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Chirality Control of "Asymmetric Oxygen Atom" generated by Metal Ion Coordination

Research Project

Project/Area Number 20550065
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionNara Women's University

Principal Investigator

MIKATA Yuji  Nara Women's University, 共生科学研究センター, 准教授 (10252826)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2008: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords金属錯体化学 / 不斉酸素原子 / 金属配位 / 金属錯体 / エーテル酸素 / キラリティー / 不斉配位 / 不斉炭素原子 / ジアステレオマー / 不斉窒素原子
Research Abstract

In this project, by careful design of the ligand and the selection of metal ion, we are going to clarify the possibility of the chirality generated on the metal-coordinated oxygen atom and its limitation, proposing the brand-new concept of "Asymmetric Oxygen". By appropriate design of the ligand, we are going to isolate and characterize the enantiomer based on exclusively "Asymmetric Oxygen". At the same time, we are going to analyze the physical properties of the compound in order to find possible application of "Asymmetric Oxygen".
At first, we examined the possible factors that are necessary to coordinate the achiral oxygen atom to the metal center. On the basis of this study, we constructed the system in which asymmetric oxygen and asymmetric nitrogen are generated simultaneously in the complex, and found that the configuration of the asymmetric nitrogen controls the configuration of the asymmetric oxygen. Furthermore, we succeeded in generating asymmetric oxygen atom using a ligand with an asymmetric carbon atom in various positions. X-ray crystallography of copper complexes revealed that the configuration of asymmetric oxygen controls the configuration of asymmetric oxygen atom. The chiral complexes exhibited characteristic Cotton effect in the d-d transition region of copper atom. This indicates that the configuration of asymmetric oxygen is preserved in solution state.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (82 results)

All 2011 2010 2009 2008

All Journal Article (42 results) (of which Peer Reviewed: 42 results) Presentation (40 results)

  • [Journal Article] Crystal structures and chiral recognition of the diastereomeric salts prepared from 2-methoxy-2-(1-naphthyl)propanoic acid2011

    • Author(s)
      A.Ichikawa, H.Ono, T.Echigo, Y.Mikata
    • Journal Title

      CrystEngComm in press

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Methoxyquinolinediethylenetriamine conjugate as a fluorescent zinc sensor2011

    • Author(s)
      Y.Mikata, A.Yamashita, K.Kawata, H.Konno, S.Itami, K.Yasuda, S.Tamotsu
    • Journal Title

      Dalton Transactions in press

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intramolecular Ether Oxygen Coordination in the Zinc Complexes with Dipicolylamine (DPA)-Derived Ligands2011

    • Author(s)
      Y.Mikata, T.Fujimoto, T.Fujiwara, S.Kondo
    • Journal Title

      Inorg.Chim.Acta in press

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Methoxy-substituted isoTQEN family for enhanced fluorescence response toward zinc ion2011

    • Author(s)
      Y.Mikata, A.Yamashita, K.Kawata, H.Konno, S.Itami, K.Yasuda, S.Tamotsu
    • Journal Title

      Dalton Transactions 40(16)

      Pages: 4055-4066

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Bismuth heterocycles based on a diphenyl sulfone scaffold : Synthesis and substituent effect on the antifungal activity against Saccharomyces cerevisiae2011

    • Author(s)
      T.Murafuji, Y.Fujiwara, D.Yoshimatsu, I.Miyakawa, K.Migita, Y.Mikata
    • Journal Title

      Eur.J.Med.Chem. 46

      Pages: 519-525

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structures and chiral recognition of the diastereomeric salts prepared from 2-methoxy-2-(1-naphthyl)-propanoic acid2011

    • Author(s)
      A.Ichikawa, H.Ono, T.Echigo, Y.Mikata
    • Journal Title

      CrystEngComm

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Methoxyquinoline-diethylenetriamine conjugate as a fluorescent zinc sensor2011

    • Author(s)
      Y.Mikata, A.Yamashita, K.Kawata, H.Konno, S.Itami, K.Yasuda, S.Tamotsu
    • Journal Title

      Dalton Transactions

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intramolecular Ether Oxygen Coordination in the Zinc Complexes with Dipicolylamine (DPA)-Derived Ligands2011

    • Author(s)
      Y.Mikata, T.Fujimoto, T.Fujiwara, S.Kondo
    • Journal Title

      Inorg.Chim.Acta

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Methoxy-substituted isoTQEN family for enhanced fluorescence response toward zinc ion2011

    • Author(s)
      Y.Mikata, A.Yamashita, K.Kawata, H.Konno, S.Itami, K.Yasuda, S.Tamotsu
    • Journal Title

      Dalton Transactions

      Volume: 40 Pages: 4059-4066

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bismuth heterocycles based on a diphenyl sulfone scaffold : Synthesis and substituent effect on the antifungal activity against Saccharomyces cerevisiae2011

    • Author(s)
      T.Murafuji, Y.Fujiwara, D.Yoshimatsu, I.Miyakawa, K.Migita, Y.Mikata
    • Journal Title

      Eur.J.Med.Chem.

      Volume: 46 Pages: 519-525

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lewis Acid Promoted Reactions of Ethenetricarboxylates with Allenes : Synthesis of Indenes and γ-Lactones via Conjugate Addition/Cyclization Reaction2010

    • Author(s)
      S.Yamazaki, Y.Yamamoto, Y.Fukushima, M.Takebayashi, T.Ukai, Y.Mikata
    • Journal Title

      J.Org.Chem. 75(15)

      Pages: 5216-5222

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cationic technetium and rhenium complexes with pendant carbohydrates2010

    • Author(s)
      C.L.Ferreira, F.L.N.Marques, M.R.Y.Okamoto, A.H.Otake, Y.Sugai, Y.Mikata, T.Storr, M.Bowen, S.Yano, M.J.Adam, R.Chammas, C.Orvig
    • Journal Title

      Appl.Radiat.Isotopes 68(6)

      Pages: 1087-1093

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal conformations and molecular packing of (S)-2-methoxy-2-(9-phenanthryl)propanoic acid and a diastereomeric amide prepared from (R)-2-methoxy-2-(1-naphthyl)propanoic acid2010

    • Author(s)
      A.Ichikawa, H.Ono, M.Takenaka, Y.Mikata
    • Journal Title

      CrystEngComm. 12(7)

      Pages: 2261-2268

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Control of aggregation property of tris(maltohexaose)-linked porphyrins with an alkyl chain2010

    • Author(s)
      Y.Mikata, T.Sawaguchi, T.Kakuchi, M.Gottschaldt, U.S.Schubert, H.Ohi, S.Yano
    • Journal Title

      Eur.J.Org.Chem.

      Pages: 663-671

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Lewis Acid Promoted Reactions of Ethenetricarboxylates with Allenes : Synthesis of Indenes and γ-Lactones via Conjugate Addition/Cyclization Reaction2010

    • Author(s)
      S.Yamazaki, Y.Yamamoto, Y.Fukushima, M.Takebayashi, T.Ukai, Y.Mikata
    • Journal Title

      J.Org.Chem.

      Volume: 75 Pages: 5216-5222

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cationic technetium and rhenium complexes with pendant carbohydrates2010

    • Author(s)
      C.L.Ferreira, F.L.N.Marques, M.R.Y.Okamoto, A.H.Otake, Y.Sugai, Y.Mikata, T.Storr, M.Bowen, S.Yano, M.J.Adam, R.Chammas, C.Orvig
    • Journal Title

      Appl.Radiat.Isotopes

      Volume: 68 Pages: 1087-1093

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal conformations and molecular packing of (S)-2-methoxy-2-(9-phenanthryl)propanoic acid and a diastereomeric amide prepared from (R)-2-methoxy-2-(1-naphthyl)propanoic acid2010

    • Author(s)
      A.Ichikawa, H.Ono, M.B.Takenaka, Y.C.Mikata
    • Journal Title

      CrystEngComm

      Volume: 12 Pages: 2261-2268

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of aggregation property of tris(maltohexaose)-linked porphyrins with analkyl chain2010

    • Author(s)
      Y.Mikata, T.Sawaguchi, T.Kakuchi, M.Gottschaldt, U.S.Schubert, H.Ohi, S.Yano
    • Journal Title

      Eur.J.Org.Chem.

      Pages: 663-671

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Antioxidant action of sugar-pendant C60 fullerenes2009

    • Author(s)
      M.Horie, A.Fukuhara, Y.Saito, Y.Yoshida, H.Sato, H.Ohi, M.Obata, Y.Mikata, S.Yano, E.Niki
    • Journal Title

      Bioorg.Med.Chem.Lett. 19(20)

      Pages: 5902-5904

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Copper(II) and zinc(II) complexes with C-glycoside-pendant dipicolylamine (DPA)-amino acid conjugates2009

    • Author(s)
      Y.Mikata, S.Fujii, M.Naemura, K.Takahashi, Y.Noguchi
    • Journal Title

      Dalton Trans. (46)

      Pages: 10305-10310

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Zinc-Catalyzed Reactions of Ethenetricarboxylates with 2-(Trimethylsilylethynyl) anilines Leading to Bridged Quinoline Derivatives2009

    • Author(s)
      S.Yamazaki, S.Morikawa, K.Miyazaki, M.Takebayashi, Y.Yamamoto, T.Morimoto, K.Kakiuchi, Y.Mikata
    • Journal Title

      Org.Lett. 11(13)

      Pages: 2796-2799

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Bisquinoline-based fluorescent zinc sensors2009

    • Author(s)
      Y.Mikata, A.Yamashita, A.Kawamura, H.Konno, Y.Miyamoto, S.Tamotsu
    • Journal Title

      Dalton Trans. (19)

      Pages: 3800-3806

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Lewis acid-promoted reactions of ethenetricarboxylates with γ-CF_3-substituted propargyl alcohols2009

    • Author(s)
      S.Yamazaki, Y.Yamamoto, Y.Mikata
    • Journal Title

      Tetrahedron 65(10)

      Pages: 1988-1994

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and conformational analysis of C-glycosyl β-and β/β-peptides2009

    • Author(s)
      Y.Inaba, T.Kawakami, S.Aimoto, T.Ikegami, T.Takeuchi, T.Nakazawa, S.Yano, Y.Mikata
    • Journal Title

      Carbohydr.Res. 344(5)

      Pages: 613-626

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Feasible attachment of dinuclear ruthenium complex to gold electrode surface via new ligand substitution reaction2009

    • Author(s)
      H.Takagi, Y.Mikata, A.Ichimura, T.Yano, I.Kinoshita, M.Hori, T.J.Collins, M.Gottschaldt, S.Yano
    • Journal Title

      Electochimica Acta 54(4)

      Pages: 1286-1291

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Antioxidant action of sugar-pendant C60 fullerenes2009

    • Author(s)
      M.Horie, A.Fukuhara, Y.Saito, Y.Yoshida, H.Sato, H.Ohi, M.Obata, Y.Mikata, S.Yano, E.Niki
    • Journal Title

      Bioorg.Med.Chem.Lett. 19

      Pages: 5902-5904

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper(II) and zinc(II) complexes with C-glycoside-pendant dipicolylamine (DPA)-amino acid conjugates2009

    • Author(s)
      Y.Mikata, S.Fujii, M.Naemura, K.Takahashi, Y.Noguchi
    • Journal Title

      Dalton Trans.

      Pages: 10305-10310

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Zinc-Catalyzed Reactions of Ethenetricarboxylates with 2-(Trimethylsilylethynyl) anilines Leading to Bridged Quinoline Derivatives2009

    • Author(s)
      S.Yamazaki, S.Morikawa, K.Miyazaki, M.Takebayashi, Y.Yamamoto, T.Morimoto, K.Kakiuchi, Y.Mikata
    • Journal Title

      Org.Lett. 11

      Pages: 2796-2799

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bisquinoline-based fluorescent zinc sensors2009

    • Author(s)
      Y. Mikata, A. Yamashita, A. Kawamura, H. Konno, Y. Miyamoto, S. Tamotsu
    • Journal Title

      Dalton Trans. (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lewis acid-promoted reactions of ethenetricarboxylates with γ-CF_3-substituted propargyl alcohols2009

    • Author(s)
      S. Yamazaki, Y. Yamamoto, Y. Mikata
    • Journal Title

      Tetrahedron 65

      Pages: 1988-1994

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and conformational analysis of C-glycosyl β^2- and β/β^2-peptides2009

    • Author(s)
      Y. Inaba, T. Kawakami, S. Aimoto, T. Ikegami, T. Takeuchi, T. Nakazawa, S. Yano, Y. Mikata
    • Journal Title

      Carbohydr. Res. (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Feasible attachment of dinuclear ruthenium complex to gold electrodesurface via new ligand substitution reaction2009

    • Author(s)
      H. Takagi, Y. Mikata, A. Ichimura, T. Yano. I. Kinoshita, M. Hori. T. J. Collins, M. Gottschaldt, S. Yano
    • Journal Title

      Electochimica Ada 54

      Pages: 1286-1291

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characteristic conformations and molecular packings in crystal structures of diastereomeric esters prepared from (S)-2-methoxy-2-(1-naphthyl)propanoic acid2008

    • Author(s)
      A.Ichikawa, H.Ono, Y.Mikata
    • Journal Title

      Tetrahedron : Asymmetry 19(23)

      Pages: 2693-2698

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Isoquinoline-Based TQEN Family as TPEN-Derived Fluorescent Zinc Sensors2008

    • Author(s)
      Y.Mikata, A.Yamanaka, A.Yamashita, S.Yano
    • Journal Title

      Inorg.Chem. 47(16)

      Pages: 7295-7301

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses, structural characterization and photophysical properties of 4-(2-pyridyl)-1, 2, 3-triazole rhenium(I) complexes2008

    • Author(s)
      M.Obata, A.Kitamura, A.Mori, C.Kameyama, J.Czaplewska, R.Tanaka, I.Kinoshita, T.Kusumoto, H.Hashimoto, M.Harada, Y.Mikata, T.Funabiki, S.Yano
    • Journal Title

      Dalton Trans. (25)

      Pages: 3292-3300

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] A general route to pendant C-glycosyl 1, 2-and 1, 3-diamines2008

    • Author(s)
      Y.Inaba, T.Fujimoto, H.Ono, M.Obata, S.Yano, Y.Mikata
    • Journal Title

      Carbohydr.Res. 343(5)

      Pages: 941-950

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of C-glycoside pendant β2-and β2, 2-amino acids2008

    • Author(s)
      Y.Inaba, S.Yano, Y.Mikata
    • Journal Title

      Bull.Chem.Soc.Jpn. 81(5)

      Pages: 606-616

    • NAID

      10021075522

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characteristic conformations and molecular packings in crystal structures of diastereomeric esters prepared from (S)-2-methoxy-2-(1-naphthyl)propanoic acid2008

    • Author(s)
      A. Ichikawa. H. Ono, Y. Mikata
    • Journal Title

      Tetrahedron : Asymmetry 19

      Pages: 2693-2698

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Isoquinoline-Based TQEN Family as TPEN-Derived Fluorescent Zinc Sensors2008

    • Author(s)
      Y. Mikata, A. Yamanaka, A. Yamashita, S. Yano
    • Journal Title

      Inorg. Chem. 47

      Pages: 7295-7301

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses, structural characterization and photophysical properties of 4-(2-pyridyl)-l, 2, 3-triazole rhenium(I)complexes2008

    • Author(s)
      M. Obata. A. Kitamura, A. Mori, C. Kameyama, J. Czaplewska, R. Tanaka, I. Kinoshita, T. Kusumoto, H. Hashimoto, M. Harada, Y. Mikata, T. Funabiki, S. Yano
    • Journal Title

      Dalton Trans.

      Pages: 3292-3300

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A general route to pendant C-glycosyl 1, 2- and 1, 3-diamines2008

    • Author(s)
      Y. Inaba, T. Fujimoto, H. Ono, M. Obata, S. Yano, Y. Mikata
    • Journal Title

      Carbohydr. Res. 343

      Pages: 941-950

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of C-glycoside pendant β^2-and β^<2, 2>-amino acids2008

    • Author(s)
      Y. Inaba, S. Yano, Y. Mikata
    • Journal Title

      Bull. Chem. Soc. Jpn. 81

      Pages: 606-616

    • NAID

      10021075522

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] キノリン部位を有する糖含有エチレンジアミン誘導体の亜鉛イオン選択的蛍光応答2011

    • Author(s)
      鵜飼杏奈・三方裕司
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      東京
    • Year and Date
      2011-03-28
    • Related Report
      2010 Final Research Report
  • [Presentation] 複素環芳香族置換グリシン誘導体を配位子とする金属錯体の合成と構造2011

    • Author(s)
      河田景子・三方裕司
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      東京
    • Year and Date
      2011-03-26
    • Related Report
      2010 Final Research Report
  • [Presentation] 複素環芳香族置換グリシン誘導体を配位子とする金属錯体の合成と構造2011

    • Author(s)
      河田景子・三方裕司
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] キノリン部位を有する糖含有エチレンジアミン誘導体の亜鉛イオン選択的蛍光応答2011

    • Author(s)
      鵜飼杏奈・三方裕司
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mercury(II)-selective fluorescent response of bisquinoline derivatives with thioether linkage.2010

    • Author(s)
      三方裕司, 中垣芙美恵
    • Organizer
      Pacifichem 2010 Congress
    • Place of Presentation
      Waikiki, USA
    • Year and Date
      2010-12-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Fluorescent response of isoquinoline-based amine derivatives toward zinc ion.2010

    • Author(s)
      河田景子, 三方裕司
    • Organizer
      Pacifichem 2010 Congress
    • Place of Presentation
      Waikiki, USA
    • Year and Date
      2010-12-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Carbohydrate-appended metal complexes for enhanced cellular uptake of metal ion.2010

    • Author(s)
      三方裕司, 野口友華, 高橋京子
    • Organizer
      Pacifichem 2010 Congress
    • Place of Presentation
      Waikiki, USA
    • Year and Date
      2010-12-16
    • Related Report
      2010 Final Research Report
  • [Presentation] Quinoline-and isoquinoline-based molecular design for functional metal complexes.2010

    • Author(s)
      三方裕司
    • Organizer
      17th International SPACC-CSJ Symposium
    • Place of Presentation
      Kagoshima INVITED LECTURE
    • Year and Date
      2010-10-15
    • Related Report
      2010 Final Research Report
  • [Presentation] 亜鉛イオン特異的蛍光応答を示すトリス(1-イソキノリルメチル)アミン誘導体の開発2010

    • Author(s)
      河田景子・三方裕司
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-29
    • Related Report
      2010 Final Research Report
  • [Presentation] 金属の細胞内導入を目指した糖含有配位子の開発2010

    • Author(s)
      高橋京子・三方裕司
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-28
    • Related Report
      2010 Final Research Report
  • [Presentation] 糖含有配位子を用いた細胞への金属イオン導入2010

    • Author(s)
      高橋京子・三方裕司
    • Organizer
      第4回バイオ合同シンポジウム
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-25
    • Related Report
      2010 Final Research Report
  • [Presentation] エーテル酸素原子が金属中心に配位した亜鉛錯体の合成と構造2010

    • Author(s)
      藤原知美・三方裕司
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2010 Final Research Report
  • [Presentation] エーテル酸素原子が金属中心に配位した亜鉛錯体の合成と構造2010

    • Author(s)
      藤原知美・三方裕司
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪府)
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] イソキノリン部位を有するアミン誘導体の亜鉛イオン選択的蛍光応答2010

    • Author(s)
      河田景子・三方裕司
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-27
    • Related Report
      2010 Final Research Report
  • [Presentation] キノリン骨格を有するアルカンチオエーテル配位子の水銀(II)イオン選択的蛍光応答2010

    • Author(s)
      中垣芙美恵・三方裕司
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-27
    • Related Report
      2010 Final Research Report
  • [Presentation] キノリン骨格を有するアルカンチオエーテル配位子の水銀(II)イオン選択的蛍光応答2010

    • Author(s)
      中坦芙美恵・三方裕司
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪府)
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] イソノリン部位を有するアミン誘導体の亜鉛イオン選択的蛍光応答2010

    • Author(s)
      河田景子・三方裕司
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪府)
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 生物学的応用を目的とした糖含有配位子の開発2010

    • Author(s)
      野口友華・三方裕司
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-26
    • Related Report
      2010 Final Research Report
  • [Presentation] 生物学的応用を目的とした糖含有配位子の開発2010

    • Author(s)
      野口友華・三方裕司
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪府)
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] Quinoline- and isoquinoline-based molecular design for functional metal complexes2010

    • Author(s)
      Y.Mikata
    • Organizer
      17th International SPACC-CSJ Symposium
    • Place of Presentation
      Kagoshima University
    • Related Report
      2010 Annual Research Report
  • [Presentation] Carbohydrate-appended metal complexes for enhanced cellular uptake of metal ion2010

    • Author(s)
      Y.Mikata, Y.Noguchi, K.Takahashi
    • Organizer
      Pacifichem 2010 Congress
    • Place of Presentation
      Hawaii Convention Center
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mercury(II)-selective fluorescent response of bisquinoline derivatives with thioether linkage2010

    • Author(s)
      Y.Mikata, F.Nakagaki
    • Organizer
      Pacifichem 2010 Congress
    • Place of Presentation
      Hawaii Convention Center
    • Related Report
      2010 Annual Research Report
  • [Presentation] Fluorescent response of isoquinoline-based amine derivatives toward zinc ion2010

    • Author(s)
      K.Kawata, Y.Mikata
    • Organizer
      Pacifichem 2010 Congress
    • Place of Presentation
      Hawaii Convention Center
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金属の細胞内導入を目指した糖含有配位子の開発2010

    • Author(s)
      高橋京子・三方裕司
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪国際交流センター
    • Related Report
      2010 Annual Research Report
  • [Presentation] 亜鉛イオン特異的蛍光応答を示すトリス(1-イソキノリルメチル)アミン誘導体の開発2010

    • Author(s)
      河田景子・三方裕司
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪国際交流センター
    • Related Report
      2010 Annual Research Report
  • [Presentation] 糖含有配位子を用いた細胞への金属イオン導入2010

    • Author(s)
      高橋京子・三方裕司
    • Organizer
      第4回バイオ合同シンポジウム
    • Place of Presentation
      大阪大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] キノリン骨格を有するチオエーテル配位子の水銀イオンに対する蛍光応答2009

    • Author(s)
      中垣芙美恵・三方裕司
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎
    • Year and Date
      2009-09-26
    • Related Report
      2010 Final Research Report
  • [Presentation] キノリン骨格を有するチオエーテル配位子の水銀イオンに対する蛍光応答2009

    • Author(s)
      中坦芙美恵・三方裕司
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2009-09-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] 新規糖含有アニオン性配位子を用いた金属錯体の開発2009

    • Author(s)
      野口友華・三方裕司
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎
    • Year and Date
      2009-09-25
    • Related Report
      2010 Final Research Report
  • [Presentation] 新規糖含有アニオン性配位子を用いた金属錯体の開発2009

    • Author(s)
      野口友華・三方裕司
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2009-09-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] The Isoquinoline-Based TQEN Family as TPEN-Derived Fluorescent Zinc Sensors.2009

    • Author(s)
      三方裕司
    • Organizer
      ICBIC
    • Place of Presentation
      Nagoya
    • Year and Date
      2009-07-27
    • Related Report
      2010 Final Research Report
  • [Presentation] The Isoquinoline-Based TQEN Family as TPEN-Derived Fluorescent Zinc Sensors2009

    • Author(s)
      Y.Mikata
    • Organizer
      14th International Conference on Biological Inorganic Chemistry (ICBIC)
    • Place of Presentation
      Nagoya conference center
    • Year and Date
      2009-07-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] The TQEN (Tetrakis(2-quinolylmethylethylenedia mine)) Family as Fluorescent Zinc Sensors.2009

    • Author(s)
      三方裕司
    • Organizer
      PPC 2009
    • Place of Presentation
      Shiga INVITED LECTURE
    • Year and Date
      2009-07-10
    • Related Report
      2010 Final Research Report
  • [Presentation] Development of Isoquinoline-Based Fluorescent Zinc Sensor with High Affinity.2008

    • Author(s)
      山下梓, 三方裕司
    • Organizer
      14th International SPACC-CSJ Symposium
    • Place of Presentation
      Osaka
    • Year and Date
      2008-11-20
    • Related Report
      2010 Final Research Report
  • [Presentation] Development of Carbohydrate-Based Ligand Bearing N-(2-Pyridylmethyl)glycine Frame.2008

    • Author(s)
      野口友華, 三方裕司
    • Organizer
      14th International SPACC-CSJ Symposium
    • Place of Presentation
      Osaka
    • Year and Date
      2008-11-20
    • Related Report
      2010 Final Research Report
  • [Presentation] Design for Hg-selective fluorescent probes with alkanedithiol scaffold.2008

    • Author(s)
      中垣芙美恵, 三方裕司
    • Organizer
      14th International SPACC-CSJ Symposium
    • Place of Presentation
      Osaka
    • Year and Date
      2008-11-20
    • Related Report
      2010 Final Research Report
  • [Presentation] メトキシイソキノリン部位を有するエチレンジアミン誘導体の亜鉛イオンに対する蛍光応答2008

    • Author(s)
      山下梓・三方裕司
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢
    • Year and Date
      2008-09-20
    • Related Report
      2010 Final Research Report
  • [Presentation] メトキシイソキノリン部位を有するエチレンジアミン誘導体の亜鉛イオンに対する蛍光応答2008

    • Author(s)
      山下梓, 三方裕司
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] 高い親和性を有する蛍光性亜鉛イオンキレーターの開発2008

    • Author(s)
      三方裕司・山中あずさ・山下梓
    • Organizer
      第3回バイオ関連化学合同シンポジウム
    • Place of Presentation
      横浜
    • Year and Date
      2008-09-19
    • Related Report
      2010 Final Research Report
  • [Presentation] 高い親和性を有する蛍光性亜鉛イオンキレークーの開発2008

    • Author(s)
      三方裕司, 山中あずさ, 山下梓
    • Organizer
      第3回バイオ関連化学合同シンポジウム
    • Place of Presentation
      東京工業大学
    • Year and Date
      2008-09-19
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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