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Pioneering 3d transition-metals coordination polymers as novel electrocatalysts for metal-air batteries.

Research Project

Project/Area Number 20K05689
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 36020:Energy-related chemistry
Research InstitutionShibaura Institute of Technology

Principal Investigator

RZEZNICKA Izabela  芝浦工業大学, 工学部, 教授 (40565769)

Co-Investigator(Kenkyū-buntansha) 堀 顕子  芝浦工業大学, 工学部, 教授 (90433713)
Project Period (FY) 2020-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2022: ¥260,000 (Direct Cost: ¥200,000、Indirect Cost: ¥60,000)
Fiscal Year 2021: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2020: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
KeywordsOER / ORR / electrocatalyst / nickel dithiooxamide / metal-air batteries / coordination polymer / copper dithiooxamide / overpotential / chelate polymers / bifunctional catalyst / nickel chelate polymers / 3d transition metals / oxygen evolution / oxygen reduction / coordination polymers / oxygen evolution react / oxygen reduction react / metal-air battery
Outline of Research at the Start

Powering electric vehicles requires high capacity rechargeable batteries.
Metal-air batteries, offer high energy density which is close to the energy density of gasoline. However, practical development of such batteries is hindered by inefficiency of two reactions; oxygen reduction reaction (ORR) and oxygen evolution reaction (OER).
To improve the efficiency, an electrocatalyst that can catalyze both reactions has to be developed. In this study, 3d transition metals coordination polymers will be synthesized and evaluated for their performance towards OER and OER in alkaline solutions.

Outline of Final Research Achievements

In the field of metal-air batteries, a bifunctional electrocatalyst able to efficiently catalyze oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) is highly desired to provide theoretically predicted high energy densities. To address this challenge we prepared copper and nickel coordination polymers (CPs) and investigated their stability and electrocatalytic activity towards OER and ORR in alkaline solutions. It is found that CuCP-derived electrocatalyst is active mainly toward OER, while NiCP-derived electrocatalyst can catalyze both OER and ORR in alkaline solutions.

Academic Significance and Societal Importance of the Research Achievements

A new method to produce active nanocomposite electrocatalysts for oxygen evolution reaction and oxygen reduction reaction in alkaline media is proposed. The method has a potential to reduce the cost of the catalyst used in metal-air batteries and electrolyzers by replacing usage of noble metals.

Report

(4 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • 2020 Research-status Report
  • Research Products

    (17 results)

All 2023 2022 2021 2020 Other

All Journal Article (5 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 5 results,  Open Access: 2 results) Presentation (9 results) (of which Int'l Joint Research: 3 results) Remarks (3 results)

  • [Journal Article] Bifunctional Catalytic Activity of γ-NiOOH toward Oxygen Reduction and Oxygen Evolution Reactions in Alkaline Solutions2022

    • Author(s)
      Ridwan P. Putra, Ihsan Budi Rachman, Hideyuki Horino, Izabela I. Rzeznicka
    • Journal Title

      Oxygen

      Volume: 2 (4) Issue: 4 Pages: 479-492

    • DOI

      10.3390/oxygen2040031

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Copper-based electrocatalyst derived from a copper chelate polymer for oxygen reduction in alkaline solutions2022

    • Author(s)
      R.P.Purtra, Y.Samejima, S.Nakabayashi, H.Hoshino, I.I.Reznicka
    • Journal Title

      Catalysis today

      Volume: 338 Pages: 360-364

    • DOI

      10.1016/j.cattod.2020.06.005

    • Related Report
      2022 Annual Research Report 2021 Research-status Report 2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] γ-NiOOH Electrocatalyst Derived from a Nickel dithiooxamide Chelate Polymer for Oxygen Evolution Reaction in Alkaline Solutions2021

    • Author(s)
      Ridwan P. Putra, Ihsan Budi Rachman, Hideyuki Horino, Izabela I. Rzeznicka
    • Journal Title

      Catalysis Today

      Volume: acceptd Pages: 308-315

    • DOI

      10.1016/j.cattod.2021.08.017

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] An Efficient Electrocatalyst for Oxygen Evolution Reaction in Alkaline Solutions Derived from a Copper Chelate Polymer via In Situ Electrochemical Transformation2020

    • Author(s)
      Ridwan P. Putra, Hideyuki Horino, Izabela I. Rzeznicka
    • Journal Title

      Catalysts

      Volume: 10 Issue: 2 Pages: 233-244

    • DOI

      10.3390/catal10020233

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Enhanced and Heteromolecular Guest Encapsulation in Non‐Porous Crystals of Perfluorinated Triketonato Dinuclear Copper Complex2020

    • Author(s)
      Ikumura Yoshinori、Habuka Yusuke、Sakai Shunichiro、Shinohara Takanori、Yuge Hidetaka、Rzeznicka Izabela Irena、Hori Akiko
    • Journal Title

      Chemistry -A European Journal

      Volume: 26 Issue: 22 Pages: 5051-5060

    • DOI

      10.1002/chem.201905740

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Activity of Ni/TiO2 Catalysts for Electrochemical Oxygen Reduction Reaction in Alkaline Media2023

    • Author(s)
      Izabela. I. Rzeznicka, Ewa Kowalska, Ridwan. P. Putra, Hideyuki Horino
    • Organizer
      7th International Conference on Catalysis and Chemical Engineering
    • Related Report
      2022 Annual Research Report
  • [Presentation] Electrochemical Synthesis of Highly Crystalline γ-NiOOH and Its Bifunctional Electrocatalytic Activity Towards Oxygen Evolution and Reduction Reactions in Alkaline Solutions2022

    • Author(s)
      Izabela Irena Rzeznicka, Ridwan Pratama Putra, Hideyuki Horino
    • Organizer
      241st Electrochemical Society Meeting
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nickel Hydroxides Derived from Nickel Dithiooxamide as Bifunctional Oxygen Electrocatalysts2022

    • Author(s)
      Izabela I. Rzeznicka, Ridwan P. Putra, Ihsan Budi Rachman, Hideyuki Horino
    • Organizer
      VI International Conference on Catalysis and Chemical Engineering, San Francisco, February 22-26, 2022
    • Related Report
      2021 Research-status Report
  • [Presentation] Nickel Hydroxides Derived from Nickel Dithioxamide Coordination Polymer as Potential Oxygen Reduction Reaction Electrocatalyst in Alkaline Solutions2021

    • Author(s)
      Ihsan Budi Rachman, Ridwan P. Putra, Hideyuki Horino, Izabela I. Rzeznicka
    • Organizer
      7th International Conference on Catalysis, Chemical Engineering and Technology (CCT 2021)
    • Related Report
      2021 Research-status Report
  • [Presentation] Izabela Rzeznicka, Hideyuki Horino2021

    • Author(s)
      Vibrational Spectroscopy of Monolayers
    • Organizer
      13th International Symposium on Atomic Level Characterizations for New Materials and Devices
    • Related Report
      2021 Research-status Report
  • [Presentation] 2D-layered Coordination Polymer of Nickel Dithioxamide as a Precursor of Bifunctional Catalyst for Metal-air Batteries2021

    • Author(s)
      Ihsan Budi Rachman, Ridwan P. Putra, Hideyuki Horino and Izabela I. Rzeznicka
    • Organizer
      Materials Research Society Fall Meeting, Boston, 2021
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Nickel-Based Electrocatalyst Derived from a Nickel Dithioxamide Chelate Polymer for Oxygen Evolution Reaction in Alkaline Solutions2021

    • Author(s)
      Izabela Rzeznicka, Ridwan P. Putra, Hideyuki Horino, Ihsan Budi Rachman
    • Organizer
      5th International Conference on Catalysis and Chemical Engineering
    • Related Report
      2020 Research-status Report
  • [Presentation] Bifunctional Electrocatalyst for Aqueous Type Rechargeable Li-Air Batteries Derived from Copper Chelate Polymer2020

    • Author(s)
      Izabela Rzeznicka, Ridwan P. Putra, Hideyuki Horino
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-state Science , PRIME 2020
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research
  • [Presentation] Copper-Based Electrocatalyst Derived from a Copper Chelate Polymer for Oxygen Reduction Reaction in Alkaline Solutions2020

    • Author(s)
      Izabela Rzeznicka, Ridwan P. Putra, Hideyuki Horino
    • Organizer
      4th International Conference on Catalysis and Chemical Engineering
    • Related Report
      2020 Research-status Report
  • [Remarks] Copper dithiooxamide- derived electrocatalyst

    • Related Report
      2022 Annual Research Report
  • [Remarks] γ-NiOOH as bifunctional OER/ORR catalyst

    • Related Report
      2022 Annual Research Report
  • [Remarks] Laboratory website

    • Related Report
      2021 Research-status Report

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Published: 2020-04-28   Modified: 2024-01-30  

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