• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Electronic Functions of Si modified with metal-organic complex

Research Project

Project/Area Number 20360314
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionKyoto University

Principal Investigator

SUGIMURA Hiroyuki  Kyoto University, 大学院・工学研究科, 教授 (10293656)

Co-Investigator(Kenkyū-buntansha) MURASE Kuniaki  京都大学, 大学院・工学研究科, 准教授 (30283633)
ICHII Takashi  京都大学, 大学院・工学研究科, 助教 (30447908)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2010: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2009: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2008: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Keywords分子メモリー / シリコン / 金属錯体 / フェロセン / 単分子膜 / 自己組織化 / 電気化学 / 光化学
Research Abstract

In this research, we have studied on fundamental electronic properties of Si modified with ferrocene derivatives in order to elucidate their potential as a charge storage material applicable to future memory devices. We have succeeded in preparing high quality monolayes of three types of ferrocene derivatives, that is, vinylferrocene, ethynylferrocene, ferrocenecarboxaldehyde, on Si by optimizing a molecular bonding process. This result enabled to evaluate electrochemical responses of the ferrocene monolayers themselves.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (26 results)

All 2011 2010 2009 2008 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (10 results) Remarks (3 results)

  • [Journal Article] Seif-Aligned Nucleation of Gold onto Templates with a Nano-scale Precision Fabricated by Scanning Probe Lithography2011

    • Author(s)
      Hiroyuki Sugimura, 他
    • Journal Title

      Journal of Photochemistry & Photobiology, A

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Alkanethiol Self-Assembled Monolayers Formed on Silicon Substrates2010

    • Author(s)
      H.Sano, K.Ohno, T.Ichii, K.Murase, H.Sugimura
    • Journal Title

      Jpn.J.Appl.Phys. 49

    • NAID

      210000067850

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Degrdation behavior of release layers for nanoimprint lithography formed on atomically flat Si(111) terraces2010

    • Author(s)
      K.Kuwabara, 他
    • Journal Title

      J.Vac.Sci.Technol.B

      Volume: 24 Pages: 968-972

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Resin Elongation Phenomenon of Polystyrene Nanopillars in Nanoimprint Lithography2010

    • Author(s)
      K.Kuwabara, 他
    • Journal Title

      Jpn.J.Appl.Phys.

      Volume: 49

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Alkanethiol Self-Assembled Monolayers Formed on Silicon Substrates2010

    • Author(s)
      H.Sano, et al.
    • Journal Title

      Jpn.J.Appl.Phys. 1

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferrocenylthiol Monolayers Induced by Atomic Force Microscopy2009

    • Author(s)
      T.Ichii, S.Nanjo, K.Murase, H.Sugimura
    • Journal Title

      Jpn.J.Appl.Phys. Vol.48

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Alkyl and Alkoxyl Monolayers Directly Attached to Silicon : Chemical Durability in Aqueous Solutions2009

    • Author(s)
      H.Sano, H.Maeda, T.Ichii, K.Murase, K.Noda, K.Matsushige, H.Sugimura
    • Journal Title

      Langumuir Vol.25 No.10

      Pages: 5516-5525

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Soft Processing for Formation of SAM on Hydrogen-Terminated Silicon Surface Based on Visible-Light Excitation2009

    • Author(s)
      H.Sano, T.Yaku, T.Ichii, K.Murase, H.Sugimura
    • Journal Title

      J.Vac.Sci.Technol.B Vol.27 No.2

      Pages: 858-862

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Alkyl and Alkoxyl Monolayers Directly Attached to Silicon : Chemical Durability in Aqueous Solutions2009

    • Author(s)
      H.Sano, et al.
    • Journal Title

      J.Vac.Sci.Technol.B 27

      Pages: 928-933

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Potential Change of Ferrocenylthiol Monolayers Induced by Atomic Force Microscopy2009

    • Author(s)
      T.Ichii, et al.
    • Journal Title

      Jpn.J.Appl.Phys. 8

    • NAID

      210000067321

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Soft Processing for Formation of SAM on Hydrogen-Terminated Silicon Surface Based on Visible-Light Excitation2009

    • Author(s)
      Hikaru Sano, et al.
    • Journal Title

      J. Vac. Sci. Technol. A 27

      Pages: 858-862

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembled Monolayers Directly Attached on Silicon Substrates Formed from 1-Hexadecene by Thermal, Ultra-Violet and Visible Light Activation Methods2008

    • Author(s)
      H.Sano, Hajime Maeda, Satoshi Matsuoka, K.Lee, K.Murase, H.Sugimura
    • Journal Title

      Jpn.J.Appl.Phys. Vol.47 No.7

      Pages: 5659-5664

    • NAID

      120001887651

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembled Monolayers Directly Attached on Silicon Substrates Formed from 1-Hexadecene by Thermal, Ultra-Violet and Visible Light Activation2008

    • Author(s)
      Hikaru Sano, et al.
    • Journal Title

      Jpn. J. Appl. Phys. 47

      Pages: 5659-5664

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Photochemical Bonding of Ferrocenyl Monolayers on Si(111) Surface2010

    • Author(s)
      H.Sugimura, 他
    • Organizer
      13th International Conference on Organized Molecular Films
    • Place of Presentation
      Quebec City, Canada
    • Year and Date
      2010-07-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] Redox Behaviors of Ferrocene Derivatives Directly Anchored on Si(111) by Different Tethering Bonds2010

    • Author(s)
      K.Murase, M.Zhao, T.Ichii, H.Sugimura
    • Organizer
      61th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Nice, France
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Photochemical Bonding of Ferrocenyl Monolayers on Si(111) Surface2010

    • Author(s)
      H.Sugimura, D.Kasahara, M.Zhao, H.Sano, T.Ichii, K.Murase
    • Organizer
      13th International Conference on Organized Molecular Films (LB13)Oral Presentation on 21th July
    • Place of Presentation
      Quebec City, Canada.
    • Related Report
      2010 Final Research Report
  • [Presentation] Electrochemical Behaviors of Ferrocene Derevatives Anchored on Silicon(111) by Different Tethering Bonds2009

    • Author(s)
      Mingxiu Zhao, et al.
    • Organizer
      216th The Electrochemical Society (ECS) Meeting
    • Place of Presentation
      Vienna, Austria
    • Year and Date
      2009-10-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] フェロセン誘導体分子によるシリコン直接結合型SAM形成および電気化学2009

    • Author(s)
      趙, 他
    • Organizer
      日本金属学会 2009年秋期(第145回)大会
    • Place of Presentation
      京都
    • Year and Date
      2009-09-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] Self-assembled monolayers formed from ferrocene derivatives on hydrogen-terminated Si(111)by visible light irradiation2009

    • Author(s)
      Mingxiu Zhao, et al.
    • Organizer
      Fifth International Conference on Molecular Electronics and Bioelectronics (M&BE5)
    • Place of Presentation
      Miyazaki
    • Year and Date
      2009-03-16
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrochemical Behaviors of Ferrocene Derevatives Anchored on Silicon(111) by Different Tethering Bonds,2009

    • Author(s)
      M.Zhao, H.Sano, T.Ichii, K.Murase, H.Sugimura
    • Organizer
      216th The Electrochemical Society(ECS)Meeting
    • Place of Presentation
      Vienna, Austria
    • Related Report
      2010 Final Research Report
  • [Presentation] Self-assembled monolayers of ferrocene derivatives on hydrogen-terminated Si(111) fomed by visible light irraditaion2009

    • Author(s)
      M.Zhao, D.Kasahara, H.Sano, T.Ichii, K.Murase,H.Sugimura
    • Organizer
      Fifth Internatioal Conference on Molecular Electronics and Buoelectronics ABSTRACTS 134
    • Place of Presentation
      Miyazaki, Japan
    • Related Report
      2010 Final Research Report
  • [Presentation] Photochemical Reaction on Hydrogen-Terminated Silicon for Self-Assembled Monolayer Formation2008

    • Organizer
      The 2nd Japan-Taiwan Joint Symposium on Organized Nanomaterials and Nanostructures Related to Photoscience(Invited)
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2010 Final Research Report
  • [Presentation] Soft Processing for Formation of SAM on Hydrogen-Terminated Silicon Surface Based on Visible-Light Excitation2008

    • Author(s)
      H.Sano, T.Yaku, T.Ichii, K.Murase, H.Sugimura
    • Organizer
      International Conference on Nanoscience + Technology (ICN+T)2008
    • Place of Presentation
      Keystone Resort&Conference Center, Keystone, Colorado, USA
    • Related Report
      2010 Final Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.mtl.kyoto-u.ac.jp/groups/sugimura-g/

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.mt1.kyoto-u.ac.jp/groups/sugimura-g/

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.mtl.kyoto-u.ac.jp/groups/sugimura-g/

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi