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Dehalogenation of Aryl halides mediated by macrocyclic metal complex catalysts.

Research Project

Project/Area Number 20550139
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental chemistry
Research InstitutionYokohama City University

Principal Investigator

MOTIDUKI Katura  Yokohama City University, 生命ナノシステム科学研究科, 教授 (60150562)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2008: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Keywords環状配位子 / 金属錯体 / 脱ハロゲン化 / 触媒
Research Abstract

We have synthesized some new macrocyclic metal complexes, which have been applied for the studies on metal-mediated dehalogenation of arly halides. In the course of this study, we have developed a new photochemical system for debromination of aryl bromides mediated by nickel(II) complexes with macrocyclic ligands.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (31 results)

All 2011 2010 2009 2008 Other

All Journal Article (12 results) (of which Peer Reviewed: 7 results) Presentation (18 results) Remarks (1 results)

  • [Journal Article] Photochemical dehalogenation mediated by macrocyclic nickel(II) complexes2011

    • Author(s)
      Mochizuki K., Suzuki M.
    • Journal Title

      Inorg. Chem. Commu. in press

    • Related Report
      2010 Final Research Report
  • [Journal Article] 汚れを落とす固形石けんの水と汚れになじみやすい部分の理科的な扱い方について2011

    • Author(s)
      早野清治・津田和也・望旦桂・大和田秀一
    • Journal Title

      北海道教育大学紀要(教育科学編)

      Volume: 第61巻 Pages: 209-217

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photochemical dehalogenation mediated by macrocyclic nickel(II) complexes2011

    • Author(s)
      Mochizuki K., Suzuki M
    • Journal Title

      Inorg.Chem.Commun.

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of {15-benzyloxy-3,7,11,17- tetraazabicyclo[11.3.1]heptadeca-1(17),13,15-triene} nickel(II) perchlorate and its analogs, and their catalytic behavior in reductive debromination of 1-bromo-4-tert-butylbenzene2010

    • Author(s)
      Mochizuki K., Sugita T., Kuroiwa S., Yamada F., Hayano K., Ohgami Y., Suzuki M., Kato S.
    • Journal Title

      Inorg. Chim. Acta 363

      Pages: 3151-3157

    • Related Report
      2010 Final Research Report
  • [Journal Article] Synthesis of {15-benzyloxy-3,7,11,17-tetraazabicyclo[11.3.1]heptadeca-1(17),13,15-triene} nickel(II) perchlorate and its analogs, and their catalytic behavior in reductive debromination of 1-bromo-4-tert-butylbenzene2010

    • Author(s)
      Mochizuki K., Sugita T., Kuroiwa S., Yamada F., Hayano K., Ohgami Y., Suzuki M., Kato S
    • Journal Title

      Inorg.Chim.Acta

      Volume: 363 Pages: 3151-3157

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New bis(macrocyclic) dinickel(II) complexes obtained by oxidation of bis(5,7-dimethyl- 1,4,8,11-tetraazacyclotetradeca- 4,7-dien-6- yl)dinickel(II) perchlorate2009

    • Author(s)
      Mochizuki K., Sugita T., Yamada F., Mochizuki N., Hayano K., Ohgami Y.
    • Journal Title

      Inorg. Chim. Acta 362(4)

      Pages: 1204-1208

    • Related Report
      2010 Final Research Report
  • [Journal Article] Synthesis and structures of zinc complexes with new binucleating ligands containing alkoxide bridges, and their activities in the hydrolysis of tris(p-nitrophenyl)phosphate2009

    • Author(s)
      Mochizuki K., Ishima Y., Hayano K.
    • Journal Title

      Inorg. Chim. Acta 362

      Pages: 2722-2727

    • Related Report
      2010 Final Research Report
  • [Journal Article] Migration of 1,3-diazacyclohexane sub-rings in ring-contracted macrocyclic silver(I) complexes2009

    • Author(s)
      Mochizuki K., Ohgami Y., Mochizuki A., Hayano K.
    • Journal Title

      Inorg. Chem. Commun 12

      Pages: 1250-1254

    • Related Report
      2010 Final Research Report
  • [Journal Article] Migration of 1,3-diazacyclohexane sub-rings in ring-contracted macrosyclic silver(I)complexes2009

    • Author(s)
      Mochizuki K., Ohgami Y, Mochizuki A., Hayano K.
    • Journal Title

      Inorg.Chem.Commun. 12

      Pages: 1250-1254

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 脂肪酸の水酸化ナトリウム水溶液による中和で生成する固形石けんの理科的な扱い方について2009

    • Author(s)
      早野清治・永田雅幸・津田和也・望月桂・大和田秀一
    • Journal Title

      北海道教育大学紀要 60

      Pages: 121-127

    • NAID

      110007224839

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New bis (macrocyclic) dinickel (II) complexes obtained by oxidation of bis (5, 7-dimethyl-1, 4, 8, 11-tetraazacyclotetradeca-4, 7-dien-6-yl) dinickel (II) perchlorate2009

    • Author(s)
      Mochizuki K., Sugita T., Yamada F., Mochizuki N., Hayano K., Ohgami Y.
    • Journal Title

      Inorg. Chim. Ada 362

      Pages: 1204-1208

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and structures of zinc complexes with new binucleating ligands containing alkoxide bridges, and their activities in the hydrolysis of tris(p-nitrophenv)phosphate2009

    • Author(s)
      Mochizuki. K., Ishima Y., Hayano K.
    • Journal Title

      Inorg. Chim. Ada 362

      Pages: 2122-2121

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 大環状配位子-銅錯体の合成2010

    • Author(s)
      大神泰伸・望月桂
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪大学
    • Year and Date
      2010-09-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] ビピリジン架橋部を持つ二環状配位子とその金属錯体大環状配位子-銅錯体の合成2010

    • Author(s)
      内田好子・望月桂
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪大学
    • Year and Date
      2010-09-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] 光受容性金属錯体を持つ環状配位子-ニッケル(11)錯体の合成2010

    • Author(s)
      望月桂・鈴木麻菜・木下愛子
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪大学
    • Year and Date
      2010-09-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] ベンジル基が導入された環状配位子-銅酸素錯体2010

    • Author(s)
      望月桂・加藤翔平・進藤朋美
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪大学
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 大環状配位子-銅錯体の合成2010

    • Author(s)
      (横浜市大生命ナノ)大神泰伸・望月桂
    • Organizer
      第60回錯体化学討論会,2PA-055
    • Place of Presentation
      大阪大学
    • Related Report
      2010 Final Research Report
  • [Presentation] ビピリジン架橋部を持つ二環状配位子とその金属錯体2010

    • Author(s)
      (横浜市大生命ナノ)内田好子・望月桂
    • Organizer
      第60回錯体化学討論会,2PA-055
    • Place of Presentation
      大阪大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 光受容性金属錯体を持つ環状配位子ーニッケル(II)錯体の合成2010

    • Author(s)
      (横浜市大国際総合) 望月桂・鈴木麻菜・木下愛子
    • Organizer
      第60回錯体化学討論会,2PA-054
    • Place of Presentation
      大阪大学
    • Related Report
      2010 Final Research Report
  • [Presentation] べンジル基が導入された環状配位子ー銅酸素錯体2010

    • Author(s)
      (横浜市大国際総合) 望月桂・加藤翔平・進藤朋美
    • Organizer
      第60回錯体化学討論会,1pc-001
    • Place of Presentation
      大阪大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 1,3‐ジアザシクロヘキサンを持つ大環状配位子‐銀(I)錯体2009

    • Author(s)
      (横浜市大国際総合・北海道教育大)望月桂・大神泰伸・早野清治
    • Organizer
      第59回錯体化学討論会,1PA-002
    • Place of Presentation
      長崎大学
    • Related Report
      2010 Final Research Report
  • [Presentation] ビピリジン架橋部を持つ二環状配位子の合成とその銅錯体2009

    • Author(s)
      (横浜市大生命ナノ)内田好子・望月桂
    • Organizer
      第59回錯体化学討論会,2PA-054
    • Place of Presentation
      長崎大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 1,3-ジアザシクロヘキサンを持つ大環状配位子-銀(I)錯体2009

    • Author(s)
      望月桂・大神泰伸・早野清治
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] ビピリジン架橋部を持つ二環状配位子の合成とその銅錯体2009

    • Author(s)
      内田好子・望月桂
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] 環状トリアミンを架橋した二環状配位子の合成とその銅-酸素錯体2008

    • Author(s)
      (横浜市大院国際総合科学)今中裕佳子・古林龍作・内田好子・望月桂
    • Organizer
      第58回錯体化学討論会,2PA-021
    • Place of Presentation
      金沢大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 環状配位子-ニッケル錯体を用いた可視光照射によるハロゲン化アリールの脱ハロゲン化2008

    • Author(s)
      (横浜市大院国際総合科学)鈴木麻菜・望月桂
    • Organizer
      第58回錯体化学討論会,2PF-004
    • Place of Presentation
      金沢大学
    • Related Report
      2010 Final Research Report
  • [Presentation] ベンジル基が導入された環状配位子の合成およびそれらの銅酸素錯体2008

    • Author(s)
      (横浜市大院国際総合科学)加藤翔平・望月桂
    • Organizer
      第58回錯体化学討論会,2PA-060
    • Place of Presentation
      金沢大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 環状トリアミンを架橋した二環状配位子の合成とその銅-酸素錯体2008

    • Author(s)
      今中裕佳子, 古林龍作, 内田好子, 望月桂
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] 環状配位子-ニッケル錯体を用いた可視光照射によるハロゲン化アリールの脱ハロゲン化2008

    • Author(s)
      鈴木麻菜, 望月桂
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] ベンジル基が導入された環状配位子の合成およびそれらの銅酸素錯体2008

    • Author(s)
      加藤翔平, 望月桂
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2008 Annual Research Report
  • [Remarks] ホームページ等

    • Related Report
      2010 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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