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Precise synthesis of cycloolefin copolymers

Research Project

Project/Area Number 20350055
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer chemistry
Research InstitutionHiroshima University

Principal Investigator

SHIONO Takeshi  Hiroshima University, 大学院・工学研究院, 教授 (10170846)

Co-Investigator(Kenkyū-buntansha) NAKAYAMA Yuushou  広島大学, 大学院・工学研究院, 准教授 (20273576)
CAI Zhengguo  広島大学, 大学院・工学研究院, 助教研究者 (90452606)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥20,020,000 (Direct Cost: ¥15,400,000、Indirect Cost: ¥4,620,000)
Fiscal Year 2010: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2009: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2008: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
Keywordsシクロオレフィン / 共重合 / リビング重合 / 重合触媒 / 光学プラスチック / 高耐熱プラスチック / チーグラー・ナッタ触媒 / シングルサイト触媒 / チーグラー・ナック触媒
Research Abstract

ansa-Dimethylsilylene(fluorenyl)(tert-butylamido)dimethyltitanium complex and its derivatives were found to be an excellent catalyst for copolymerization of norbornene and 1-alkene when combined with a suitable cocatalyst. The glass transition temperature of the produced polymer was widely controlled by the comonomer composition up to 400℃. The catalytic system conducted living copolymerization combined with a suitable cocatalyst, which enable us to synthesize tailor-made polymers composed of norbornene and 1-alkene.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (62 results)

All 2011 2010 2009 2008

All Journal Article (20 results) (of which Peer Reviewed: 15 results) Presentation (42 results)

  • [Journal Article] Living polymerization of olefins with ansa-dimethylsilylene(fluorenyl)(amido)-dimethy ltitanium-based catalysts2011

    • Author(s)
      塩野毅
    • Journal Title

      Polym.J. 43[4]

      Pages: 331-351

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Highly Thermostable and Low Birefringent Norbornene-Styrene Copolymers with Advanced Optical Properties : A Potential Plastic Substrate for Flexible Displays2011

    • Author(s)
      H.T.Ban, H.Hagihara, Y.Tsunogae, T.Shiono
    • Journal Title

      J.Polym.Sci.PART A, Polym.Chem.

      Volume: 49 Pages: 67-71

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Living polymerization of olefins with ansa-dimethylsilylene-(fluorenyl)(amido)dimethyltitanium-based catalysts2011

    • Author(s)
      T.Shiono
    • Journal Title

      Polym.J.

      Volume: 43 Pages: 331-351

    • NAID

      10028159264

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Active Living Random Copolymerization of Norbornene and 1-Alkene with ansa-Fluorenylamidodimethyltitanium Derivative : Substituent Effects on Fluorenyl Ligand2010

    • Author(s)
      Z.Cai, R.Harada, Y.Nakayama, T.Shiono
    • Journal Title

      Macromolecules 43[20]

      Pages: 4527-4531

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Stereoblock Polypropylene by Change of Temperature in Living Polymerization2010

    • Author(s)
      Z.Cai, Y.Nakayama, T.Shiono
    • Journal Title

      Macromol. Res. 18[8]

      Pages: 737-741

    • NAID

      120002753658

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 架橋型フルオレニルアミドジメチルチタン錯体によるオレフィンのリビング配位重合2010

    • Author(s)
      塩野毅
    • Journal Title

      触媒 52[8]

      Pages: 540-546

    • NAID

      40017431971

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] プロピレンの立体特異的リビング配位重合2010

    • Author(s)
      塩野毅, 蔡正国
    • Journal Title

      高分子 59[10]

      Pages: 777-780

    • NAID

      10026686974

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 1-アルケンのアルキル鎖長が重合速度におよぼす影響-架橋フルオレニルアミドジメチルチタン触媒の場合-2010

    • Author(s)
      蔡正国, 塩野毅
    • Journal Title

      次世代ポリオレフィン総合研究 4

      Pages: 81-84

    • Related Report
      2010 Final Research Report
  • [Journal Article] Highly Active Living Random Copolymerization of Norbornene and 1-Alkene with ansa-Fluorenylamidodimethyltitanium Derivative : Substituent Effects on Fluorenyl Ligand2010

    • Author(s)
      Z.Cai, R.Harada, Y.Nakayama, T.Shiono.
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 4527-4531

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient Molecular Weight Control with Trialkylaluminum in Ethylene/Norbornene Copolymerization by[Ph_2C(Flu)(3-MeCp)]ZrCl_2/Methylaluminoxane Catalyst2010

    • Author(s)
      T.Tada, Z.Cai, Y.Nakayam, T.Shiono
    • Journal Title

      Macromol.Chem.Phys.

      Volume: 211 Pages: 2132-2137

    • NAID

      120002753659

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 1-アルケンのアルキル鎖長が重合速度におよぼす影響-架橋フルオレニルアミドジメチルチタン触媒の場合-2010

    • Author(s)
      蔡正国, 塩野毅
    • Journal Title

      次世代ポリオレフィン総合研究

      Volume: 4 Pages: 81-84

    • Related Report
      2010 Annual Research Report
  • [Journal Article] 架橋型フルオレニルアミドジメチルチタン錯体によるオレフィンのリビング配位重合2010

    • Author(s)
      塩野毅
    • Journal Title

      触媒

      Volume: 43 Pages: 540-546

    • NAID

      40017431971

    • Related Report
      2010 Annual Research Report
  • [Journal Article] A Highly Active Catalyst Composed of ansa-Fluorenylamidodimethyltitanium Derivative for Propene Polymerization2009

    • Author(s)
      T.Shiono, R.Harada, Z.Cai, Y.Nakayama
    • Journal Title

      Topics Catal. 52[6-7]

      Pages: 675-680

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly Active Syndiospecific Living Polymerization of Higher 1-Alkene with ansa-Fluorenylamidodimethyltitanium Complex2009

    • Author(s)
      Z.Cai, M.Ohmagari, Y.Nakayama, T.Shiono
    • Journal Title

      Macromol. Rapid Commun 30[12]

      Pages: 1812-1816

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Synthesis of a Monodisperse Olefin Block Cpolymer Using a Living Polymerization System2008

    • Author(s)
      Z.Cai, Y.Nakayama, T.Shiono
    • Journal Title

      Macromol. Rapid Commun. 29[6]

      Pages: 525-529

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Random Copolymerization of Norbornene with Higher 1-Alkene with ansa-Fluorenylamidodimethyltitanium Catalyst2008

    • Author(s)
      T.Shiono, M.Sugimoto, T.Hasan, Z.Cai, T.Ikeda
    • Journal Title

      Macromolecules 41[22]

      Pages: 8292-8294

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Facile Synthesis of Tailor-Made Stereoblock Polypropylenes via Successive Variation of Monomer Pressure2008

    • Author(s)
      Z.Cai, Y.Nakayama, T.Shiono
    • Journal Title

      Macromolcules 41[17]

      Pages: 6596-6598

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] チタン錯体触媒による炭化水素系モノマーのリビング重合2008

    • Author(s)
      蔡正国, 塩野毅
    • Journal Title

      有機合成化学協会誌 66[7]

      Pages: 664-672

    • NAID

      10021175898

    • Related Report
      2010 Final Research Report
  • [Journal Article] ジメチルシリレン架橋フルオレニルアミドジメチルチタン錯体によるプロピレンのシンジオ特異的リビング重合2008

    • Author(s)
      蔡正国, 塩野毅
    • Journal Title

      次世代ポリオレフィン総合研究 1

      Pages: 106-113

    • Related Report
      2010 Final Research Report
  • [Journal Article] Random Copolymerization of Norbornene with Higher 1-Alkene with ansa-Fluorenylamidodimethyltitanium Catalyst2008

    • Author(s)
      T. Shiono, M. Sugimoto, T. Hasan, Z. Cai, T. Ikeda
    • Journal Title

      Macromolecules 41

      Pages: 8292-8294

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 架橋フルオレニルアミドジメチルチタン誘導体によるノルボルネン-1-アルケンの高速リビング共重合2011

    • Author(s)
      蔡正国, 原田亮太郎, 中山祐正, 塩野毅
    • Organizer
      第40回石油・石油化学討論会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2011-11-26
    • Related Report
      2010 Final Research Report
  • [Presentation] 架橋型フルオレニルアルキルアミドジメチルチタン錯体によるオレフィン重合におけるアルキルアミドの置換基効果2011

    • Author(s)
      十川祐一, 蔡正国, 中山祐正, 塩野毅
    • Organizer
      第40回石油・石油化学討論会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2011-11-26
    • Related Report
      2010 Final Research Report
  • [Presentation] 架橋フルオレニルアミドジメチルチタン誘導体によるノルボルネン-1-アルケンの高速リビング共重合2010

    • Author(s)
      蔡正国, 原田亮太郎, 中山祐正, 塩野毅
    • Organizer
      石油化学討論会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2010-11-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 架橋型フルオレニルアルキルアミドジメチルチタン錯体によるオレフィン重合におけるアルキルアミドの置換基効果2010

    • Author(s)
      十川祐一, 蔡正国, 中山祐正, 塩野毅
    • Organizer
      石油化学討論会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2010-11-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Precision Polymerization of Hydrocarbon Monomers Using Coordination Polymerization Catalysts2010

    • Author(s)
      塩野毅
    • Organizer
      The 16^<th> Malaysian Chemical Congress
    • Place of Presentation
      Kuala Lumpur, Malaysia.
    • Year and Date
      2010-10-14
    • Related Report
      2010 Final Research Report
  • [Presentation] Precision Polymerization of Hydrocarbon Monomers Using Coordination Polymerization Catalysts2010

    • Author(s)
      T Shiono
    • Organizer
      The 16^<th> Malaysian Chemical Congress
    • Place of Presentation
      Kuala Lumpur(招待講演)
    • Year and Date
      2010-10-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] 架橋型アルキル置換フルオレニルアミドジメチルチタン錯体触媒を用いたプロピレンとスチレンおよびスチレン誘導体との共重合2010

    • Author(s)
      三浦佳奈子・蔡正国・中山祐正・塩野毅
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター
    • Year and Date
      2010-09-17
    • Related Report
      2010 Final Research Report
  • [Presentation] 架橋型アルキル置換フルオレニルアミドジメチルチタン錯体触媒によるプロピレンとスチレンおよびスチレン誘導体の共重合2010

    • Author(s)
      三浦佳奈子, 蔡正国, 中山祐正, 塩野毅
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 1-アルケンのアルキル鎖長が重合速度におよぼす影響-架橋フルオレニルアミドジメチルチタン触媒の場合-2010

    • Author(s)
      塩野毅
    • Organizer
      第5回次世代ポリオレフィン総合研究会
    • Place of Presentation
      田町キャンパス・イノベーションセンター
    • Year and Date
      2010-08-06
    • Related Report
      2010 Final Research Report
  • [Presentation] 架橋型アルキル置換フルオレニルアミドジメチルチタン錯体触媒によるプロピレンとスチレン誘導体の共重合2010

    • Author(s)
      三浦佳奈子・蔡正国・中山祐正・塩野毅
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2010-05-28
    • Related Report
      2010 Final Research Report
  • [Presentation] 架橋型アルキル置換フルオレニルアミドジメチルチタン錯体触媒によるプロピレンとスチレン誘導体の共重合2010

    • Author(s)
      三浦佳奈子, 蔡正国, 中山祐正, 塩野毅
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      パシラィコ横浜
    • Year and Date
      2010-05-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] リビング配位重合による炭化水素系ポリマーの構造制御2010

    • Author(s)
      塩野毅
    • Organizer
      中国四国支部第65回パネル討論会-機能性有機分子の創成を目指して-
    • Place of Presentation
      広島大学鏡山キャンパス
    • Year and Date
      2010-05-15
    • Related Report
      2010 Final Research Report
  • [Presentation] リビング配位重合による炭化水素系ポリマーの構造制御2010

    • Author(s)
      塩野毅
    • Organizer
      中国四国支部第65回パネル討論会-機能性有機分子の創成を目指して-
    • Place of Presentation
      広島大学鏡山キャンパス(招待講演)
    • Year and Date
      2010-05-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 架橋型ジメチルシリレンフルオレニルシクロドデシルアミドジメチルチタン錯体の合成とオレフィン重合触媒作用2010

    • Author(s)
      十川祐一・蔡正国・中山祐正・塩野毅
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Year and Date
      2010-03-27
    • Related Report
      2010 Final Research Report
  • [Presentation] 架橋型ジメチルシリレンフルオレニルシクロドデシルアミドジメチルチタン錯体の合成とオレフィン重合触媒作用2010

    • Author(s)
      十川祐一, 察正国, 中山祐正, 塩野毅
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 架橋型フルオレニルアミドジメチルチタン錯体を用いたリビング重合によるオレフィンブロック共重合体の精密合成2010

    • Author(s)
      蔡正国・中山祐正・塩野毅
    • Organizer
      第105回触媒討論会
    • Place of Presentation
      京都テルサ
    • Year and Date
      2010-03-24
    • Related Report
      2010 Final Research Report
  • [Presentation] Random copolymerization of propene and styrene with ansa-fluorenylamido dimethyltitanium-based catalyst2009

    • Author(s)
      塩野毅
    • Organizer
      The 3^<rd> Asian Polyolefin Workshop (APO2009)
    • Place of Presentation
      Seoul, Korea.
    • Year and Date
      2009-10-27
    • Related Report
      2010 Final Research Report
  • [Presentation] Precise synthesis of cycloolefin copolymers, Advances in Polyolefins 20092009

    • Author(s)
      塩野毅
    • Organizer
      ACS Polymer Division
    • Place of Presentation
      Santa Rosa, California USA.
    • Year and Date
      2009-09-22
    • Related Report
      2010 Final Research Report
  • [Presentation] Precise synthesis of cycloolefin copolymers2009

    • Author(s)
      塩野毅
    • Organizer
      Advances in Polyolefins 2009, ACS Polymer Division
    • Place of Presentation
      Santa Rosa, California, USA
    • Year and Date
      2009-09-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] オレフィンの精密重合における錯体触媒と活性化剤の協奏効果2009

    • Author(s)
      塩野毅
    • Organizer
      第58回高分子討論会併設シンポジウム「協奏機能触媒と高分子化学」
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] 架橋型アルキル置換フルオレニルアミドジメチルチタン錯体触媒によるスチレンとプロピレンの共重合2009

    • Author(s)
      三浦佳奈子, 蔡正国, 中山祐正, 塩野毅
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学黒髪キャンパス
    • Year and Date
      2009-09-16
    • Related Report
      2010 Final Research Report
  • [Presentation] 新規架橋型フルオレニルアミドジメチルチタン錯体を用いたエチレンとジシクロペンタジエンの高活性共重合2009

    • Author(s)
      西井圭, 早野重孝, 角替靖男, 蔡正国, 中山祐正, 塩野毅
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学黒髪キャンパス
    • Year and Date
      2009-09-16
    • Related Report
      2010 Final Research Report
  • [Presentation] オレフィンの精密重合における錯体触媒と活性化剤の協奏効果2009

    • Author(s)
      塩野毅
    • Organizer
      第58回高分子討論会併設シンポジウム「協奏機能触媒と高分子化学」
    • Place of Presentation
      熊本大学黒髪キャンパス
    • Year and Date
      2009-09-16
    • Related Report
      2010 Final Research Report
  • [Presentation] Precision Polymerization of 1-Alkene and Norbornene Using ansa-Fluorenylamidodimethyltitanium Catalysts2009

    • Author(s)
      塩野毅
    • Organizer
      The 13^<th> Asian Chemical Congress
    • Place of Presentation
      Shanghai, China.
    • Year and Date
      2009-09-15
    • Related Report
      2010 Final Research Report
  • [Presentation] Precision Polymerization of 1-Alkene and Norbornene Using ansa-Fluorenylamidodimethyltitanium Catalysts2009

    • Author(s)
      塩野毅
    • Organizer
      The 13th Asian Chemical Congress Shanghai
    • Place of Presentation
      Shanghai China
    • Year and Date
      2009-09-15
    • Related Report
      2010 Final Research Report
  • [Presentation] Precision Polymerization of 1-Alkene and Norbornene Using ansa-Fluorenylamidodimethyltitanium Catalysts2009

    • Author(s)
      塩野毅
    • Organizer
      The 13th Asian Chemical Congress
    • Place of Presentation
      Shanghai, 中国
    • Year and Date
      2009-09-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] Concerted Cocatalyst Effects in Olefin Polymerization with Single-site Catalysts2009

    • Author(s)
      塩野毅
    • Organizer
      The 3rd ECUST International Mini-Workshop of Polyolefin and Catalysis
    • Place of Presentation
      at East China University of Science and Technology (ECUST), Shanghai China.
    • Year and Date
      2009-09-13
    • Related Report
      2010 Final Research Report
  • [Presentation] Precision Polymerization of 1-Alkene and Norbornene Using ansa-Fluorenylamidodimethyltitanium Catalysts2009

    • Author(s)
      塩野毅
    • Organizer
      3rd ECUST International Mini-Workshop of Polyolefin and Catalysis
    • Place of Presentation
      Shanghai 中国
    • Year and Date
      2009-09-13
    • Related Report
      2009 Annual Research Report
  • [Presentation] Synthesis of Novel Cyclic Oefin Copolymers for Optical Plastics2009

    • Author(s)
      塩野毅
    • Organizer
      The 13th International Symposium on Advanced Display Materials and Devices
    • Place of Presentation
      Higashi-Hiroshima.
    • Year and Date
      2009-07-23
    • Related Report
      2010 Final Research Report
  • [Presentation] Synthesis of Novel Cyclic Oefin Copolymers for Optical Plastics2009

    • Author(s)
      塩野毅
    • Organizer
      The 13th International Symposium on Advanced Display Materials and Devices
    • Place of Presentation
      Higashi-hiroshima
    • Year and Date
      2009-07-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] 架橋型フルオレニルアミドジメチルチタン錯体によるノルボルネンと非共役ジエンの共重合2009

    • Author(s)
      竹中拓磨・蔡正国・中山祐正・塩野毅
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2009-03-30
    • Related Report
      2010 Final Research Report
  • [Presentation] 架橋型フルオレニルアミドジメチルチタン錯体によるノルボルネンと非共役ジェンの共重合2009

    • Author(s)
      竹中拓磨, 蔡正国, 中山祐正, 塩野毅
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] 架橋型フルオレニルアミドジメチルチタン錯体によるオレフィンブロック共重合体の精密合成2008

    • Author(s)
      蔡正国, 中山祐正, 塩野毅
    • Organizer
      第17回ポリマー材料フォーラム
    • Place of Presentation
      広島国際会議場
    • Year and Date
      2008-11-28
    • Related Report
      2010 Final Research Report
  • [Presentation] 架橋型フルオレニルアミドジメチルチタン錯体によるオレフィンブロック共重合体の精密合成2008

    • Author(s)
      蔡 正国, 中山祐正, 塩野 毅
    • Organizer
      第17回ポリマー材料フォーラム
    • Place of Presentation
      広島
    • Year and Date
      2008-11-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] 有機チタン錯体による炭化水素系モノマーのリビング重合2008

    • Author(s)
      塩野毅
    • Organizer
      理研シンポジウム「第4回有機金属化学の最前線」
    • Place of Presentation
      理化学研究所,和光
    • Year and Date
      2008-11-14
    • Related Report
      2010 Final Research Report
  • [Presentation] 架橋型フルオレニルアミドジメチルチタン錯体によるオレフィンブロック共重合体の精密合成2008

    • Author(s)
      M.D.Hasan, 蔡正国, 中山祐正, 塩野毅
    • Organizer
      第38回石油・石油化学討論会
    • Place of Presentation
      国立オリンピック記念青少年総合センター
    • Year and Date
      2008-11-06
    • Related Report
      2010 Final Research Report
  • [Presentation] 架橋型フルオレニルアミドジメチルチタン錯体触媒を用いたシクロオレフィン共重合体の官能基化2008

    • Author(s)
      M. D. Hasan, 蔡 正国, 中山祐正, 塩野 毅
    • Organizer
      第38回石油・石油化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2008-11-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] オレフィンのリビング配位重合2008

    • Author(s)
      塩野毅
    • Organizer
      第57回高分子討論会「株式会社カネカフォーカスセッション」
    • Place of Presentation
      大阪市大杉本キャンパス
    • Year and Date
      2008-09-25
    • Related Report
      2010 Final Research Report
  • [Presentation] 新規架橋フルオレニルアニリノジメチルチタン錯体の合成とオレフィン重合触媒作用2008

    • Author(s)
      加藤慶一・蔡正国・中山祐正・塩野毅
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市大杉本キャンパス
    • Year and Date
      2008-09-24
    • Related Report
      2010 Final Research Report
  • [Presentation] フルオレニルアミドチタン錯体による高速配位リビング重合を利用したブロック共重合体の触媒的合成2008

    • Author(s)
      蔡正国, 中山祐正, 塩野毅
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市大杉本キャンパス
    • Year and Date
      2008-09-24
    • Related Report
      2010 Final Research Report
  • [Presentation] フルオレニルアミドチタン錯体による高速配位リビング重合を利用したブロック共重合体の触媒的合成2008

    • Author(s)
      蔡 正国, 中山祐正, 塩野 毅
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] 新規架橋フルオレニルアニリノジメチルチタン錯体の合成とオレフィン重合触媒作用2008

    • Author(s)
      加藤慶一, 蔡正国, 中山祐正, 塩野毅
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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