• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Diagnosis of urban air quality by laser spectroscopy and the controlling strategy for oxidation formation

Research Project

Project/Area Number 21221001
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Environmental dynamic analysis
Research InstitutionKyoto University (2012-2013)
Tokyo Metropolitan University (2009-2011)

Principal Investigator

KAJII Yoshizumi  京都大学, 地球環境学堂, 教授 (40211156)

Co-Investigator(Kenkyū-buntansha) IMAMURA Takashi  国環研, 環境計測研究センター, センター長 (60184826)
YOKOUCHI Yoko  国環研, 環境計測研究センター, フェロー (20125230)
Co-Investigator(Renkei-kenkyūsha) KATO Shungo  首都大, 都市環境, 准教授 (20381452)
SATO Kei  国環研, 地域環境研究センター, 主任研究員 (10282815)
NAKASHIMA Yoshihiro  農工大学院, 農学研究院, 助教 (20419873)
Project Period (FY) 2009-05-11 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥208,000,000 (Direct Cost: ¥160,000,000、Indirect Cost: ¥48,000,000)
Fiscal Year 2013: ¥29,900,000 (Direct Cost: ¥23,000,000、Indirect Cost: ¥6,900,000)
Fiscal Year 2012: ¥36,660,000 (Direct Cost: ¥28,200,000、Indirect Cost: ¥8,460,000)
Fiscal Year 2011: ¥33,800,000 (Direct Cost: ¥26,000,000、Indirect Cost: ¥7,800,000)
Fiscal Year 2010: ¥44,980,000 (Direct Cost: ¥34,600,000、Indirect Cost: ¥10,380,000)
Fiscal Year 2009: ¥62,660,000 (Direct Cost: ¥48,200,000、Indirect Cost: ¥14,460,000)
Keywordsオキシダント / レーザー計測 / OH反応性 / 未計測VOC / 植物起源VOC / 自動車排気ガス / 光酸化生成物 / NO3ラジカル / VOC / NOx / 軽車両 / 排気ガス / CO / 登録台数 / OH収率 / 窒素酸化物 / 揮発性有機化合物(VOC) / 窒素酸化物(NOx) / 液化天然ガス(CNG) / イソプレン / モノテルペン / セスキテルペン / HO_2反応性 / モノテルペ / OHラジカル反応性 / 未知なるOH反応性 / NO_3反応性 / NO_3ラジカル / 都心部 / 郊外地域 / N_2O_5
Research Abstract

Unknown VOC that may contribute for the production of oxidants were investigated by laser based OH reactivity technique. Possible sources of unknown VOCs considered were either biogenic VOC (BVOC), vehicular exhaust, or oxygenated VOC (OVOC). Using photochemical chamber, unknown OH reactivity was estimated to be 40% and 75% in the oxidation products of isoprene and p-xylene, respectively. The instruments for the HO2 and NO3 reactivity measurement were successfully developed. Predominant candidate for missing reactivity of OH were concluded to be both BVOC and OVOC.

Assessment Rating
Verification Result (Rating)

A

Report

(7 results)
  • 2014 Research Progress Assessment (Verification Result) ( PDF )
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (47 results)

All 2014 2013 2012 2011 2010 2009 Other

All Journal Article (38 results) (of which Peer Reviewed: 28 results) Presentation (2 results) Remarks (7 results)

  • [Journal Article] A novel fast gas chromatography method for higher time resolution measurements of speciated monoterpenes in air2014

    • Author(s)
      C. E. Jones, S. Kato, Y. Nakashima, Y. Kajii
    • Journal Title

      Atmospheric Measurement and Techniques

      Volume: 7 Issue: 1 Pages: 1-17

    • DOI

      10.5194/amt-7-1-2014

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Total OH reactivity measurements in ambient air in a southern Rocky mountain ponderosa pine forest during BEACHONSRM08 summer campaign2014

    • Author(s)
      Y. Nakashima, S. Kato, Y. Kajii, et al.
    • Journal Title

      Atmospheric Environment

      Volume: 85 Pages: 1-8

    • Related Report
      2013 Final Research Report
  • [Journal Article] otal OH reactivity measurements in ambient air in a southern Rocky Mountain ponderosa pine forest during BEACHON-SRM08 summer campaign2014

    • Author(s)
      Yoshihiro Nakashima et al.
    • Journal Title

      Atmospheric Environment

      Volume: 85 Pages: 1-8

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] オゾン誘起によるHOx (OH, HO2)ラジカル生成速度直接測定装置の開発2014

    • Author(s)
      鶴丸央 等
    • Journal Title

      大気環境学会誌

      Volume: 49 Pages: 86-92

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aerial observation of nitrogen compounds over the East China Sea in 2009 and 20102014

    • Author(s)
      H. Fjiwara et al.
    • Journal Title

      Atmospheric Environment

      Volume: 未

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aerial observations of air masses transported from East Asia to the Western Pacific: Vertical structure of polluted air masses2014

    • Author(s)
      S. Hatakeyama et al.
    • Journal Title

      Atmospheric Environment

      Volume: 未

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] UV Light induced Water Condensation in Air and a Role of Hydrogen Peroxide2014

    • Author(s)
      K. Yoshihara et al.
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 未

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A novel Fast Gas Chromatography based technique for higher time resolution measurements of speciated monoterpenes in air2014

    • Author(s)
      C. E. Jones et al.
    • Journal Title

      Atmos. Meas. Tech

      Volume: 未

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Concentration variations of total reactive nitrogen and total nitrate during transport to Fukue Island and to Cape Hedo, Japan in the marine boundary layer2014

    • Author(s)
      A. Yuba et al.
    • Journal Title

      Atmospheric Environment

      Volume: 未

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 反応性比較法に基づくガスクロマトグラフィーやプロトン移動反応質量分析による大気中OHラジカル反応性の測定2013

    • Author(s)
      加藤俊吾, 中嶋吉弘, 梶井克純
    • Journal Title

      分析化学

      Volume: 62 Pages: 369-378

    • NAID

      10031159078

    • Related Report
      2013 Final Research Report
  • [Journal Article] A laser-flash photolysis and laser-induced fluorescence detection technique for measuring total HO_2 reactivity in ambient air2013

    • Author(s)
      K. Miyazaki, Y. Nakashima, C. Schoemaecker, C. Fittschen, Y. Kajii
    • Journal Title

      Review of Scientific Instruments

      Volume: 84

    • Related Report
      2013 Final Research Report
  • [Journal Article] Effect of OH radical scavengers on secondary organic aerosol formation from reactions of isoprene with ozone2013

    • Author(s)
      K. Sato, S. Inomata, J-.H. Xing, T. Imamura, R. Uchida, S. Fukuda, K. Nakagawa, J. Hirokawa, M. Okumura, S. Tohno
    • Journal Title

      Atmos. Environ

      Volume: 79 Pages: 147-154

    • Related Report
      2013 Final Research Report
  • [Journal Article] Evaluation of HOx sources and cycling using measurement-constrained model calculations in a 2-methyl-3-butene-2-ol (MBO) and monoterpene (MT) dominated ecosystem2013

    • Author(s)
      S. Kim et al.
    • Journal Title

      Atmospheric Chemistry and Physics

      Volume: 13 Pages: 2031-2044

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A laser-flash photolysis and laser-induced fluorescence detection technique for measuring total HO2 reactivity in ambient air2013

    • Author(s)
      K. Miyazaki et al.
    • Journal Title

      Review of Scientific Instruments

      Volume: 84 Issue: 7 Pages: 76106-76106

    • DOI

      10.1063/1.4812634

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of a High Speed Measurement of Atmospheric Trace Species Using High Repetition Rate Cavity Ring-Down Spectroscopy2013

    • Author(s)
      A. Ida et al.
    • Journal Title

      The Review of Laser Engineering

      Volume: 41 Pages: 845-840

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Missing peroxy radical sources within a rural forest canopy2013

    • Author(s)
      G. M. Wolfe et al.
    • Journal Title

      Atmospheric Chemistry and Physics Discussion

      Volume: 13 Pages: 31713-31759

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A novel Fast Gas Chromatography based technique for higher time resolution measurements of speciated monoterpenes in air2013

    • Author(s)
      C. E. Jones et al.
    • Journal Title

      Atmos. Meas. Tech. Discuss

      Volume: 6 Pages: 10921-10954

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Total OH reactivity measurements in laboratory studies of the photooxidation of isoprene2013

    • Author(s)
      Y. Nakashima
    • Journal Title

      Atmospheric Environment

      Volume: 62 Pages: 243-247

    • DOI

      10.1016/j.atmosenv.2012.08.033

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Long term observation of surface O3 and its precursors in Dhaka, Bangladesh2013

    • Author(s)
      H. Akhter Sikder
    • Journal Title

      Atmospheric Research

      Volume: 122 Pages: 378-390

    • DOI

      10.1016/j.atmosres.2012.09.011

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Total OH reactivity measurements in laboratory studies of the photooxidation of isoprene2012

    • Author(s)
      Y. Nakashima, H. Tsurumaru, T. Imamura, I.Bejan, J. C. Wenger, and Y. Kajii
    • Journal Title

      Atmos. Environ

      Volume: 62 Pages: 243-247

    • Related Report
      2013 Final Research Report
  • [Journal Article] Kinetic study of the daytime atmospheric fate of (Z)-3-hexenal2012

    • Author(s)
      J.-H. Xing, M. Ono, A. Kuroda, K. Obi, K. Sato, and T. Imamura
    • Journal Title

      J. Phys. Chem. A

      Volume: 116 Pages: 8523-8529

    • Related Report
      2013 Final Research Report
  • [Journal Article] Air quality diagnosis from comprehensive observations of total OH reactivity and reactive trace species in urban central Tokyo2012

    • Author(s)
      A. Yoshino, Y. Kajii, et al.
    • Journal Title

      Atmospheric Environment

      Volume: Vol.49 Pages: 51-59

    • Related Report
      2013 Final Research Report
  • [Journal Article] 2008年W-PASS沖縄辺戸岬集中観測時の越境汚染の数値シミュレーションによる解析2012

    • Author(s)
      鵜野伊津志, 板橋秀一, 山地一代, 高見昭憲, 長田和雄, 横内陽子, 清水厚, 兼保直樹,梶井克純, 加藤俊吾, 古谷浩志
    • Journal Title

      大気環境学会誌

      Volume: 47(5) Pages: 195-204

    • NAID

      10030879695

    • Related Report
      2013 Final Research Report
  • [Journal Article] AMS and LC/MS analyses of SOA from the photooxidation of benzene and 1,3,5-trimethylbenzene in the presence of Nox : effects of chemical structure on SOA aging2012

    • Author(s)
      K. Sato, A. Takami, Y. Kato, T. Seta, Y. Fujitani, T. Hikida, A. Shimono, and T. Imamura
    • Journal Title

      Atmos. Chem. Phys

      Volume: 12 Pages: 4667-4682

    • Related Report
      2013 Final Research Report
  • [Journal Article] Observations of glyoxal and formaldehyde as metrics for the anthropogenic impact on rural photochemistry2012

    • Author(s)
      J.P. Digangi
    • Journal Title

      Atmospheric Chemistry and Physics

      Volume: 12 Issue: 20 Pages: 9529-9543

    • DOI

      10.5194/acp-12-9529-2012

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 北米産針葉樹から放出されるVOCsの化学分析とOH反応性測定2012

    • Author(s)
      山﨑昌平
    • Journal Title

      大気環境学会誌

      Volume: 47 Pages: 9-17

    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ox生成に関わる未計測VOCについて2012

    • Author(s)
      加藤俊吾
    • Journal Title

      大気環境学会誌

      Volume: 47

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Air quality diagnosis from comprehensive observations of total OH reactivity and reactive trace species in urban central Tokyo2012

    • Author(s)
      Yoshino, A., Nakashima, Y., Miyazaki, K., Kato, S., Suthawaree, J., Shimo, N., Matsunaga, S., Chatani, S., Apel, E., Greenberg, J., Guenther, A., Ueno, H., Sasaki, H., Hoshi, J., Yokota, H., Ishii, K., Kajii, Y.
    • Journal Title

      Atmos.Environ.

      Volume: 49 Pages: 51-59

    • DOI

      10.1016/j.atmosenv.2011.12.029

    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of extensive Compressed Natural Gas (CNG) usage on air quality2012

    • Author(s)
      J.Suthawaree, Y.Kajii, et al
    • Journal Title

      Atmospheric Environment

      Volume: 54 Pages: 296-307

    • DOI

      10.1016/j.atmosenv.2012.01.066

    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Identification of volatile organic compounds in suburban Bangkok, Thailand and their potential for ozone formation2012

    • Author(s)
      J. Suthawaree
    • Journal Title

      Atmospheric Research

      Volume: Vol. 104-105 Pages: 245-254

    • DOI

      10.1016/j.atmosres.2011.10.019

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observations of glyoxal and formaldehyde as metrics for the anthropogenic impact on rural photochemistry2012

    • Author(s)
      P.DiGangi, Y.Kajii, et al
    • Journal Title

      Atmos.Chem.Phys.Discuss.

      Volume: 12 Pages: 6049-6084

    • DOI

      10.5194/acpd-12-6049-2012

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A method to estimate the contribution of unidentified VOCs to OH reactivity2011

    • Author(s)
      S.Kato, T.Sato, Y.Kajii
    • Journal Title

      Atmospheric Environment

      Volume: 45 Issue: 31 Pages: 5531-5539

    • DOI

      10.1016/j.atmosenv.2011.05.074

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 東アジアから輸送される汚染大気中の炭素質エアロゾルの変動と発生源推定2011

    • Author(s)
      島田幸治郎, 高見昭憲, 加藤俊吾, 梶井克純, 畠山史郎
    • Journal Title

      大気環境学会誌

      Volume: 46 Pages: 1-9

    • NAID

      10027413950

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of non-methane hydrocarbon (NMHC) emissions based on an ambient airmeasurement in Tokyo area, Japan2010

    • Author(s)
      S.Matsunaga, S.Chatani, T.Morikawa, S.Nakatsuka, J.Suthawaree, Y.Tajima, S.Kato, Y.Kajii, H.Minoura
    • Journal Title

      Atmospheric Environment

      Volume: 44 Pages: 4982-4993

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Measurements of Volatile Organic Compounds in the middle of Central East China during Mount Tai Experiment 2006 (MTX 2006) : observation of regional background and impact of biomass burning2010

    • Author(s)
      J.Suthawaree, S.Kato, K.Okuzawa, Y.Kanaya, P.Pochanart, H.Akimoto, Z.Wang, Y.Kajii
    • Journal Title

      Atmos.Chem.Phys.

      Volume: 10 Pages: 1269-1285

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 東京郊外での多成分揮発性有機化合物の長期測定とOH反応性およびオゾン生成ポテンシャルによる大気質評価2010

    • Author(s)
      田島洋介, 加藤俊吾, Jeeranut Suthawaree, 梶井克純
    • Journal Title

      大気環境学会誌 45

      Pages: 56-65

    • NAID

      10026035931

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 自動車排気ガスのOHラジカル反応性および反応性成分測定2010

    • Author(s)
      亀井成美, 中嶋吉弘, 山崎晃司, 長田拓也, 宮崎洸治, 石井康一郎, 今野秀徳, 小林伸治, 加藤俊吾, 梶井克純
    • Journal Title

      大気環境学会誌 45

      Pages: 21-31

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Total OH reactivity and VOC analyses for gasoline vehicular exhaust with a chassis dynamometer2010

    • Author(s)
      Yoshihiro NAKASHIMA, Narumi KAMEI, Shinji KOBAYASHI, Yoshizumi KAJII
    • Journal Title

      Atmospheric Environment 44

      Pages: 468-475

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 都市域における大気光化学反応について2011

    • Author(s)
      梶井克純
    • Organizer
      光化学オキシダント調査検討会、環境省
    • Place of Presentation
      東京
    • Year and Date
      2011-10-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Diagonosisi of air quality by laser induced fluorescence technique2009

    • Author(s)
      Yoshizumi Kajii
    • Organizer
      8^<th> Workshop in the Series "Urban Air Quality and Traffic"
    • Place of Presentation
      Paris, France
    • Year and Date
      2009-06-15
    • Related Report
      2009 Annual Research Report
  • [Remarks] 朝日新聞 (2013年9月5日、全国版、18頁科学)

    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://www.atmchem.ges.kyoto-u.ac.jp/project.html

    • Related Report
      2013 Final Research Report
  • [Remarks] プロジェクト研究 文部科学省助成

    • URL

      http://www.atmchem.ges.kyoto-u.ac.jp/project.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 平成21-25年度 文部科学省科学研究費補助金 基盤研究(S)

    • URL

      http://www.atmchem.ges.kyoto-u.ac.jp/project.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://atmchem.apchem.metro-u.ac.jp

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://atmchem.apchem.metro-u.ac.jp

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://atmchem.apchem.metro-u.ac.jp/main-j.html

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi