しない。
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| Strategy for Future Research Activity |
令和2年度が最終年度であるため、記入しない。
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