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Development of liquid-phase growth process for Bi_2Te_3-based Thermoelectric Materials

Research Project

Project/Area Number 20760494
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Material processing/treatments
Research InstitutionShimane University

Principal Investigator

KITAGAWA Hiroyuki  Shimane University, 総合理工学部, 准教授 (00325044)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords熱電変換材料 / 液相成長法 / キャリア輸送特性 / ビスマステルライド / 結晶成長
Research Abstract

A liquid-phase growth process of Bi_2Te_3-based materials was developed in order to obtain polycrystals with a preferred orientation for use in thermoelectric applications. The liquid-phase growth was carried out under an argon atmosphere by using the sliding-boat method, which is an easy and short-time process compared with the conventional method for preparing the single crystals. X-ray diffraction patterns show that the hexagonal c-plane of the grown crystal is almost parallel to the substrate. The Hall mobility of the grown crystal (p-type Bi_<0.5>Sb_<1.5>Te_3) was 1.8~2 times larger than that of the sintered materials with a comparable carrier concentration. As a result, the thermoelectric power factor was improved by this process because of the low electrical resistivity due to the high carrier mobility.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (10 results)

All 2010 2009 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (6 results) Remarks (2 results)

  • [Journal Article] Structure and Carrier Transport Properties of Hot-press Deformed Bi0. 5Sb1. 5Te32010

    • Author(s)
      Hiroyuki Kitagawa, Akira Kurata, Hiroshi Araki, Shigekazu Morito, Eishi Tanabe
    • Journal Title

      Physica Status Solidi A 207

      Pages: 401-406

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structure and Carrier Transport Properties of Hot-press Deformed Bi_<0.5>Sb_<1.5>Te_32010

    • Author(s)
      Hiroyuki Kitagawa, Akira Kurata, Hiroshi Araki, Shigekazu Morito, Eishi Tanabe
    • Journal Title

      Physica Status Solidi A 207

      Pages: 401-406

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] スライドボート法により作製したBi0. 5Sb1. 5Te3の熱電特性2010

    • Author(s)
      北川裕之, 森広永喜, 山田容士, 久保衆伍
    • Organizer
      日本金属学会2010年度春期大会
    • Place of Presentation
      筑波大学
    • Year and Date
      2010-03-30
    • Related Report
      2009 Final Research Report
  • [Presentation] スライドボート法により作製したBi_<0.5>Sb_<1.5>Te_3の熱電特性2010

    • Author(s)
      北川裕之, 森広永喜, 山田容士, 久保衆伍
    • Organizer
      日本金属学会2010年度春期大会
    • Place of Presentation
      筑波大学筑波キャンパス
    • Year and Date
      2010-03-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] Texture and thermoelectric properties of Bi0. 5Sb1. 5Te3 prepared by hot-press deformation2009

    • Author(s)
      Hiroyuki Kitagawa, Akira Kurata, Hiroshi Araki, Shigekazu Morito, Eishi Tanabe
    • Organizer
      The 28th International Conference on Thermoelectrics
    • Place of Presentation
      Freiburg, Germany
    • Year and Date
      2009-07-27
    • Related Report
      2009 Final Research Report
  • [Presentation] Texture and thermoelectric properties of Bi_<0.5>Sb_<1.5>Te_3 prepared by hot-press deformation2009

    • Author(s)
      Hiroyuki Kitagawa, Akira Kurata, Hiroshi Araki, Shigekazu Morito, Eishi Tanabe
    • Organizer
      28th International Conference on Thermoelectrics
    • Place of Presentation
      Concert Hall of Freiburg, Freiburg, Germany
    • Year and Date
      2009-07-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] スライドボート法によるBi2Te3系熱電材料の液相成長2009

    • Author(s)
      北川裕之, 谷口大祐, 國貞俊光, 山田容士, 久保衆伍
    • Organizer
      日本金属学会2009年度春期大会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2009-03-29
    • Related Report
      2009 Final Research Report
  • [Presentation] スライドボート法によるBi_2Te_3系熱電材料の液相成長2009

    • Author(s)
      北川裕之
    • Organizer
      日本金属学会2009年春期講演大会
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.crc.shimane-u.ac.jp/res-pr/seeds02/

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.crc.shimane-u.ac.jp/res-pr/seeds02/

    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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