| Budget Amount *help |
¥19,630,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥4,530,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
Fiscal Year 2008: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
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| Research Abstract |
Clean and remote methods for controlling fluidity and molecular rearrangement of clothes-pin shaped palladium and platinum complexes by mechanostress as an external stimuli was explored in order to create a new functional materials. Molecular assembly of cyclic dinuclear palladium complex can be controlled by reaction conditions such as sonication time, solvent, and addition of its structural isomer. Furthermore, the corresponding platinum complexes were found to show sonication-induced emission enhancement phenomenon.
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