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Synergy effect of piezoelectricity and piezoluminescence

Research Project

Project/Area Number 19H00835
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Review Section Medium-sized Section 26:Materials engineering and related fields
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Xu Chao-Nan  国立研究開発法人産業技術総合研究所, エレクトロニクス・製造領域, 総括研究主幹 (70235810)

Co-Investigator(Kenkyū-buntansha) 王 瑞平  国立研究開発法人産業技術総合研究所, エレクトロニクス・製造領域, 主任研究員 (00358392)
西堀 麻衣子  東北大学, 国際放射光イノベーション・スマート研究センター, 教授 (20462848)
鄭 旭光  佐賀大学, 理工学部, 教授 (40236063)
Project Period (FY) 2019-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥45,370,000 (Direct Cost: ¥34,900,000、Indirect Cost: ¥10,470,000)
Fiscal Year 2021: ¥14,820,000 (Direct Cost: ¥11,400,000、Indirect Cost: ¥3,420,000)
Fiscal Year 2020: ¥14,820,000 (Direct Cost: ¥11,400,000、Indirect Cost: ¥3,420,000)
Fiscal Year 2019: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Keywords応力発光 / マルチピエゾ / センサ / 非破壊検査 / 圧電 / 多相境界 / IOT / ロボティクス / 応力分布可視化 / センシング / 強誘電 / 光機能 / アクチェーター / 構造物診断 / IoT
Outline of Research at the Start

申請者は僅かな機械応力を加えることで「目に見える」光を放出する特異構造の無機結晶応力発光体を発見し、開拓者としてこの分野の研究を牽引してきた。直近では新規に圧電性の強い結晶系の応力発光体の合成に初めて成功している。このような強い応力発光性と圧電性を同時に発現させる革新的な機能を我々はマルチピエゾと名付けている。しかし、応力発光性と圧電性の相関メカニズムはまだ解明されておらず、なぜ極微力に対しても繰り返し発光するか、現状理論では説明できない。本研究では、今までのポテンシャル蓄積と新規発見を足場に、マルチピエゾ材料の物性・機能を解明することで、多元変換の本質を明らかにする。

Outline of Final Research Achievements

The aim of this study is to elucidate the mechanism of a newly discovered multipiezo material and reveal the synergy effect between piezoluminescence and piezoelectricity. We focused on LiNbO3 and employed non-stoichiometric composition and element substitution for crystal control. As a result, we identified a significant enhancement of piezoluminescence intensity near the morphotropic phase boundary (MPB) of Na-substituted LiNbO3 with specific crystal structures. This piezoluminescence at the MPB achieved more than a tenfold improvement compared to non-stoichiometric LiNbO3, along with a similar tenfold enhancement in piezoelectricity, as demonstrated by the increased piezoelectric coefficient d33. Furthermore, we extended this phenomenon of synergy effect between piezoluminescence and piezoelectricity to other material systems.

Academic Significance and Societal Importance of the Research Achievements

本研究では、理論と実験の両面からアプローチすることで、新たに発見したマルチピエゾ材料の機構を解明し、応力発光と圧電性の相乗効果を明らかにし、相境界付近での応力発光強度と圧電効果が同時に飛躍的に増強されることを明らかにしている。さらに、この発見はLiNbO3に限らず、他の材料系にも展開可能であることを示し、マルチピエゾ材料の応力発光と圧電の相乗効果の理解を深め、マイルピエゾ材料領域の開拓に寄与する。

Report

(6 results)
  • 2022 Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • 2019 Comments on the Screening Results   Annual Research Report
  • Products Report
  • Research Products

    (54 results)

All 2023 2022 2021 2020 2019

All Journal Article (10 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 10 results,  Open Access: 7 results) Presentation (36 results) (of which Int'l Joint Research: 12 results,  Invited: 11 results) Patent(Industrial Property Rights) (8 results) (of which Overseas: 3 results)

  • [Journal Article] New mode of stress sensing in multicolor (Ca1-Sr )8Mg3Al2Si7O28:Eu2+ solid-solution compounds2022

    • Author(s)
      Liu Shiqi、Liu Rong、Yang Xiuxia、Li Jun、Sun Mingzi、Xu Chao-Nan、Huang Bolong、Liang Yujun、Tu Dong
    • Journal Title

      Nano Energy

      Volume: 93 Pages: 106799-106799

    • DOI

      10.1016/j.nanoen.2021.106799

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Near-Infrared Mechanoluminescence Material from Organic Acid-Aided Process2021

    • Author(s)
      Fujio Yuki、Xu Chao-Nan、Terasaki Nao
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 168 Issue: 4 Pages: 047508-047508

    • DOI

      10.1149/1945-7111/abf5f8

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effective Repeatable Mechanoluminescence in Heterostructured Li1-xNaxNbO3: Pr3+2021

    • Author(s)
      Yang Xiuxia、Liu Rong、Xu Xuhui、Liu Zhichao、Sun Mingzi、Yan Wei、Peng Dengfeng、Xu Chao‐Nan、Huang Bolong、Tu Dong
    • Journal Title

      Small

      Volume: 17 Issue: 46 Pages: 2103441-2103441

    • DOI

      10.1002/smll.202103441

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Control of crystal structure and performance evaluation of multi-piezo material of Li<sub>1−</sub><i><sub>x</sub></i>Na<i><sub>x</sub></i>NbO<sub>3</sub>:Pr<sup>3+</sup>2020

    • Author(s)
      HARA Hirotaka、XU Chao-Nan、WANG Ruiping、ZHENG Xu-Guang、NISHIBORI Maiko、NISHIBORI Eiji
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 128 Issue: 8 Pages: 518-522

    • DOI

      10.2109/jcersj2.20015

    • NAID

      130007883934

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2020-08-01
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Photoluminescent Ferroelectric LiNb03 Crystals Grown from Mxenes2020

    • Author(s)
      S.Tu, M. Mizohata, G. Sheng, L. Liu, F. Ming, C.N. Xu, D. Tu, X. Zhang, H.N. Alshareef
    • Journal Title

      Advanced Functional Materials

      Volume: 1909843 Issue: 47 Pages: 1-6

    • DOI

      10.1002/adfm.201909843

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Ferroelectric Sr 3 Sn 2 O 7 :Nd 3+ : A New Multipiezo Material with Ultrasensitive and Sustainable Near‐Infrared Piezoluminescence2020

    • Author(s)
      Tu Dong、Xu Chao‐Nan、Kamimura Sunao、Horibe Yoichi、Oshiro Hirotaka、Zhang Lu、Ishii Yoshiharu、Hyodo Koji、Marriott Gerard、Ueno Naohiro、Zheng Xu‐Guang
    • Journal Title

      Advanced Materials

      Volume: 32 Issue: 25 Pages: 1908083-1908083

    • DOI

      10.1002/adma.201908083

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Invisible crack visualization and depth analysis by mechanoluminescence film2020

    • Author(s)
      Fujio Yuki、Xu Chao-Nan、Sakata Yoshitaro、Ueno Naohiro、Terasaki Nao
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 832 Pages: 154900-154900

    • DOI

      10.1016/j.jallcom.2020.154900

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis of Near-Infrared Mechanoluminescence Material Via Organic Acid-Aided Process2020

    • Author(s)
      Fujio Yuki、Xu Chao-Nan、Terasaki Nao
    • Journal Title

      ECS Transactions

      Volume: 98 Issue: 11 Pages: 61-68

    • DOI

      10.1149/09811.0061ecst

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 応力発光技術の概要と風車ブレードへの応用2020

    • Author(s)
      徐超男、阿部裕幸、森川泰、小垣哲也
    • Journal Title

      日本風力エネルギー学会誌

      Volume: 44 Pages: 359-362

    • NAID

      130008128574

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Trap-controlled mechanoluminescent materials2019

    • Author(s)
      Zhang Jun-Cheng、Wang Xusheng、Marriott Gerard、Xu Chao-Nan
    • Journal Title

      Progress in Materials Science

      Volume: 103 Pages: 678-742

    • DOI

      10.1016/j.pmatsci.2019.02.001

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] 応力発光技術による動的ひずみ分布計測と破壊現象の可視化2021

    • Author(s)
      藤尾侑輝、徐超男、寺崎正
    • Organizer
      日本セラミックス協会 2022年年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 近赤外応力発光を示すZnOにおける発光機能の向上機構2021

    • Author(s)
      岩田隆正、西堀英治、鄭旭光、徐超男
    • Organizer
      日本セラミックス協会 2022年年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Multi-piezo発光体を用いた応力記録機能の発見2021

    • Author(s)
      温昊、濵惇一郎、岩田隆正、任銘昭、徐超男
    • Organizer
      日本セラミックス協会 2022年年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] X線吸収分光によるMulti-Piezo材料の局所構造解析2021

    • Author(s)
      池田尚輝、二宮翔、徐超男、西堀麻衣子
    • Organizer
      第60回セラミックス基礎科学討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Enhancement of mechanoluminescence characteristic by tuning SrAl2O4 crystallization process assisted with organic acid2021

    • Author(s)
      Y. Fujio, C.N. Xu, N. Terasaki
    • Organizer
      4th Pacific Rim Conference on Ceramic and Glass Technology(PaCRim14)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高感度応力発光体を用いた構造体内部損傷の可視化2021

    • Author(s)
      濵惇一郎、徐超男
    • Organizer
      2021年度 応用物理学会九州支部学術講演会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 応力発光のソフトクリスタルの界面制御による光機能開拓2021

    • Author(s)
      徐超男
    • Organizer
      ソフトクリスタル領域会議
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] Creation of multi-piezo material of LiNbO3 emits visible-near infrared light2021

    • Author(s)
      任銘昭、温昊、徐超男
    • Organizer
      第41回電子材料研究討論会
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] μSRを用いた応力発光のメカニズム研究2021

    • Author(s)
      鄭旭光, 山内一広, 幸田章宏, 西村昇一郎, 中村惇平, 徐超男
    • Organizer
      日本物理学会 2021年秋季大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 液相法による多元素添加近赤外応力発光体の開発2021

    • Author(s)
      藤尾侑輝、徐超男、寺崎正
    • Organizer
      2021年電気化学秋季大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 発光するナノ・テクスチャー構造の Multi-piezo 体の創製2021

    • Author(s)
      任銘昭、劉剣橋、岩田隆正、濵惇一郎、温昊、徐超男
    • Organizer
      公益社団法人日本セラミックス協会 第46回 学術写真賞
    • Related Report
      2021 Annual Research Report
  • [Presentation] 応力発光塗料技術の風力分野への応用2021

    • Author(s)
      徐超男
    • Organizer
      令和3年度第1回福島県再生可能エネルギー関連産業推進研究会 風力分科会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 超高速分光で探る希土類発光材料の光機能2020

    • Author(s)
      宮田潔志、田中孝記、宮崎栞、鈴木郁哉、北川裕一、長谷川靖哉、徐超男、山方啓、恩田健
    • Organizer
      第36回希土類討論会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Synthesis of near-infrared mechanoluminescence material via organic acid-aided process2020

    • Author(s)
      Y. Fujio, C.N. Xu, N. Terasaki
    • Organizer
      PRiME 2020 Pacific Rim Meeting on Electrochemical & Solid-State Science
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development and mechanism of novel highly-sensitive near-infrared mechanoluminescence material2020

    • Author(s)
      D. Tu, C.N. Xu
    • Organizer
      The 2020 Annual Meeting of the Chinese Society of Rare Earths
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] マルチピエゾ体CaZnOSを用いた特異的な近赤外発光特性2020

    • Author(s)
      溝畑将之、徐超男*、上野直広
    • Organizer
      第40回電子材料研究討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 有機酸支援法によるSrAl2O4:Eu応力発光体の合成と発光特性2020

    • Author(s)
      藤尾侑輝、徐超男、寺崎正
    • Organizer
      第40回電子材料研究討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 応力発光力学イメージングによる衝撃応力とその応力波の伝搬の可視化2020

    • Author(s)
      濵惇一郎、岩田隆正、徐超男
    • Organizer
      2021年第68回応用物理学会春季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 応力発光体を用いた複雑な構造物の応力分布の可視化2020

    • Author(s)
      溝畑将之、徐超男
    • Organizer
      2021年第68回応用物理学会春季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Development of multi-piezo material with morphotropic phase boundary (MPB)2020

    • Author(s)
      M.Z. Ren, H. Wen, C.N. Xu
    • Organizer
      公益社団法人日本セラミックス協会 2021年年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ZnOにおける近赤外応力発光機能の発現2020

    • Author(s)
      岩田隆正、溝畑将之、徐超男
    • Organizer
      公益社団法人日本セラミックス協会 2021年年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 応力発光機能の開拓とマルチピエゾ2019

    • Author(s)
      徐超男
    • Organizer
      日本セラミックス協会 九州支部 平成31年度九州支部 支部大会・春季特別講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Deep-Trap Dominated Sustainable Mechanoluminescence from Layered Perovskite Sr3Sn2O7:Sm3+2019

    • Author(s)
      D. Tu, Chao-Nan Xu
    • Organizer
      2019 MRS Spring Meeting & Exhibit(Phoenix, Arizona, U.S.A)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mechanoluminescence: from materials to applications and standardization2019

    • Author(s)
      Chao-Nan Xu
    • Organizer
      The Eleventh International Conference on High-Performance Ceramics (CICC-11) (Kunming, China)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 応力発光技術を用いたコンクリート橋のひび割れ進展挙動の定量評価に関する試験施工2019

    • Author(s)
      福田雅人、徐超男、貝沼重信、麻生孝志
    • Organizer
      令和元年度全国大会 第74回年次学術講演会 (香川大学幸町キャンパス)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 応力発光技術の風車ブレードへの応用2019

    • Author(s)
      徐超男
    • Organizer
      日本風力エネルギー学会第2回ブレード技術研究会(日本風力発電協会:東京都港区)
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Recent progress in sustainable mechanoluminescence materials2019

    • Author(s)
      Chao-Nan Xu
    • Organizer
      20th International Union of Materials Research Societies International Conference in Asia (IUMRS-ICA 2019) (Perth Convension & Exhibition Centre, Perth Australia)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Piezoluminescence Crystalline Material And Their Applications2019

    • Author(s)
      C.N. Xu, R. Wang, M. Nishibori, X.G. Zheng
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PACRIM13) (Okinawa Convention Center, Japan)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Performance Improvement of Multi-Piezo Material by Control of Crystal Structure2019

    • Author(s)
      H. Hara, R. Wang, X.G. Zheng, M. Nishibori, C.N. Xu
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PACRIM13) (Okinawa Convention Center, Japan)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Visualization of Stress Distribution from Outside the Biological Tissue by Near-infrared Mechanoluminescence Material2019

    • Author(s)
      Y. Ishii, N. Ueno, C.N. Xu
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PACRIM13) (Okinawa Convention Center, Japan)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Dual-mode mechano-optical conversion in phosphorescent CaZnOS:Cu2019

    • Author(s)
      D Tu, C.N. Xu
    • Organizer
      International Symposiums for Phosphor Materials (Phosphor Safari 2019)(Xiamen, China)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Progress in mechanoluminescence materials and their applications2019

    • Author(s)
      C.N. Xu
    • Organizer
      International Symposiums for Phosphor Materials (Phosphor Safari 2019)(Xiamen, China)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 近赤外応力発光体による生体組織外からの応力解析2019

    • Author(s)
      石井孝治、上野直広、徐超男
    • Organizer
      第39回電子材料研究討論会(愛知県名古屋市:ウインク愛知)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Multi-piezo材料の結晶構造制御による性能向上2019

    • Author(s)
      原弘峻、王瑞平、鄭旭光、西堀麻衣子、徐超男
    • Organizer
      第39回電子材料研究討論会(愛知県名古屋市:ウインク愛知)
    • Related Report
      2019 Annual Research Report
  • [Presentation] "CaZnOS:Mn の開発とMulti-piezo性能の向上2019

    • Author(s)
      溝畑将之、徐超男
    • Organizer
      第39回電子材料研究討論会(愛知県名古屋市:ウインク愛知)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 応力発光現状と応用例2019

    • Author(s)
      徐超男
    • Organizer
      賢材研講演会 (東京都)
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Patent(Industrial Property Rights)] 応力発光材料及び同応力発光材料の製造方法2023

    • Inventor(s)
      徐 超男
    • Industrial Property Rights Holder
      国立研究開発法人産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2023-503970
    • Filing Date
      2023
    • Related Report
      Products Report
  • [Patent(Industrial Property Rights)] 圧電性および応力発光性を有する多機能性マルチピエゾ材料2023

    • Inventor(s)
      徐 超男、王 瑞平
    • Industrial Property Rights Holder
      国立研究開発法人産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Acquisition Date
      2023
    • Related Report
      Products Report
  • [Patent(Industrial Property Rights)] MULTIFUNCTIONAL MULTI-PIEZO MATERIAL HAVING PIEZOELECTRIC PROPERTIES AND MECHANOLUMINESCENCE PROPERTIES, AND MULTIFUNCTIONAL PIEZOELECTRIC BODY, MEMS DEVICE, ROBOT, STRAIN/FATIGUE/DAMAGE DIAGNOSIS DEVICE, AND NONDESTRUCTIVE INSPECTION METHOD USING SAME2022

    • Inventor(s)
      徐 超男、王 瑞平
    • Industrial Property Rights Holder
      国立研究開発法人産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Filing Date
      2022
    • Related Report
      Products Report
    • Overseas
  • [Patent(Industrial Property Rights)] 圧電性および応力発光性を有する多機能性マルチピエゾ材料2022

    • Inventor(s)
      徐 超男、王 瑞平
    • Industrial Property Rights Holder
      国立研究開発法人産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2022-540003
    • Filing Date
      2022
    • Related Report
      Products Report
  • [Patent(Industrial Property Rights)] 応力発光材料及び同応力発光材料の製造方法2022

    • Inventor(s)
      徐 超男
    • Industrial Property Rights Holder
      国立研究開発法人産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Filing Date
      2022
    • Related Report
      Products Report
    • Overseas
  • [Patent(Industrial Property Rights)] 応力発光材料及び同応力発光材料の製造方法2021

    • Inventor(s)
      徐超男
    • Industrial Property Rights Holder
      産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2021-035875
    • Filing Date
      2021
    • Related Report
      2021 Annual Research Report
  • [Patent(Industrial Property Rights)] 圧電性および応力発光性を有する多機能性マルチピエゾ材料、並びにそれを用いた多機能性圧電体、MEMSデバイス、ロボット、歪・欠陥・健全性計測装置および非破壊検査方法2021

    • Inventor(s)
      徐 超男、王 瑞平
    • Industrial Property Rights Holder
      国立研究開発法人産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Filing Date
      2021
    • Related Report
      Products Report
    • Overseas
  • [Patent(Industrial Property Rights)] 圧電性および応力発光性を有する多機能性マルチピエゾ材料、並びにそれを用いた多機能性圧電体、MEMSデバイス、ロボット、歪・欠陥・健全性計測装置および非破壊検査方法2020

    • Inventor(s)
      徐超男、王瑞平
    • Industrial Property Rights Holder
      産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2020-126975
    • Filing Date
      2020
    • Related Report
      2020 Annual Research Report

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Published: 2019-04-18   Modified: 2025-03-27  

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