Fabrication of alkaline type membrane for fuel cells and Evaluation of fuel cell properties
Project/Area Number |
21360327
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic materials/Physical properties
|
Research Institution | Tokyo City University |
Principal Investigator |
NAGAI Masayuki 東京都市大学, 総合研究所, 教授 (80112481)
|
Co-Investigator(Kenkyū-buntansha) |
MUNAKATA Fumio 東京都市大学, 工学部, 教授 (50386356)
|
Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2010: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2009: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
|
Keywords | 燃料電池 / 新エネルギー / 化学プロセス / 電極触媒 / 材料評価 / アルカリ形 / 無機有機コンポジット / 電解質膜 / 水酸化物イオン / 高導電性 / ハイブリッド / 無機・有機複合体 / 製膜性 / 水酸化物伝導体 / イオン交換容量 / 電気伝導度 / エポキシ変性シリコン / クラスター構造 / 架橋剤 / 電池特性 / アルカリ膜形燃料電池 / シリコーン系材料 / イオン伝導率 / 電池出力密度 / 電極イオノマー / 電極作製法 |
Research Abstract |
The sample which showed the highest conductivity value was a film prepared using tri-methylamine and the value was 0.9mS/cm at 60℃ under 80% relative humidity. From the relationship between structure and properties, it was found that the homogeneity of the film was largely important for the ionic conductivity and it was possible to control the conductivity by choosing the starting materials. The single fuel cell performance was measured under the flow of hydrogen and oxygen. The highest power density of the cell was 016mW/cm^2 and the highest current density was 0.8mA/cm^2. The complex impedance measurement during the cell performance indicated that a resistance was observed in the frequency range between the high frequency part and 10Hz. It may be due to small ionic conduction and poor diffusion near the catalyst particles. In this study, development of novel solid electrolytes and electrodes for AMFC was conducted and its cell performance was demonstrated.
|
Report
(4 results)
Research Products
(31 results)