Control of nanoporous structures induced by fluorine-containing block copolymers and star-branched polymers
| Project/Area Number |
21550114
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Hosei University (2010-2011)
Tokyo Institute of Technology (2009) |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | 高分子合成 / リビングアニオン重合 / パーフルオロアルキル基 / 官能基化ポリマー / 表面解析 / X線光電子分光法 / 接触角測定 / 撥油性 / 撥水性 / リビンダアニオン重合 |
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| Research Abstract |
The precise syntheses of the fluorine-containing block copolymers and star-branched polymers have been successfully established on the basis of living anionic polymerization techniques. Supercritical carbon dioxide processing of the obtained polymer films induced the hydro-and oleophobic film surface formation due to the highly enrichment of fluorine components at the top of film surfaces. In addition, the phase transition behavior of nano-structures was examined under supercritical carbon dioxide conditions in order to optimize the processing conditions to control the size and shape of the nanoporous structures.
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Report
(4 results)
Research Products
(71 results)
