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Proposal of Carbon air secondary battery system charging and discharging using electrochemical reaction and high-temperature thermochemical equilibrium

Research Project

Project/Area Number 20K20364
Project/Area Number (Other) 18H05349 (2018-2019)
Research Category

Grant-in-Aid for Challenging Research (Pioneering)

Allocation TypeMulti-year Fund (2020)
Single-year Grants (2018-2019)
Review Section Medium-sized Section 31:Nuclear engineering, earth resources engineering, energy engineering, and related fields
Research InstitutionTokyo Institute of Technology

Principal Investigator

IHARA MANABU  東京工業大学, 物質理工学院, 教授 (90270884)

Co-Investigator(Kenkyū-buntansha) 長谷川 馨  東京工業大学, 物質理工学院, 助教 (50644944)
Project Period (FY) 2018-06-29 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥26,000,000 (Direct Cost: ¥20,000,000、Indirect Cost: ¥6,000,000)
Fiscal Year 2021: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2020: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2019: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2018: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Keywords固体酸化物燃料電池 / 蓄電デバイス / CO2電解 / 工学 / エネルギー生成・変換 / 総合工学 / エネルギー学 / 原子力工学 / 地球資源工学
Outline of Research at the Start

本研究では、「カーボン空気二次電池」という新しい概念の実現性や優位性を、固体酸化物型電気化学デバイス、二次電池双方のアプローチから検討し、さらにシステム全体を設計しその実現性、優位性を検討する

Outline of Final Research Achievements

Power-to-gas-to-power systems that produce H2 by water electrolysis and generate electricity from this H2 are promising long-term electric energy storage systems for extensive installation of renewable energies. However, such systems require complex thermal management, and must be sufficiently large to enable the use of waste heat for higher efficiency. Here we propose the “carbon/air secondary battery” (CASB) system that uses a C/CO2 reaction with potentially higher volumetric energy density and efficiency than that of the H2/H2O reaction. This system produces C by CO2 electrolysis for energy storage and generates electricity from the C via solid oxide electrolysis cells/fuel cells. Repetitive power generation (10 charge-discharge cycles) of the CASB system with Boudouard equilibrium was firstly demonstrated at 800°C without degradation. The system achieved a maximum Coulombic efficiency of 84%, charge-discharge efficiency of 38%, and power density of 80 mW cm-2.

Academic Significance and Societal Importance of the Research Achievements

炭素は多くの金属を上回るエネルギー密度を持ち、常に文明活動の主要なエネルギー源であった。近年ではCO2排出制限により低炭素化が必須となっているが、CO2を排出しない方法での炭素の高エネルギー密度、汎用性の積極利用は有用である。本提案ではCO2を二次電池構成物質として繰り返し利用するため、実質のCO2排出はゼロとなる。本提案では、金属、水素に加えて第3の蓄エネルギー媒体としてCO2/Cを利用する挑戦的な提案である。原材料の高い汎用性により、低コスト、大規模な実装が可能になると期待される。

Report

(5 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Research-status Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (31 results)

All 2022 2021 2020 2019 2018 Other

All Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (24 results) (of which Int'l Joint Research: 12 results,  Invited: 1 results) Book (2 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Carbon/air secondary battery system and demonstration of its charge-discharge2021

    • Author(s)
      Kameda Keisuke、Manzhos Sergei、Ihara Manabu
    • Journal Title

      Journal of Power Sources

      Volume: 516 Pages: 230681-230681

    • DOI

      10.1016/j.jpowsour.2021.230681

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] 原子価結合法への機械学習の適用によるペロブスカイト型プロトン伝導体探索の検討2022

    • Author(s)
      有賀 嵩晃、亀田 恵佑、佐々木 瑛太、長谷川馨、Manzhos Sergei、伊原学
    • Organizer
      化学工学会第87年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Ni/GDCおよびNi/YSZ燃料極を使用したカーボン空気二次電池システムの充放電特性の比較2020

    • Author(s)
      亀田 恵佑、長谷川 馨、伊原 学
    • Organizer
      化学工学会第51回秋季大会
    • Related Report
      2020 Research-status Report
  • [Presentation] 酸化物イオン伝導性酸化物上でのカーボンナノチューブ合成の検討2020

    • Author(s)
      山田 耕生、亀田 恵佑、飯田 雄太、長谷川 馨、伊原 学
    • Organizer
      化学工学会第85年会
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体酸化物燃料電池/電解セルの包括的燃料極反応モデルの提案と多変数フィッティング手法の構築2020

    • Author(s)
      古賀 康友、飯田 雄太、亀田 恵佑、長谷川 馨、伊原 学
    • Organizer
      化学工学会第85年会
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体酸化物燃料電池へのカーボンナノチューブ直接成長に対するイオン伝導性酸化物の影響2020

    • Author(s)
      長谷川 馨、山田 耕生、 細田 万吉、飯田 雄太、亀田 恵佑、伊原 学
    • Organizer
      化学工学会第85年会
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ni/GDCおよびNi/YSZ燃料極を使用したカーボン空気二次電池システムの充放電特性の比較2020

    • Author(s)
      亀田 恵佑、長谷川 馨、伊原 学
    • Organizer
      化学工学会第85年会
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Unified Kinetics Model of Reversible Solid Oxide Fuel Cell / Electrolysis with Competitive Adsorption Reaction on Anode Triple Phase Boundary」2019

    • Author(s)
      Kei Hasegawa, Hyojae Lee, Keisuke Kameda, Yuta Iida and Manabu Ihara
    • Organizer
      The World Hydrogen Technologies Convention (WHTC 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Consideration of operating condition and suppressing anode degradation for steep output power variation on liquid fuel direct supply solid oxide fuel cell2019

    • Author(s)
      Yuta Iida, Keisuke Kameda, Kei Hasegawa, Manabu Ihara
    • Organizer
      The World Hydrogen Technologies Convention (WHTC 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Proposed carbon-air secondary battery system as an electric power storage system」2019

    • Author(s)
      Keisuke Kameda, Yuta Iida, Mankichi Hosoda, Tatsuya Matsuhira, Kei Hasegawa, Manabu Ihara
    • Organizer
      The World Hydrogen Technologies Convention (WHTC 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] カーボンナノチューブを“作る”から“使う”,電池を“作る”から“使う”へ2019

    • Author(s)
      長谷川 馨
    • Organizer
      化学工学会横浜大会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 固体酸化物燃料電池を用いたカーボン空気二次電池システムの電解反応メカニズム2019

    • Author(s)
      亀田恵佑、飯田雄太、長谷川馨、伊原 学
    • Organizer
      2019年電気化学秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Kinetics Model to describe Reversible Operation of Solid Oxide Fuel Cell Electrolysis with Competitive Adsorption Reaction on Anode Triple Phase Boundary2019

    • Author(s)
      Kei Hasegawa, Hyojae Lee, Keisuke Kameda, Yuta Iida and Manabu Ihara
    • Organizer
      18th Asian Pacific Confederation of Chemical Engineering Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development and evaluation of liquid fuel direct supply SOFC for high load followability based on actual demand/supply data2019

    • Author(s)
      Yuta Iida, Keisuke Kameda, Tatsuya Okubo, Kei Hasegawa, Manabu Ihara
    • Organizer
      18th Asian Pacific Confederation of Chemical Engineering Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Proposal of carbon-air secondary battery system and evaluation of its potential as a large capacity energy storage2019

    • Author(s)
      Keisuke Kameda, Yuta Iida, Mankichi Hosoda, Tatsuya Matsuhira, Kei Hasegawa, Manabu Ihara
    • Organizer
      18th Asian Pacific Confederation of Chemical Engineering Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Comprehensive Kinetics Model with Competitive Adsorption Reaction on Water Electrode in Reversible Solid Oxide Fuel Cell / Electrolysis2019

    • Author(s)
      K. Hasegawa, H. Lee, K. Kameda, Y. Iida, and M. Ihara
    • Organizer
      236th ECS Meeting
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高負荷追従性と高利用率の両立を目指した液体直噴固体酸化物燃料電池の発電特性2019

    • Author(s)
      飯田 雄太、亀田 恵佑、長谷川 馨、伊原 学
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] カーボン空気二次電池システムの固体炭素反応メカニズムの解明2019

    • Author(s)
      亀田 恵佑、飯田 雄太、細田 万吉、松平 達哉、長谷川 馨、伊原 学
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 岩塩層を持つ層状ペロブスカイト構造酸化物のキャリア選択性の考察2019

    • Author(s)
      長尾 泰成、松平 達哉、亀田 恵佑、長谷川 馨、伊原 学
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 固体酸化物燃料電池へのカーボンナノチューブ合成技術の導入2018

    • Author(s)
      長谷川 馨、細田 万吉、伊原 学
    • Organizer
      第50回化学工学会秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ペロブスカイト関連構造の過剰酸素・酸素欠損とプロトン伝導性の関係2018

    • Author(s)
      松平 達哉、倉橋 佑輔、長谷川 馨、伊原 学
    • Organizer
      第50回化学工学会秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 固体酸化物燃料電池の燃料極へのカーボンナノチューブの直接合成法の検討2018

    • Author(s)
      細田 万吉、長谷川 馨、伊原 学
    • Organizer
      第50回化学工学会秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 大規模蓄エネルギーを目指した「カーボン空気二次電池」システムの提案2018

    • Author(s)
      亀田 恵佑、長谷川 馨、伊原 学
    • Organizer
      第50回化学工学会秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Carbon-Air Secondary Battery” System By Combining Direct Carbon Fuel Cells and CO2 Electrolysis As Large Scale Energy Storage2018

    • Author(s)
      K. Kameda, K. Hasegawa, and M. Ihara
    • Organizer
      234th ECS and SMEQ2018 Joint International Meeting (AiMES 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Evaluation of Fuel Electrode of Proton Conductive SOFC Considering Ion Transport Number2018

    • Author(s)
      K. Kameda, K. Hasegawa, and M. Ihara
    • Organizer
      The Asia-Oceania Top University League on Engineering (AOTULE 2018)
    • Related Report
      2018 Annual Research Report
  • [Book] 最近の化学工学67 進化する燃料電池・二次電池 --反応・構造・製造技術の基礎と未来社会を支える電池技術--, 2-1「電気化学・電極反応の基礎」2019

    • Author(s)
      伊原学・長谷川馨
    • Total Pages
      15
    • Publisher
      三恵社(化学工学会発行)
    • ISBN
      9784864879965
    • Related Report
      2018 Annual Research Report
  • [Book] 最近の化学工学67 進化する燃料電池・二次電池 --反応・構造・製造技術の基礎と未来社会を支える電池技術--, 3-III-5「電池技術と将来のエネルギーの姿」2019

    • Author(s)
      伊原学
    • Total Pages
      13
    • Publisher
      三恵社(化学工学会発行)
    • ISBN
      9784864879965
    • Related Report
      2018 Annual Research Report
  • [Remarks] 伊原・Manzhos研究室ホームページ

    • URL

      http://www.chemeng.titech.ac.jp/~iharalab/index.html

    • Related Report
      2021 Annual Research Report
  • [Remarks] CO2を利用する「大容量蓄電システム」を開発

    • URL

      https://www.titech.ac.jp/news/2022/063052

    • Related Report
      2021 Annual Research Report
  • [Remarks] 世界初となる「カーボン空気二次電池システム」の提案と開発

    • URL

      https://www.titech.ac.jp/news/2021/062640

    • Related Report
      2021 Annual Research Report
  • [Patent(Industrial Property Rights)] 二次電池及びそれを用いた充放電方法2018

    • Inventor(s)
      伊原学, 長谷川馨, 亀田恵佑
    • Industrial Property Rights Holder
      伊原学, 長谷川馨, 亀田恵佑
    • Industrial Property Rights Type
      特許
    • Patent Publication Number
      2020-038770
    • Filing Date
      2018
    • Acquisition Date
      2020
    • Related Report
      2019 Annual Research Report

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Published: 2018-07-20   Modified: 2024-03-26  

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