Supramolecular Synthetic Chemistry Constructed for Giant and Complicated Functional Systems

• Project/Area Number: 20550098
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Synthetic chemistry
• Research Institution: Nara Institute of Science and Technology
• Principal Investigator: SATAKE Akiharu Nara Institute of Science and Technology, 理学部・第二部化学科, 准教授 (00277831)
• Project Period (FY): 2008 – 2011
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2008: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
• Keywords: 超分子化学 / 超分子合成化学 / ポルフィリン / 光捕集アンテナ / 超分子 / ナノ化学 / 光合成

Research Abstract

Some supramolecular systems based on porphyrin derivatives have been constructed. Trisporphyrin derivatives gave supramolecular nanoring spontaneously. Supramolecular composites of the nanoring and energy acceptors were produced by complementary metal-ligand coordination. Tube-like supramolecular structures were also constructed from porphrin nanorings having six benzoic acid groups by complementary hydrogen bondings. These results must contribute to artificial photosynthesis and nanochemistry.

Research Products

• [Journal Article] Supramolecular Organization of Light-Harvesting Porphyrin Macrorings (2011)
  • Author(s): Akiharu Satake, Shintaro Azuma, Yusuke Kuramochi, Shun Hirota, Yoshiaki Kobuke,
  • Journal Title: Chem.Eur.J. 17 Pages: 855-865
  • NAID: 130004597311
• [Journal Article] Supramolecular Organization of Light-Harvesting Porphyrin Macrorings (2011)
  • Author(s): Akiharu Satake
  • Journal Title: Chem.Eur.J. Volume: 17 Pages: 855-865
  • NAID: 130004597311
  • Peer Reviewed
• [Journal Article] Coordination-induced sliding motion of a complementary porphyrin-phthalocyanine dimer : fluorescence-based molecular switch (2009)
  • Author(s): Akiharu Satake, Toshimasa Sugimura, Yoshiaki Kobuke
  • Journal Title: J.Porphyrins and Phthalocyanines 13 Pages: 326-335
• [Journal Article] Energy transfer followed by electron transfer in a porphyrin macrocycle and central acceptor ligand : A model for a photosynthetic composite of the light-harvesting complex and reaction center (2009)
  • Author(s): Yusuke Kuramochi, Atula S.D. Sandanayaka, Akiharu Satake, Yasuyuki Araki, Kazuya Ogawa, Osamu Ito, Yoshiaki Kobuke
  • Journal Title: Chem.Eur.J. 15 Pages: 2317-2327
• [Journal Article] Single Supramolecular Porphyrin Wires Bridging Gold Nanoparticles (2009)
  • Author(s): Akiharu Satake, Masakuni Fujita, Yusuke Kurimoto, Yoshiaki Kobuke
  • Journal Title: Chem.Commun. Pages: 1231-1233
• [Journal Article] Coordination-induced sliding motion of a complementary porphyrin-phthalocyanine dimer : fluorescence-based molecular switch (2009)
  • Author(s): Akiharu Satake
  • Journal Title: J.Porphyrins and Phthalocyanines 13 Pages: 326-335
• [Journal Article] Energy transfer followed by electron transfer in a porphyrin macrocycle and central acceptor ligand : A model for a photosynthetic composite of the light-harvesting complex and reaction center (2009)
  • Author(s): Yusuke Kuramochi
  • Journal Title: Chem. Eur. J. 15 Pages: 2317-2327
  • Peer Reviewed
• [Journal Article] Single Supramolecular Porphyrin Wires Bridging Gold Nanoparticles (2009)
  • Author(s): Akiharu Satake
  • Journal Title: Chem. Commun. Pages: 1231-1233
  • Peer Reviewed
• [Journal Article] Construction of Giant Porphyrin Macrorings Self-Assembled from Thiophenylene-Linked Bisporphyrins for Light-Harvesting Antennae (2008)
  • Author(s): Kaori Fujisawa, Akiharu Satake, Shun Hirota, Yoshiaki Kobuke
  • Journal Title: Chem.Eur.J. 14 Pages: 10735-10744
• [Journal Article] Stable Supramolecular Complex of Porphyrin Macroring with Pyridyl and Fullerenyl Ligands (2008)
  • Author(s): Zafer Uyar, Akiharu Satake, Yoshiaki Kobuke, Shun Hirota
  • Journal Title: Tetrahedron Lett. 49 Pages: 5484-5487
• [Journal Article] Transmembrane Nanopores from Porphyrin Supramolecules (2008)
  • Author(s): Akiharu Satake, Mika Yamamura, Masafumi Oda, Yoshiaki Kobuke
  • Journal Title: J.Am.Chem.Soc. 130 Pages: 6314-6315
• [Journal Article] Oxidation of Adamantane Catalysed by Imidazolylporphyrinatoiron (III) Complexes and Structural Studies of 5-Coordinating Iron(III) Porphyrin (2008)
  • Author(s): Yuji Miyazaki, Akiharu Satake, Yoshiaki Kobuke
  • Journal Title: J.Mol.Cat.A : Chemical. 283 Pages: 129-139
• [Journal Article] Light-Harvesting Supramolecular Porphyrin Macroring Accommodating a Fullerene-Tripodal Ligand (2008)
  • Author(s): Yusuke Kuramochi, Akiharu Satake, Mitsunari Itou, Kazuya Ogawa, Yasuyuki Araki, Osamu Ito, Yoshiaki Kobuke
  • Journal Title: Chem.Eur.J. 14 Pages: 2827-2841
• [Journal Article] Construction of Giant Porphyrin Macrorings Self-Assembled from Thiophenylene-Linked Bisporphyrins for Light-Harvesting Antennae (2008)
  • Author(s): Kaori Fujisawa
  • Journal Title: Chem. Eur. J. 14 Pages: 10735-10744
  • Peer Reviewed
• [Journal Article] Stable Supramolecular Complex of Porphyrin Macroring with Pyridyl and Fullerenyl Ligands (2008)
  • Author(s): Zafer Uyar
  • Journal Title: Tetrahedron Lett. 49 Pages: 5484-5487
  • Peer Reviewed
• [Presentation] ビス(クラウンベンズイミダゾール)の超分子二量体構造の置換基による影響 (2011)
  • Organizer: 第91回日本化学会春季年会
  • Year and Date: 2011-03-28
• [Presentation] ビス(クラウンベンズイミダゾール)の超分子二量体構造の置換基による影響 (2011)
  • Author(s): 朝倉大樹
  • Organizer: 第91回日本化学会春季年会
  • Place of Presentation: 東京
  • Year and Date: 2011-03-28
• [Presentation] ポルフィリン超分子を用いた光捕集アンテナの構築 (2011)
  • Organizer: 錯体超分子化学の研究会
  • Place of Presentation: 東京理科大学
  • Year and Date: 2011-01-08
• [Presentation] ポルフィリン超分子を用いた光捕集アンテナの構築 (2011)
  • Author(s): 佐竹彰治
  • Organizer: 東京理科大学 錯体超分子化学の研究会
  • Place of Presentation: 東京
  • Year and Date: 2011-01-08
• [Presentation] Supramolecular porphyrin systems-How to construct? How to confirm? (2010)
  • Organizer: N. Research Project Presents Mini Symposium on Supramolecules
  • Place of Presentation: Nihon University
  • Year and Date: 2010-11-11
• [Presentation] Supramolecular porphyrin systems-How to construct? How to confirm? (2010)
  • Author(s): 佐竹彰治
  • Organizer: Nihon University, "N." Research Project Presents Mini Symposium on Supramolecules
  • Place of Presentation: 東京
  • Year and Date: 2010-11-11
• [Presentation] パイ-アリルパラジウム錯体が連結した1,4-ベンゾキノンの合成と機能 (2010)
  • Organizer: 第60回錯体化学討論会
  • Year and Date: 2010-09-30
• [Presentation] パイ-アリルパラジウム錯体が連結した1,4-ベンゾキノンの合成と機能 (2010)
  • Author(s): 佐竹彰治
  • Organizer: 第60回錯体化学討論会
  • Place of Presentation: 大阪
  • Year and Date: 2010-09-30
• [Presentation] ビスクラウンイミダゾリルパラジウム錯体の超分子自己組織化 (2010)
  • Organizer: 日本化学会第90春季年会
  • Year and Date: 2010-03-26
• [Presentation] π-アリルパラジウム錯体を有する1,4-ベンゾキノンの合成と性質 (2010)
  • Organizer: 日本化学会第90春季年会
  • Year and Date: 2010-03-26
• [Presentation] ビスクラウンイミダゾリルパラジウム錯体の超分子自己組織化 (2010)
  • Author(s): 小田哲久
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学、東大阪
  • Year and Date: 2010-03-26
• [Presentation] \-アリルパラジウム錯体を有する1,4-ベンゾキノンの合成と性質 (2010)
  • Author(s): 桐山雅成
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学、東大阪
  • Year and Date: 2010-03-26
• [Presentation] ビスクラウンイミダゾリルパラジウム錯体の超分子自己組織化 (2009)
  • Organizer: 第59回錯体化学討論会
  • Year and Date: 2009-09-26
• [Presentation] ビスクラウンイミダゾリルパラジウム錯体の超分子自己組織化 (2009)
  • Author(s): 小田哲久
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎大学
  • Year and Date: 2009-09-26
• [Presentation] 超分子ポルフィリンナノリングの超分子組織化と光捕集アンテナ機能 (2009)
  • Organizer: 第59回錯体化学討論会
  • Year and Date: 2009-09-25
• [Presentation] 配位子にキノン基を有するη3-アリルパラジウム錯体の光還元と反応性 (2009)
  • Organizer: 第59回錯体化学討論会
  • Year and Date: 2009-09-25
• [Presentation] 超分子ポルフィリンナノリングの超分子組織化と光捕集アンテナ機能 (2009)
  • Author(s): 佐竹彰治
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎大学
  • Year and Date: 2009-09-25
• [Presentation] 配位子にキノン基を有するη^3-アリルパラジウム錯体の光還元と反応性 (2009)
  • Author(s): 桐山雅成
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎大学
  • Year and Date: 2009-09-25
• [Presentation] 超分子ポルフィリンナノリングのホストゲスト化学 (2009)
  • Organizer: 第5回ホスト・ゲスト化学シンポジウム
  • Year and Date: 2009-05-31
• [Presentation] 超分子ポルフィリンナノリングのホストゲスト化学 (2009)
  • Author(s): 佐竹彰治
  • Organizer: 第5回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 宇都宮大学
  • Year and Date: 2009-05-31
• [Presentation] マイカ基板に垂直固定化された超分子ポルフイリンナノチューブの原子間力顕微鏡観察 (2009)
  • Author(s): 佐竹 彰治
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日大、船橋
  • Year and Date: 2009-03-27
• [Presentation] The 8th GIST/NAIST Joint Symposium on Advanced Materials (2008)
  • Organizer: Dynamic Supramolecular Systems using Porphyrin-Phthalocyanine Dyads
  • Place of Presentation: Nara
  • Year and Date: 2008-11-27
• [Presentation] Dynamic Supramolecular Sys terns using Porphyrin-Phthalocyanine Dyads (2008)
  • Author(s): Akiharu Satake
  • Organizer: The 8th GIST/NAIST Joint Symposium on Advanced Materials
  • Place of Presentation: Nara Institute of Science and Technology, Nara
  • Year and Date: 2008-11-27
• [Presentation] 講演タイトル「超分子ポルフィリンリングの超分子化学」 (2008)
  • Organizer: 第39回錯体化学若手の会近畿地区勉強会
  • Place of Presentation: 阪大吹田
  • Year and Date: 2008-11-22
• [Presentation] 超分子ポルフィリンリングの超分子化学 (2008)
  • Author(s): 佐竹 彰治
  • Organizer: 第39回錯体化学若手の会近畿地区勉強会
  • Place of Presentation: 阪大、吹田
  • Year and Date: 2008-11-22
• [Presentation] キノンを有する二座窒素配位子を持つ η3-アリルパラジウム錯体の合成と反応性 (2008)
  • Author(s): 佐竹 彰治
  • Organizer: 第55回有機金属化学討論会
  • Place of Presentation: 大阪府立大、堺
  • Year and Date: 2008-09-29
• [Presentation] Fifth International Conference on Porphyrins and Phthalocyanines (ICPP-5) (2008)
  • Organizer: Coordination-induced selective transformation of complementary porphyrin-phthalocyanine dimer
  • Place of Presentation: Moscow
  • Year and Date: 2008-07-10
• [Presentation] Coordination-induced selective trans format ion of complementary porphyrin-phthalocyanine dimer (2008)
  • Author(s): Akiharu Satake
  • Organizer: Fifth Internat ional Conference on Porphyr ins and Phthalocyanines (ICPP-5)
  • Place of Presentation: Moscow
  • Year and Date: 2008-07-10
• [Presentation] 講演タイトル「カーボンナノチューブの修飾による分散化と複合機能材料の合成」 (2008)
  • Organizer: 技術情報協会「カーボンナノチューブ」セミナー
  • Place of Presentation: 北区王子北とぴあ
  • Year and Date: 2008-04-23
• [Book] 注目の論文「ベストパートナーは多くの出会いで探せ!」(化学、化学同人 65) (2010)
  • Author(s): 佐竹彰治
• [Remarks] ホームページ等
  • URL: http://www.rs.kagu.tus.ac.jp/sata_lab/
• [Remarks]
  • URL: http://mswebs.naist.jp/LABs/hirota/index.html