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絶縁膜上のGeチャネルに於ける結晶・界面の総合評価

Research Project

Project/Area Number 20035011
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKyushu University

Principal Investigator

中島 寛  Kyushu University, 産学連携センター, 教授 (70172301)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥5,200,000)
Fiscal Year 2009: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 2008: ¥2,600,000 (Direct Cost: ¥2,600,000)
KeywordsGe-MOS / 絶縁膜 / Ge構造 / チャネル / 結晶性 / 界面準位 / SGOI / GOI / 結晶欠陥 / Ge
Research Abstract

本研究では、界面層制御した高品質な絶縁膜/Ge構造形成技術を確立すると共に、Ge-On-Insulator (GOI)チャネル層の物性を解明することを目的としている。平成21年度は、(1) 絶縁膜/Ge構造形成、(2) GOIチャネル層の結晶性評価、の研究を実施し、以下の成果が得られた。
(1) Ge-MOS構造として、Ge表面をSiO_2/GeO_2の2層膜でパッシベーションする手法を検討した。GeO_2及びSiO_2膜の役割はそれぞれGe表面のダングリングボンド終端化及びGeO_2中への不純物(水や炭化水素)混入防止にある。この2層パッシベーション膜を大気暴露無しで形成する手法を開発した。この新規な界面層形成手法を用いれば、低い界面準位密度(4×10^<11>cm^<-2>eV^<-1>)のMOS構造が実現できる。この独自技術は良質なGe-MOS界面構造形成のための手法として有用であることを実証した。
(2) Ge濃度が15~90%のSiGe-On-Insulator (SGOI)およびGOIを酸化濃縮法で作成した。これらの試料にリン(P)を固相拡散してソース/ドレインを形成し、バックゲート型MOSFETを作成した。試料の電気特性から閾値電圧を求め、イオン化アクセプタ濃度(NA)を算出した。その結果、NAのGe濃度依存性は、Hall効果法で求めた正孔濃度(p)の依存性と異なることを示した。即ち、低Ge濃度領域では、NAが10^<16>cm^<-3>以上であるのに対して、pは約2桁低い。一方、高Ge濃度領域では両者はほぼ一致する。この相違は、酸化濃縮過程で生じる欠陥が深いアクセプタ(A)として働き、Ge濃度の増加に伴い、Aのエネルギー準位が価電子帯側ヘシフトする事で説明できる。このエネルギーシフトをホール効果の温度依存性から明らかにした。

Report

(2 results)
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (38 results)

All 2010 2009 2008 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (23 results) Remarks (2 results)

  • [Journal Article] Electrical characterization of High-k Gate Dielectrics on Ge with HfGeN and GeoO_2 interlayers2010

    • Author(s)
      K.Hirayama, W.Kira, K.Yoshino, H.Yang, D.Wang, H.Nakashima
    • Journal Title

      Thin Solid Films Vol.518

      Pages: 2505-2508

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Defect control by Al-deposition and the subsequent post-annealing for SiGe-on-insulator substrates with different Ge fractions2010

    • Author(s)
      H.Yang, D.Wang, H.Nakashima, K.Hirayama, S.Kojima, S.Ikeura
    • Journal Title

      Thin Solid Films Vol.518

      Pages: 2342-2345

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Defect-Induced Deep Levels in SiGe-On-Insulator Substrate Fabricated using Ge Condensation Technique2009

    • Author(s)
      H.Yang, D.Wang, H.Nakashima
    • Journal Title

      Extended Abstracts of the 2009 International Conference on Solid State Devices and Materials

      Pages: 396-397

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical and Electrical Characterization of Defects in SiGe-on-Insulator2009

    • Author(s)
      H.Nakashima, D.Wang, H.Yang
    • Journal Title

      The Electrochemical Society Transactions Vol.25, No.7

      Pages: 99-114

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evidence for existence of deep acceptor levels in SiGe-on-insulator substrate fabricated using Ge condensation technique2009

    • Author(s)
      H.Yang, D.Wang, H.Nakashima
    • Journal Title

      Applied Physics Letters Vol.95, No.12

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical and electrical evaluations of SiGe layers on insulator fabricated using Ge condensation by dry oxidation2009

    • Author(s)
      D.Wang, H.Nakashima
    • Journal Title

      Solid-State Electronics Vol.53, No.8

      Pages: 841-849

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microstructural change of dislocation structure around SiGe/Si interface in SGOI wafer : wafer ramping process2008

    • Author(s)
      S. Ii, Y. Takata, K. Ikeda, H. Nakashima, H. Nakashima
    • Journal Title

      Thin Solid Films 517

      Pages: 38-40

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dependences of effective work functions of TaN on HfO_2 and SiO_2 on post-metallization anneal2008

    • Author(s)
      Y. Sugimoto, K. Yamamoto, M. Kajiwara, Y. Suehiro, D. Wang. H. Nakashima
    • Journal Title

      Thin Solid Films 517

      Pages: 204-206

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of top surface passivation on bottom-channel hole mobility of ultrathin SiGe-and Ge-on-insulator2008

    • Author(s)
      H. Yang, D. Wang, H. Nakashima, H. Gao, K. Hirayama, K. Ikeda, S. Hata. H. Nakashima
    • Journal Title

      Applied Physics Letters 93

      Pages: 72104-3

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrical and structural evaluations of high-k gate dielectrics using plasma oxidation and the subsequent annealing of Hf/Si02/Si structure2008

    • Author(s)
      H. Nakashima, Y. Sugimoto, Y Suehiro, K. Yamamoto, M. Kajiwara, K. Hirayama, D. Wang
    • Journal Title

      Semiconductor Science and Technology 23

      Pages: 125020-6

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical and electrical evaluations of SiGe layers on insulator fabricated using Ge Condensation by dry oxidation2008

    • Author(s)
      H. Nakashima, D. Wang
    • Journal Title

      Abstract of 4^<th> Intemational SiGe Technology and Device Meeting (招待講演)

      Pages: 125-126

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrical and Structural Evaluations of Ultrathin SiGe and Ge-on-insulator Fabricated Using Ge Condensation by Dry Oxidation2008

    • Author(s)
      H. Yang, D. Wang, H. Gao, K. Hirayama, K. Ikeda, S. Hata, H. Nakashima, H. Nakashima
    • Journal Title

      Extended Abstracts of the 2008 International ronference on Solid State Devices and Materials

      Pages: 438-439

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of high-k gate dielectrics using plasma oxidation and subsequent annealing of Hf/SiO_2/Si structure2008

    • Author(s)
      H. Nakashima, Y. Sugimoto, Y. Suehiro, K. Yamamoto, M. Kaiiwara, K. Hirayama, D. Wang
    • Journal Title

      Proceeding of 9th International Conference on Solid-State and Integrated-Circuit Technology C5.7

      Pages: 1-4

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Ge上への極薄SiO_2/GeO_2界面層の形成2010

    • Author(s)
      平山佳奈、吉野圭介、岩村義明、上野隆二、楊海貴、王冬、中島寛
    • Organizer
      2010年春季第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2010-03-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] Al_2O_3PDAによる酸化濃縮SiGe-On-Insulator基板中の欠陥制御2010

    • Author(s)
      井餘田昌俊、池浦奨悟、楊海貴、王冬、中島寛
    • Organizer
      2010年春季第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2010-03-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] 酸化濃縮法で作成したSiGe-On-Insulator基板中の欠陥制御2009

    • Author(s)
      井餘田昌俊、池浦奨悟、楊海貴、王冬、中島寛
    • Organizer
      2009年応用物理学会九州支部学術講演会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-11-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] GeO_2/Ge界面のDHS法による評価2009

    • Author(s)
      上野隆二、平山佳奈、吉野圭介、楊海貴、王冬、中島寛
    • Organizer
      2009年応用物理学会九州支部学術講演会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-11-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] ZrSiO_x/GeO_2/Ge MIS構造の形成と電気的評価2009

    • Author(s)
      岩村義明、平山佳奈、吉野圭介、楊海貴、王冬、中島寛
    • Organizer
      2009年応用物理学会九州支部学術講演会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-11-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] Defect-Induced Deep Levels in SiGe-on-Insulator Substrate Fabricated using Ge Condensation Technique2009

    • Author(s)
      H.Yang, D.Wang, H.Nakashima
    • Organizer
      2009 International Conference on Solid State Devices and Materials
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      2009-10-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] Optical and Electrical Characterizations of Defects in SiGe-on-Insulator(Invited)2009

    • Author(s)
      H.Nakashima, D.Wang, H.Yang
    • Organizer
      216^<th> Electrochemical Society Meeting
    • Place of Presentation
      Vienna, Austria
    • Year and Date
      2009-10-06
    • Related Report
      2009 Annual Research Report
  • [Presentation] SiGe-on-Insulator基板形成時に発生する欠陥の電気・光学的評価2009

    • Author(s)
      中島寛、楊海貴、王冬
    • Organizer
      日本物理学会領域10格子欠陥・ナノ構造分科、第19回格子欠陥フォーラム「半導体格子欠陥の最前線」
    • Place of Presentation
      九州大学
    • Year and Date
      2009-09-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] ZrSiO_x/GeO_2/Ge MIS構造の形成と電気的評価2009

    • Author(s)
      吉野圭介、平山佳奈、上野隆二、楊海貴、王冬、中島寛
    • Organizer
      2009年秋季第70回応用物理学会学術講演会
    • Place of Presentation
      富山大学
    • Year and Date
      2009-09-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] 酸化濃縮法で作成したSiGe-On-Insulator基板中の欠陥生成機構2009

    • Author(s)
      池浦奨悟、楊海貴、王冬、中島寛
    • Organizer
      2009年秋季第70回応用物理学会学術講演会
    • Place of Presentation
      富山大学
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] 界面層にHfGeNおよびGeO_2を有するhigh-k膜/Ge構造の形成と電気的評価2009

    • Author(s)
      中島寛、平山佳奈、楊海貴、王冬
    • Organizer
      応用物理学会分科会 シリコンテクノロジー:「ゲートスタック研究の進展Ge系材料を中心に」
    • Place of Presentation
      東京大学
    • Year and Date
      2009-06-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] Electrical characterization of High-k Gate Dielectrics on Ge with HfGeN and GeO_2 interlayers2009

    • Author(s)
      K.Hirayama, W.Kira, K.Yoshino, H.Yang, D.Wang, H.Nakashima
    • Organizer
      European Materials Research Society 2009 Spring Meeting
    • Place of Presentation
      Strasbourg, France
    • Year and Date
      2009-06-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Defect Control by Al-deposition and the subsequent post-annealing for SiGe-on-insulator substrates with different Ge fractions2009

    • Author(s)
      H.Yang, D.Wang, H.Nakashima, K.Hirayama, S.Kojima, S.Ikeura
    • Organizer
      European Materials Research Society 2009 Spring Meeting
    • Place of Presentation
      Strasbourg, France
    • Year and Date
      2009-06-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] SOI構造に於けるチャネル層の移動度評価2008

    • Author(s)
      池浦奨悟、小嶋慧、楊海貴、王冬、中島寛
    • Organizer
      応用物理学会九州支部学術講演会
    • Place of Presentation
      宮崎大学
    • Year and Date
      2008-11-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] Ge基板上へのpn接合形成2008

    • Author(s)
      真栄田祐、楊海貴、王冬、中島寛
    • Organizer
      応用物理学会九州支部学術講演会
    • Place of Presentation
      宮崎大学
    • Year and Date
      2008-11-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] Ge上へのhigh-kゲート絶縁膜形成2008

    • Author(s)
      吉野圭介、吉良渉、平山佳奈、楊海貴、王冬、中島寛
    • Organizer
      応用物理学会九州支部学術講演会
    • Place of Presentation
      宮崎大学
    • Year and Date
      2008-11-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] Fabrication of high-k gate dielectrics using plasma oxidation and subsequent annealing of HVSiO_2/Si structure2008

    • Author(s)
      H. Nakashima, Y. Sugimoto, Y. Suehiro, K. Yamamoto, M. Kaiiwara, K. Hiravama, D. Wang
    • Organizer
      9th International Conference on Solid-State and Integrated-Circuit Technology
    • Place of Presentation
      Beijing, China
    • Year and Date
      2008-10-23
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrical and Structural Evaluations of Ultrathin SiGe and Ge-on-insulator Fabricated Using Ge Condensation by Dry Oxidation2008

    • Author(s)
      H. Yang, D. Wang, H. Gao, K. Hirayama, K. Ikeda, S. Hata, H. Nakashima, H. Nakashima
    • Organizer
      2008 International Conference on Solid State Devices and Materials
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2008-09-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] Hf_xGe_<1-x>N_y界面層を有する絶縁膜NGe構造の形成2008

    • Author(s)
      平山佳奈、吉良渉、楊海貴、王冬、中島寛
    • Organizer
      第69回応用物理学会学術講演会
    • Place of Presentation
      中部大学
    • Year and Date
      2008-09-04
    • Related Report
      2008 Annual Research Report
  • [Presentation] 薄膜SiGe-及びGe表On-Insulatorのバックチャネル移動度に与える表面パッシベーションの影響2008

    • Author(s)
      楊海貴、王冬、中島寛、高紅叶、平山佳奈、池田賢一、波多聰、中島英治
    • Organizer
      第69回応用物理学会学術講演会
    • Place of Presentation
      中部大学
    • Year and Date
      2008-09-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] SOI構造に於けるチャネル層の移動度評価2008

    • Author(s)
      小嶋慧、王冬、中島寛
    • Organizer
      第69回応用物理学会学術講演会
    • Place of Presentation
      中部大学
    • Year and Date
      2008-09-02
    • Related Report
      2008 Annual Research Report
  • [Presentation] Optical and electrical evaluations of SiGe layers on insulator fabricated using Ge Condensation by dry oxidation (Invited)2008

    • Author(s)
      H. Nakashima, D. Wang
    • Organizer
      4^<th> International SiGe Technology and Device Meeting
    • Place of Presentation
      Hchinchu, Taiwan
    • Year and Date
      2008-05-14
    • Related Report
      2008 Annual Research Report
  • [Presentation] GeO_2界面層を有する上へのhigh-k膜/Ge構造の形成

    • Author(s)
      平山佳奈、吉野圭介、吉良渉、楊海貴、王冬、中島寛
    • Organizer
      第56回応用物理学関係連合講演会
    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://astec.kyushu-u.ac.jp/nakasima/naka_home.htm

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://astec.kyushu-u.ac.jpNnakasima/naka_home.htm

    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2018-03-28  

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