Self-assembly of novel metallamacrocycles as a functional anion receptors
| Project/Area Number |
20550069
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | Kinki University |
|---|
Principal Investigator |
MAEKAWA Masahiko Kinki University, 理工学総合研究所, 教授 (70229293)
|
|---|
| Project Period (FY) |
2008 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
|
|---|
| Keywords | Cu(I)錯体 / エチレン付加体 / 配位高分子 / メタラマクロサイクリック / アニオンレセプター / 自己集積化 / 分子認識 / Cu(I)ハライド / 架橋窒素配位子 / X線構造解析 / 熱重量分析 / π-πスタックキング / 水素結合 / 銅錯体 / カルボニル付加体 |
|---|
| Research Abstract |
The C2H4 adducts of novel 13 Cu(I) coordination polymers and metallamacrocycles were self-assembled by the combinations of parent Cu(I) complexes with different counter anions and three 4,4'-bipyrimidine derivatives. The roles of counter anions and reaction solvents were systematically proved in the formation processes. These new compounds are expected to become as a potential anion receptor. In addition, thermally stable polynuclear Cu(I) ethylene adducts are useful to construct the chemical adsorption and the catalytic reaction sites.
|
Report
(4 results)
Research Products
(29 results)
-
-
-
-
-
-
[Journal Article] Eur.J.Inorg.Chem.2009
Author(s)
M. Maekawa, T.Tominaga, T.Okubo, T.Kuroda-Sowa, M.Munakata
-
Journal Title
Novel Cu(I) ethylene complexes with 6,6'-diphenyl-4,4'-bipyrimidine three-dimensionally self-assembled by an intermolecular π-π stacking interaction and a C-H…N contact (28)
Pages: 4225-4231
Related Report
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
