PREPARATION AND PERMEATION/SEPARATION OF CARBON DIOXIDE IN POLYIMIDE/CARBON HYBRID MEMBRANES

• Project/Area Number: 20550196
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer/Textile materials
• Research Institution: Meiji University
• Principal Investigator: NAGAI Kazukiyo Meiji University, 理工学部, 教授 (40350269)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000); Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2008: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
• Keywords: 高分子合成 / 高分子構造・物性 / ナノ材料 / 二酸化炭素排出削減 / 反応・分離工学

Research Abstract

Many countries focus on removal of a major greenhouse gas, carbon dioxide, to prevent global warming. Novel organic/inorganic hybrid membranes were prepared by ABA-type poly (methyl methacrylate) and fluorine-containing polyimide triblock copolymers with various block lengths.

Research Products

• [Journal Article] Membrane color and gas permeability of 6FDA-TeMPD polyimide membranes prepared with various membrane preparation protocols (2011)
  • Author(s): S.Kanehashi, S.Sato, K.Nagai
  • Journal Title: Polym.Eng.Sci. (in press)
  • Peer Reviewed
• [Journal Article] Membrane Color and Gas Permeability of 6FDA-TeMPD Polyimide Membranes Prepared With Various Membrane Preparation Protocols (2011)
  • Author(s): S.Kanehashi, S.Sato, K.Nagai
  • Journal Title: Polym.Eng.Sci. Volume: (印刷中)
  • Peer Reviewed
• [Journal Article] Analysis of permeability, solubility and diffusivity of carbon dioxide, oxygen, and nitrogen in crystalline and liquid crystalline polymers (2010)
  • Author(s): S.Kanehashi, A.Kusakabe, S.Sato, K.Nagai
  • Journal Title: J.Membrane Sci. 365 Pages: 40-51
  • Peer Reviewed
• [Journal Article] Analysis of permeability, solubility and diffusivity of carbon dioxide, oxygen, and nitrogen in crystalline and liquid crystalline polymers (2010)
  • Author(s): S.Kanehashi, A.Kusakabe, S.Sato, K.Nagai
  • Journal Title: J.Membrane Sci. Volume: 365 Pages: 40-51
  • Peer Reviewed
• [Journal Article] Solid and thermal properties of ABA-type triblock copolymers designed using a difunctional fluorine-contained polyimide macroinitiators with methyl methacrylate (2009)
  • Author(s): S.Miyata, K.Yoshida, H.Shirokura, M.Kashio, K.Nagai
  • Journal Title: Polym.Int. 58 Pages: 1148-1159
  • Peer Reviewed
• [Journal Article] 6FDA-TeMPDポリイミドマクロ開始剤から合成したABA型ブロックコポリマーによる多孔構造の作製 (2009)
  • Author(s): 宮田壮、代蔵隼人、永井一清
  • Journal Title: 高分子論文集 66 Pages: 170-178
  • NAID: 10024760243
  • Peer Reviewed
• [Journal Article] Temperature dependence on gas permeability and permselectivity of poly (lactic acid) blend membranes (2009)
  • Author(s): T.Komatsuka, K.Nagai
  • Journal Title: Polym.J. 41 Pages: 455-458
  • NAID: 10025092178
  • Peer Reviewed
• [Journal Article] 6FDA-TeMPDポリイミドマクロ開始剤から合成したABA型ブロックコポリマーによる多孔構造の作製
  • Author(s): 宮田壮, 代蔵隼人, 永井一清
  • Journal Title: 高分子論文集 (受理され印刷中)
  • NAID: 10024760243
  • Peer Reviewed
• [Presentation] 結晶性高分子における気体透過特性の相関解析 (2010)
  • Author(s): 兼橋真二、日下部輝、佐藤修一、永井一清
  • Organizer: 第48回高分子と水に関する討論会
  • Place of Presentation: 東京
  • Year and Date: 2010-12-06
• [Presentation] 結晶性高分子における気体透過性、溶解性、拡散性の相関解析 (2010)
  • Author(s): 兼橋真二、佐藤修一、永井一清
  • Organizer: 日本化学会第4回関東支部大会
  • Place of Presentation: 東京
  • Year and Date: 2010-08-31
• [Presentation] Polymeric separation membranes for greenhouse gas recovery against global warming (2010)
  • Author(s): 永井一清
  • Organizer: 3rd International Conference for Young Chemists (ICYC2010)
  • Place of Presentation: Penang, Malaysia
  • Year and Date: 2010-06-24
• [Presentation] Polymeric separation membranes for greenhouse gas recovery against global warming (2010)
  • Author(s): 永井一清
  • Organizer: 3rd International Conference for Young Chemists(ICYC2010)
  • Place of Presentation: Penang, Malaysia
  • Year and Date: 2010-06-24
• [Book] サイエンス&テクノロジー(第15章ガス透過性/ガスバリア性の測定・分析, ,実践 高分子の構造・物性分析・測定)(東京) (2010)
  • Author(s): 永井一清
• [Book] Membrane Gas Separation(B.D.Freeman, Yu. Yampolskii eds.)(Chapter 1 Synthesis and gas permeability of hyperbranched and cross-linked polyimide membranes)(Wiley, NY) (2010)
  • Author(s): 兼橋真二, 佐藤修一, 永井一清
• [Book] エヌ・ティー・エス(日本ポリイミド・芳香族系高分子研究会編)(第2編第II部第5章ポリイミド分離膜・透過膜, 最新ポリイミド-基礎と応用-) (2010)
  • Author(s): 兼橋真二, 佐藤修一, 永井一清
• [Book] Handbook of Membrane Research : Properties, Performance and Applications(S.V.Gorley ed.)(Chapter 14 Materials design of gas separation polymer membranes) (2009)
  • Author(s): 永井一清
  • Publisher: Nova Science Publishers(NY)