| Budget Amount *help |
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2010: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2009: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2008: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
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| Research Abstract |
Hybrid-type domino radical reactions of conjugated imine as a conjugated p-system were newly developed via the route involving various types of chemical species such as radical, ion, and organometallic species. Efficient synthetic methodology for highly functionalized products was developed via environmentally benign oxidation and radical-ionic domino reaction both of which proceeded via trapping the intermediates by atmospheric oxygen and appropriate electrophiles. Particularly, we were able to isolate unexpected reaction intermediates and thus succeeded in the development of powerful synthetic methods for various types of versatile and potential compounds by only one-manipulation.
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