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High-Perormance and Durable Electrodes in High-Temperature Solid Oxide Electrolysis Cell for Efficient Hydrogen Production

Research Project

Project/Area Number 21350114
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionUniversity of Yamanashi

Principal Investigator

UCHIDA Hiroyuki  山梨大学, クリーンエネルギー研究センター, 教授 (20127434)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2011: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2010: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2009: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Keywords電気化学 / 水蒸気電解 / 水素製造 / 混合導電体 / 金属ナノ粒子
Research Abstract

We have investigated novel high performance, durable electrodes in a solid oxide electrolysis cell(SOEC) for hydrogen production/power generation(solid oxide fuel cell, SOFC, mode). We have succeded in preparing mixed conducting samaria-or gadolinina-doped ceria with highly dispersed Ni or Ni-Co nanoparticle catalysts. The performance of Ni-Co/SDC hydrogen electrode was found to be improved with increasing ionic conductivity in the solid oxide electrolyte. We also found that(Sr_<1-x> Ce_x) MnO_<3±δ> exhibited a good perforamnce as the SOFC cathode.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (23 results)

All 2012 2011 2010 2009 Other

All Journal Article (5 results) (of which Peer Reviewed: 2 results) Presentation (15 results) Remarks (3 results)

  • [Journal Article] Performances of Metal Particle-Dispersed Ceria Hydrogen Electrodes in Reversible SOFCs2011

    • Author(s)
      H. Uchida, R. Nishida, M. Tatsuzawa, H. Nishino, K. Kakinuma, M. Watanabe
    • Journal Title

      ECS Trans

      Volume: Vol.35(No.1) Pages: 1811-1816

    • URL

      http://dx.doi.org/10.1149/1.3570169

    • Related Report
      2011 Final Research Report
  • [Journal Article] Performances of Metal Particle-Dispersed Ceria Hydrogen Electrodes in Reversible SOFCs2011

    • Author(s)
      H.Uchida, R.Nishida, M.Tatsuzawa, H.Nishino, K.Kakinuma, M.Watanabe
    • Journal Title

      ECS Trans.

      Volume: 35 Issue: 1 Pages: 1811-1816

    • DOI

      10.1149/1.3570169

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Performances of Metal Particle-Dispersed Ceria Hydrogen Electrodes in Reversible SOFCs2010

    • Author(s)
      H.Uchida
    • Journal Title

      ECS moans., SOFC XII

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Synthesis of Nickel Nanoparticles Supported on Hollow Samaria-Doped Ceria Particles via the Solution-Spray Plasma Technique2009

    • Author(s)
      R. Nishida, K. Kakinuma, H. Nishino, T. Kamino, H. Yamashita, M. Watanabe, H. Uchida
    • Journal Title

      Anode, Catalysts for SOFCs, Solid State Ionics

      Volume: Vol.180(No.14-16) Issue: 14-16 Pages: 968-972

    • DOI

      10.1016/j.ssi.2009.04.005

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Nickel Nanoparticles Supported on Hollow Samaria-Doped Ceria Particles via the Solution-Spray Plasma Technique : Anode Catalysts for SOFCs2009

    • Author(s)
      R.Nishida
    • Journal Title

      Solid State Ionics 180

      Pages: 968-972

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] クリーンエネルギーシステムと材料開発:電力〓水素の高効率変換をめざして2012

    • Author(s)
      内田裕之
    • Organizer
      材料とイノベーション特別講演
    • Place of Presentation
      東芝電力システム社(横浜)(招待講演)
    • Year and Date
      2012-01-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高温水蒸気電解-SOFC可逆作動セルによる電力の平準化2011

    • Author(s)
      内田裕之
    • Organizer
      2011年電気化学会関東支部セミナー
    • Place of Presentation
      明電舎大崎会館(東京)
    • Year and Date
      2011-12-14
    • Related Report
      2011 Final Research Report
  • [Presentation] 高温水蒸気電解-SOFC可逆作動セルによる電力の平準化2011

    • Author(s)
      内田裕之
    • Organizer
      2011年電気化学会関東支部セミナー
    • Place of Presentation
      明電舎大崎会館(東京)(招待講演)
    • Year and Date
      2011-12-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] 可逆作動SOFC用Ni-Co高分散SDC水素極特性への電解質の導電率の効果2011

    • Author(s)
      立澤正仁,西野華子,渡辺政廣,内田裕之
    • Organizer
      第37回固体イオニクス討論会
    • Place of Presentation
      白兎会館(鳥取市)
    • Year and Date
      2011-12-09
    • Related Report
      2011 Final Research Report
  • [Presentation] 可逆作動SOFC用Ni-Co高分散SDC水素極特性への電解質の導電率の効果2011

    • Author(s)
      立澤正仁, 西野華子, 渡辺政廣, 内田裕之
    • Organizer
      第37回固体イオニクス討論会
    • Place of Presentation
      鳥取市・白兎会館
    • Year and Date
      2011-12-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] Performances of Metal Particle-Dispersed Ceria Hydrogen Electrodes in Reversible SOFCs2011

    • Author(s)
      H. Uchida, R. Nishida, M. Tatsuzawa, H. Nishino, K. Kakinuma, M. Watanabe
    • Organizer
      12th Solid Oxide Fuel Cells(219th ECS Meeting)
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      2011-05-05
    • Related Report
      2011 Final Research Report
  • [Presentation] Performances of Metal Particle-Dispersed Ceria Hydrogen Electrodes in Reversible SOFCs2011

    • Author(s)
      H.Uchida, R.Nishida, M.Tatsuzawa, H.Nishino, K.Kakinuma, M.Watanabe
    • Organizer
      12th Solid Oxide Fuel Cells (219th ECS Meeting)
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      2011-05-05
    • Related Report
      2011 Annual Research Report
  • [Presentation] 可逆作動SOFC用二重層型電極の開発とPEFC用電極触媒・電解質膜の評価法2010

    • Author(s)
      内田裕之
    • Organizer
      山梨大学新技術説明会
    • Place of Presentation
      JSTホール(東京)
    • Year and Date
      2010-12-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] Ce0. 8Sm0. 201. 9を添加したn型電子伝導体(Sr1-xCex) MnO3±δのSOFCカソードへの応用2010

    • Author(s)
      植松佑太,柿沼克良,西野華子,内田裕之,渡辺政廣
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台市情報・産業プラザ(仙台市)
    • Year and Date
      2010-11-25
    • Related Report
      2011 Final Research Report
  • [Presentation] Ce_0.8Sm_0.2O_1.9を添加した_n型電子伝導体(Sr_1-xCe_x)MnO_3±δのSOFCカソードへの応用2010

    • Author(s)
      内田裕之
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台市情報・産業プラザ
    • Year and Date
      2010-11-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Polarization Properties of Oxygen and Hydrogen Electrodes for Reversible Solid Oxide Fuel Cells2010

    • Author(s)
      H. Uchida, H. Nishino, K. Kakinuma, M. Watanabe
    • Organizer
      3rd International Congress on Ceramics
    • Place of Presentation
      グランキューブ大阪(大阪市)
    • Year and Date
      2010-11-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Polarization Properties of Oxygen and Hydrogen Electrodes for Reversible Solid Oxide Fuel Cells2010

    • Author(s)
      H.Uchida
    • Organizer
      3rd International Congress on Ceramics
    • Place of Presentation
      グランキューブ大阪(大阪市) 招待講演
    • Year and Date
      2010-11-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 噴霧プラズマ法および含浸法で調製したNi-Co高分子散セリアの電極特性2009

    • Author(s)
      西田龍太
    • Organizer
      第18回SOFC研究発表会
    • Place of Presentation
      科学技術館(東京)
    • Year and Date
      2009-12-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属高分散セリアの噴霧プラズマ合成とSOFCアノード特性2009

    • Author(s)
      西田龍太
    • Organizer
      第50回電池討論会
    • Place of Presentation
      京都国際会館(京都)
    • Year and Date
      2009-12-01
    • Related Report
      2009 Annual Research Report
  • [Presentation] n型電子伝導性(Sr_<1-x>Ce_x)MnO_<3-δ>のSOFCカソードへの応用2009

    • Author(s)
      植松佑太
    • Organizer
      第50回電池討論会
    • Place of Presentation
      京都国際会館(京都)
    • Year and Date
      2009-12-01
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://erdb.yamanashi.ac.jp/rdb/A_DispInfo.Scholar/8/43A6399EA0398212.html

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://erdb.yamanashi.ac.jp/rdb/A_DispInfo.Scholar/8/43A6399EA0398212.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.abll.yamanashi.ac.jp/~mwatanab/index.html

    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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