Molecular Design and Synthetic Applications of Chiral Aminophosphonium Salts
| Project/Area Number |
20350018
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
OOI Takashi Nagoya University, 工学研究科, 教授 (80271708)
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| Co-Investigator(Kenkyū-buntansha) |
URAGUCHI Daisuke 名古屋大学, 大学院・工学研究科, 講師 (70426328)
OHMATSU Kohsuke 名古屋大学, 大学院・工学研究科, 助教 (00508997)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2010: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2009: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2008: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
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| Keywords | 有機化学 / 不斉合成 / ホスホニウム塩 / 酸・塩基触媒 / 分子認識 |
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| Research Abstract |
A series of P-spiro chiral tetraaminophosphonium salts have been designed and synthesized as a new class of organic molecular catalysts, and their inherent abilities to exert four different, synthetically relevant asymmetric catalyses have been brought out through the unique molecular design on a single core structure, N_4P^+. Further, these catalyses have been applied to the development of various C-C, C-P, and C-N bond-forming reactions, in which the remarkably high catalytic performances and stereocontrolling abilities of the chiral tetraaminophosphonium salts have been successfully demonstrated.
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Report
(4 results)
Research Products
(36 results)
