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Preparation and Reactivity of Coordinatively Unsaturated Low Valent Noble Metal Clusters with Imido and Phosphinidene Ligand

Research Project

Project/Area Number 21550064
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionOsaka Prefecture University

Principal Investigator

MATSUZAKA Hiroyuki  大阪府立大学, 大学院・理学系研究科, 教授 (50221586)

Co-Investigator(Kenkyū-buntansha) TAKEMOTO Shin  大阪府立大学, 大学院・理学系研究科, 教授 (20347511)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords有機金属化学 / クラスター錯体 / ルテニウム / 架橋イミド配位子 / 架橋アミド配位子 / 架橋ヒドリド配位子 / 配位不飽和クラスター / スタニレン配位子 / 架橋アルキリジン配位子 / 架橋ビニリデン配位子 / アルキン / 環化付加 / メタラサイクル / 白金 / カーバイド / フィッシャー・トロプシュ反応 / エチリデン
Research Abstract

Novel homo-and heterometallic clusters of ruthenium, cobalt, and platinum containing bridging imido-or phosphinidene ligands were prepared and both spectroscopically and crystallographically characterized. Unique transformation of substrate molecules including CO, CNR, and alkynes on the cluster readily proceeded on the clusters to give a series of new type of ligand sets via C-C, C-N, and C-H bond formation and C-H bond cleavage.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (49 results)

All 2012 2011 2010 2009

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (40 results)

  • [Journal Article] Recent Advances in the Chemistry of Ruthenium Carbido Complexes2012

    • Author(s)
      Takemoto, S. and Matsuzaka, H.
    • Journal Title

      Coord. Chem. Rev

      Volume: 256 Pages: 574-588

    • URL

      http://dx.doi.org/10.1016/j.ccr.2011.10.025

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Recent Advances in the Chemistry of Ruthenium Carbido Complexes2012

    • Author(s)
      Takemoto, S.
    • Journal Title

      Coord.Chem.Rev.

      Volume: 256 Issue: 5-8 Pages: 574-588

    • DOI

      10.1016/j.ccr.2011.10.025

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Reactivity of Coordinatively Unsaturated Dinuclear Ruthenium Bridging Imido Complexes2011

    • Author(s)
      Takemoto, S.; Kobayashi, T.; Ito, T.; Inui, A.; Karitani, K.; Katagiri, S.; Masuhara, Y.; Matsuzaka, H.
    • Journal Title

      Organometallics

      Volume: 30 Issue: 8 Pages: 2160-2172

    • DOI

      10.1021/om1011227

    • Related Report
      2011 Annual Research Report 2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dinuclear Cp* Co Amido and Alkoxo Complexes : Synthesis, Structures, and Reactivity2011

    • Author(s)
      Takemoto, S.; Honma, T.; Matsuzaka, H.
    • Journal Title

      Organometallics

      Volume: 30 Issue: 5 Pages: 1013-1020

    • DOI

      10.1021/om101065z

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dinuclear Cp^*Co Amido and Alkoxo Complexes : Synthesis, Structures, and Reactivity2011

    • Author(s)
      Takemoto, S.
    • Journal Title

      Organometallics

      Volume: 30 Pages: 1013-1020

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Bimetallic Ru_2Pt Complex Containing a Trigonal-Planarμ_3-Carbido Ligand : Formation, Structure, and Reactivity Relevant to The Fischer-Tropsch Process2009

    • Author(s)
      Takemoto, S.; Morita, H.; Karitani, K.; Fujiwara, H.; Matsuzaka, H.
    • Journal Title

      J. Am. Chem. Soc

      Volume: 131 Pages: 18026-18027

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Bimetallic Ru_2Pt Complex Containing a Trigonal-Planar μ3-Carbido Lig and : Formation, Structure, and Reactivity Relevant to the Fischer-Tropsch Process2009

    • Author(s)
      Takemoto, S.
    • Journal Title

      Journal of the American Chemical Society 131

      Pages: 18026-18027

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Induction of One-handed Helical Oligo(p-benzammide)s by Domino Effect Based on Planar-axial-helical Chirality Relay2009

    • Author(s)
      Kamikawa, K.
    • Journal Title

      Chemical Communications

      Pages: 1201-1203

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Organocatalysts with One-handed Helix and Their Application to the Kinetic Resolution of Secondary Alcohol2009

    • Author(s)
      Kamikawa, K.
    • Journal Title

      Research on Chemical Intermediates 35

      Pages: 931-937

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 2核ルテニウムイミド錯体と有機リチウム試薬との反応2012

    • Author(s)
      藤原裕美・竹本真・松坂裕之
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学
    • Year and Date
      2012-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] 末端アミド配位子を有するアニオン性Cp* Ru錯体の合成と反応性2012

    • Author(s)
      湯本純弘・竹本真・松坂裕之
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学
    • Year and Date
      2012-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] 2核ルテニウムアミド錯体と2価スズ化合物との反応によるスタニレンおよびスタニリン錯体の合成2012

    • Author(s)
      吉井要・竹本真・松坂裕之
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学
    • Year and Date
      2012-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] 2核ルテニウムアミド錯体と2価スズ化合物との反応によるスタニレンおよびスタニリン錯体の合成2012

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学日吉キャンパス
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] 2核ルテニウムイミド錯体と有機リチウム試薬との反応2012

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学日吉キャンパス
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] 末端アミド配位子を有するアニオン性Cp*Ru錯体の合成と反応性2012

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学日吉キャンパス
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] A Bimetallic Ru_2Pt Complexes Containing a Trigonal-Planarμ_3-Carbido Ligand : Formation, Structure, and Reactivity Relevant to The Fischer-Tropsch Process2011

    • Author(s)
      松坂裕之
    • Organizer
      International Symposium on Nano Science and Functional Materials : Post-symposium of International Symposium on Catalysis and Fine Chemicals 2011(C & FC2011)
    • Place of Presentation
      首都大学東京
    • Year and Date
      2011-12-10
    • Related Report
      2011 Final Research Report
  • [Presentation] A Bimetallic Ru_2Pt Complexes Containing a Trigonal-Planar μ_3-Carbido Ligand : Formation, Structure, and Reactivity Relevant to The Fischer-Tropsch Process2011

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      International Symposium on Nano Science and Functional Materials : Post-symposium of International Symposium on Catalysis and Fine Chemicals 2011 (C&FC2011)
    • Place of Presentation
      首都大学東京南大沢キャンパス(招待講演)
    • Year and Date
      2011-12-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] アニオン性Ruアミド錯体の合成と性質2011

    • Author(s)
      湯本純弘・竹本真・松坂裕之
    • Organizer
      第61回錯体化学会討論会
    • Place of Presentation
      岡山理科大学
    • Year and Date
      2011-09-18
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 2核ルテニウム錯体上での直鎖状炭素鎖成長反応2011

    • Author(s)
      大下雅樹・久川善寛・竹本真・松坂裕之
    • Organizer
      第61回錯体化学会討論会
    • Place of Presentation
      岡山理科大学
    • Year and Date
      2011-09-17
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 架橋NH_2配位子を利用したパラジウムおよび白金多核錯体の選択的合成2011

    • Author(s)
      大畠潤・竹本真・松坂裕之
    • Organizer
      第61回錯体化学会討論会
    • Place of Presentation
      岡山理科大学
    • Year and Date
      2011-09-17
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 分子内水素結合によって保持された異種金属間結合の形成2011

    • Author(s)
      吉井要・竹本真・松坂裕之
    • Organizer
      第61回錯体化学会討論会
    • Place of Presentation
      岡山理科大学
    • Year and Date
      2011-09-17
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 2核ルテニウムイミドジヒドリド錯体の合成およびN-H結合形成反応2011

    • Author(s)
      竹本真・山崎祐亮・松坂裕之
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-07
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] A Bimetallic Ru2Pt Complex Containing a Trigonal-Planarμ_3-Carbido Ligand : Formation, Structure, and Reactivity Relevant to The Fischer-Tropsch Process2011

    • Author(s)
      松坂裕之、竹本真
    • Organizer
      14th Asian Chemical Congress
    • Place of Presentation
      バンコク
    • Year and Date
      2011-09-06
    • Related Report
      2011 Final Research Report
  • [Presentation] A Bimetallic Ru_2Pt Complexes Containing a Trigonal-Planar μ_3-Carbido Ligand : Formation, Structure, and Reactivity Relevant to The Fischer-Tropsch Process2011

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      14th Asian Chemical Congress
    • Place of Presentation
      バンコク、タイ(招待講演)
    • Year and Date
      2011-09-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] 2核Ruイミド・アレン錯体の合成と構造および反応性2011

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春季年会 (2011)講演予稿集(震災により学会開催中止)
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 2核Ruアミド錯体と亜鉛化合物との反応による金属-金属結合形成反応2011

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春季年会 (2011)講演予稿集(震災により学会開催中止)
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] アニオン性Ruアミド錯体の合成2011

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春季年会 (2011)講演予稿集(震災により学会開催中止)
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 白金ジアミドおよびテトラアミド錯体を利用したアミド架橋多核金属錯体の合成2011

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春季年会 (2011)講演予稿集(震災により学会開催中止)
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 鎖状構造を有するアミド架橋パラジウム3核および4核錯体の合成2011

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春季年会 (2011)講演予稿集(震災により学会開催中止)
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and Reactivity of Dinuclear Cp* Rh Amido and Imido Complexes2010

    • Author(s)
      大川智博、大槻尚平、竹本真、松坂裕之
    • Organizer
      PACIFICCHEM 2010
    • Place of Presentation
      ホノルル
    • Year and Date
      2010-12-18
    • Related Report
      2011 Final Research Report
  • [Presentation] Formation and Reactivity of a Bimetallic Ruthenium Platinum Carbido Complex2010

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      環太平洋国際化学会議(PACIFICHEM2010)
    • Place of Presentation
      ホノルル
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Formation and Reactivity of a Bimetallic Ruthenium Platinum Carbido Complex2010

    • Author(s)
      竹本真、苅谷賢二、森田英伸、松坂裕之
    • Organizer
      PACIFICCHEM 2010
    • Place of Presentation
      ホノルル
    • Year and Date
      2010-12-17
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis and Reactivity of Dinuclear Cp^*Rh Amido and Imido Complexes2010

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      環太平洋国際化学会議(PACIFICHEM2010)
    • Place of Presentation
      ホノルル
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 架橋スズ配位子を有する2核Ruアミドおよびイミド錯体の合成と反応性2010

    • Author(s)
      山崎祐亮・井本良平・竹本真・松坂裕之
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-30
    • Related Report
      2011 Final Research Report
  • [Presentation] 架橋メチリジン配位子を有するRu2Au異種3核錯体の合成と反応性2010

    • Author(s)
      田中淳・竹本真・藤原秀紀・松坂裕之
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-30
    • Related Report
      2011 Final Research Report
  • [Presentation] 架橋スズ配位子を有する2核Ruアミドおよびイミド錯体の合成と反応性2010

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪国際交流センター
    • Year and Date
      2010-09-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] 架橋メチリジン配位子を有するRu_2Au異種3核錯体の合成と反応性2010

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪国際交流センター
    • Year and Date
      2010-09-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] 三方平面型Ru2Ptカーバイド錯体における炭素-炭素結合形成反応2010

    • Author(s)
      竹本真・苅谷賢二・大畠潤・吉井要・松坂裕之
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学
    • Year and Date
      2010-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] 三方平面型Ru_2Ptカーバイド錯体における炭素-炭素結合形成反応2010

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] A Bimetallic Ru2Pt Complexes Containing a Trigonal-Planarμ_3-Carbido Ligand : Formation, Structure, and Reactivity Relevant to The Fischer-Tropsch Proce2010

    • Author(s)
      竹本真、森田英伸、苅谷賢二、藤原秀紀、松坂裕之
    • Organizer
      XXIV International Conference on Organometallic Chemistry-ICOMC2010
    • Place of Presentation
      台北
    • Year and Date
      2010-07-20
    • Related Report
      2011 Final Research Report
  • [Presentation] A Bimetallic Ru_2Pt Complexes Containing a Trigonal-Planar μ_3-Carbido Ligand : Formation, Structure, and Reactivity Relevant to The Fischer-Tropsch Process2010

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      第24回有機金属化学国際会議(ICOMC2010)
    • Place of Presentation
      台北国際会議場
    • Year and Date
      2010-07-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] 2核Ruイミド・メチリジン錯体への異種金属導入反応2010

    • Author(s)
      田中淳・苅谷賢二・本間崇志・竹本真・藤原秀紀・松坂裕之
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-29
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 架橋スズ配位子を有する2核Ruアミドおよびイミド錯体の合成2010

    • Author(s)
      山崎祐亮・竹本真・藤原秀紀・松坂裕之
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-29
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 2核Ruアザメタラサイクル錯体の合成とヨウ素による酸化反応2010

    • Author(s)
      井本良平・竹本真・藤原秀紀・松坂裕之
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-29
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] Ruthenium-Platinum Carbido Complex via C-H Bond Activation of a Bridging Methylene Ligand2010

    • Author(s)
      竹本真、苅谷賢二、森田英伸、松坂裕之
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-28
    • Related Report
      2011 Final Research Report
  • [Presentation] Ruthenium-Platinum Carbido Complex via C-H Bond Activation of A Bridging Methylene Ligand2010

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 2核ルテニウムアミド錯体と水素分子との反応:ヒドリド誘導体の生成と性質2009

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2009-09-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] 架橋ビニリデン配位子を有する配位不飽和な2核ルテニウムイミド錯体の合成と反応性2009

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2009-09-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] Ru_2Ptクラスター上での三方平面型μ3-カーバイド配位子の生成と反応性2009

    • Author(s)
      竹本真・松坂裕之
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      同志社大学(今出川)
    • Year and Date
      2009-09-11
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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