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Tracing nitrous oxide using the triple oxygen isotopic compositions as tracers

Research Project

Project/Area Number 20710001
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Environmental dynamic analysis
Research InstitutionHokkaido University

Principal Investigator

KOMATSU Daisuke  Hokkaido University, 大学院・理学研究院, 博士研究員 (70422011)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords酸素同位体異常 / 三酸素同位体 / 物質循環 / 亜酸化窒素 / 海洋化学 / 一酸化二窒素
Research Abstract

To identify the sources of the ^<17>O excess in atmospheric N_2O, we analyzed Δ^<17>O values of N_2O emitted from ocean and soil environment using the new analytical method. The Δ^<17>O values of oceanic N_2O collected in the western North Pacific was firstly measured. I found definite positive ^<17>O anomaly in shallow and deep seawater. In addition, the Δ^<17>O values of soil N_2O in forest and cultivated land was measured. However, I could not identify the N_2O sources having large ^<17>O excess during this investigation.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (12 results)

All 2010 2009 2008

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (5 results)

  • [Journal Article] Simultaneous determination of δ15N and δ18O of N2O and δ13C of CH4 in nanomolar quantities from a single water sample.2010

    • Author(s)
      Hirota, A., U. Tsunogai, D.D. Komatsu, F. Nakagawa
    • Journal Title

      Rapid Communications in Mass Spectrometry 24

      Pages: 1085-1092

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tracing the fate of atmospheric nitrate deposited onto a forest ecosystem in eastern Asia using Δ^<17>O2010

    • Author(s)
      U.Tsunogai, D.D.Komatsu, S.Daita, G.A.Kazemi, F.Nakagawa, I.Noguchi, J.Zhang
    • Journal Title

      Atmospheric Chemistry and Physics 10

      Pages: 1809-1820

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Simultaneous determination of δ^<15>N and δ^<18>O of N_2O and δ^<13>C of CH_4 in nanomolar quantities from a single water sample2010

    • Author(s)
      A.Hirota, U.Tsunogai, D.D.Komatsu, F.Nakagawa
    • Journal Title

      Rapid Communications in Mass Spectrometry 24

      Pages: 1085-1092

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enrichment of nitrous oxide in a water column in the Bering and Chukchi Sea area.2009

    • Author(s)
      Hirota, A., A. Ijiri, D.D. Komatsu, S.B. Ohkubo, F. Nakagawa, U. Tsunogai
    • Journal Title

      Marine Chemistry 116

      Pages: 47-53

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enrichment of nitrous oxide in a water column in the Bering and Chukchi Sea area2009

    • Author(s)
      A.Hirota, A.Ijiri, D.D.Komatsu, S.B.Ohkubo, F.Nakagawa, U.Tsunogai
    • Journal Title

      Marine Chemistry 116

      Pages: 47-53

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Determination of the 15N/14N, 17O/16O, and 18O/16O ratios of nitrous oxide by using continuous-flow isotope ratio MS.2008

    • Author(s)
      Komatsu, D.D., T. Ishimura, F. Nakagawa, U. Tsunogai
    • Journal Title

      Rapid communications in Mass Spectrometry 22

      Pages: 1587-1596

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Determination of the ^<15>N/^<14>N, ^<17>O/^<16>O, and ^<18>O/^<16>O ratios of nitrous oxide by using continuous-flow isotope ratio mass spectrometry2008

    • Author(s)
      Komatsu, D.D., T. Ishimura, F. Nakagawa, and U. Tsunogai
    • Journal Title

      Rapid Communications in Mass Spectrometry 22

      Pages: 1587-1596

    • NAID

      130005053470

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 大気中の一酸化二窒素における三酸素同位体比異常発生源を探して2009

    • Author(s)
      鈴木敦之、角皆潤、中川書子、小松大祐
    • Organizer
      2009年度日本質量分析学会同位体比部会
    • Place of Presentation
      箱根高原ホテル
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] 一酸化二窒素の高精度三酸素同位体定量法開発2008

    • Author(s)
      小松大祐、石村豊穂、中川書子、角皆潤
    • Organizer
      日本地球化学会第55回年会
    • Place of Presentation
      東京大学
    • Related Report
      2009 Final Research Report
  • [Presentation] 三酸素同位体指標を用いた大気中一酸化二窒素の収支について2008

    • Author(s)
      小松大祐、石村豊穂、中川書子、角皆潤
    • Organizer
      日本地球惑星科学連合2008年大会
    • Place of Presentation
      幕張メッセ国際会議場
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 一酸化二窒素の高精度三酸素同位体定量法開発2008

    • Author(s)
      小松大祐、石村豊穂、中川書子、角皆潤
    • Organizer
      日本地球化学会第55回年会
    • Place of Presentation
      東京大学教養学部
    • Related Report
      2008 Annual Research Report
  • [Presentation] 大気由来硝酸の指標 : 三酸素同位体組成とその応用2008

    • Author(s)
      小松大祐、大久保智、石村豊穂、中川書子、角皆潤
    • Organizer
      2008年度日本質量分析学会同位体比部会
    • Place of Presentation
      愛知県民の森
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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