| Project/Area Number |
21550004
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Physical chemistry
|
|---|
| Research Institution | University of Tsukuba |
|---|
Principal Investigator |
|
|---|
| Research Collaborator |
ANTON Kokalj スロベニア・J.Stefan 研究所, 物理化学部, 上級研究員
ORITA Hideo 産業技術総合研究所, ナノシステム研究部門, 主務
SAKURAI Masataka 筑波大学, 大学院・数理物質科学研究科, 学生
|
|---|
| Project Period (FY) |
2009 – 2011
|
| Project Status |
Completed (Fiscal Year 2011)
|
| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
|---|
| Keywords | 表面 / 界面 / 亜酸化窒素 / パラジウム / イリジウム / NOx処理 / ステップ表面 / 窒素の脱離 / 脱離の角度分布 / 表面窒素の除去 / パラジム / 私応経路 / 窒素の放出 / 窒素酸化物処理 / 角度分解昇温脱離法 / 吸着分子配向 |
|---|
| Research Abstract |
The structure of dissociating intermediate N_2O in the catalyzed NO reduction on stepped Pd(211)=[(s)3(111)×(001)] has been examined from the spatial distribution of emitted N_2 and DFT-GGA model calculations. The active N_2O is adsorbed through the terminal N on a (111) terrace and its dissociation is completed by the terminal oxygen removal onto stepped Pd atoms. The N_2 emission is concentrated along the rupture bond axis, i.e., in the plane along the step up-and-down direction.
|
