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Synthesis and evaluation of solid-emissive fluorescent dyes useful for energy conversion

Research Project

Project/Area Number 21550181
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic industrial materials
Research InstitutionKochi University

Principal Investigator

YOSHIDA Katsuhira  高知大学, 教育研究部・総合科学系, 教授 (30036595)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywords固体発光性色素 / 蛍光色素 / 光物性 / 単結晶X線構造 / 近赤外蛍光色素 / 波長変換機能 / 蛍光フィルム / 耐光性 / 発光性ホウ素錯体 / 波長変換用資材 / 分子間相互作用
Research Abstract

To develop new fluorescent dyes useful for energy conversion, novel polyheterocyclic solid-emissive fluorescent dyes have been designed and synthesized. Their potophysical properties in solution and in the solid state were measured, and the relation between the solid-fluorescence and X-ray crystal structure was investigated. Moreover, the photostability of the dye-doped films have been prepared and investigated. The dye-doped polymer films showed excellent wavelength conversion ability and exhibited good photostability.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (48 results)

All 2012 2011 2010 2009

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (36 results)

  • [Journal Article] Photophysical properties and photostability of novel unsymmetric poly-cyclicphenazine-type D-π-A fluorescent dyes and the dye-doped films2012

    • Author(s)
      H. E. Ooyama, T. Ide, T. Tanigami, H. Yamasaki, A. Harada, Y. Nagahama, and K. Yoshida
    • Journal Title

      Journal of Photochemistry and Photobiology A : Chemistry

      Volume: 230 Pages: 38-46

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photophysical properties and photostability of novel symmetric polycyclicphenazine-type fluorescent dyes and the dye-doped films2012

    • Author(s)
      H. E. Ooyama, T. Ide, H. Yamasaki, Y. Nagahama, A. Ono, and K. Yoshida
    • Journal Title

      Dyes and Pigments

      Volume: 94 Pages: 103-112

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photophysical properties and photostability of novel unsnmmetric polycyclicphenazine-type D-π-A fluorescent dyes and the dye-doped films2012

    • Author(s)
      Haruka Egawa Ooyama, Katsuhira Yoshida
    • Journal Title

      Journal of Photochemistry and Photobiology A : Chemistry

      Volume: 230 Issue: 1 Pages: 38-46

    • DOI

      10.1016/j.jphotochem.2011.12.009

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and photophysical properties of structural isomers of novel 2, 10-disubstituted benzofuro[ 2, 3-e] naphthoxazole-type fluo-rescent dyes.2011

    • Author(s)
      H. E. Ooyama, Y. Ooyama, T. Hino, T. Sakamoto, T. Yamaguchi, and K. Yoshida
    • Journal Title

      Dyes and Pigments

      Volume: 91 Pages: 481-488

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and photophysical properties of structural isomers of novel 2,10-disubstituted benzofuro[2,3-e]naphthoxazole-type fluorescent dyes2011

    • Author(s)
      Haruka Egawa Ooyama, Katsuhira Yoshida
    • Journal Title

      Dyes and Pigments

      Volume: 91 Issue: 3 Pages: 481-488

    • DOI

      10.1016/j.dyepig.2011.03.031

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Photophysical Properties of Structural Isomers of Novel 2,10-Disubstituted Benzofuro[2,3-e]naphthoxazole-type Fluorescent Dyes.2011

    • Author(s)
      Haruka Egawa Ooyama, Katsuhira Yoshida
    • Journal Title

      Dyes and Pigments

      Volume: 80(in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heterocyclic quinol-type fluorophores, Effect of forming a continuous intermolecular hydrogen bonding chain between fluorophores on the solid-state fluorescence properties2010

    • Author(s)
      Y. Ooyama, S. Nabeshima, T. Mamura, H. E. Ooyama, and K. Yoshida
    • Journal Title

      Tetrahedron

      Volume: 66 Pages: 7954-7960

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Heterocyclic quinol-type fluorophores, Effect of forming a continuous intermolecular hydrogen bonding chain between fluorophores on the solid-state fluorescence properties.2010

    • Author(s)
      Yousuke Ooyama, Katsuhira Yoshida
    • Journal Title

      Tetrahedron

      Volume: 66 Pages: 7954-7960

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photophysical properties of phenanthro[ 9, 10-d] imidazole-type fluo-rescent hosts upon inclusion of organic solvent molecules2009

    • Author(s)
      Y. Ooyama, H. Kumaoka, K. Uwada, and K. Yoshida
    • Journal Title

      Tetrahedron

      Volume: 65 Pages: 8336-8343

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Drastic solid-state fluorescence enhancement behavior of phenanthro-[ 9, 10-d] imidazole-type fluorescent hosts upon inclusion of carboxylic acids2009

    • Author(s)
      Y. Ooyama, K. Uwada, H. Kumaoka, and K. Yoshida
    • Journal Title

      Eur. J. Org. Chem.

      Volume: 34 Pages: 5979-5990

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Drastic fluorescence enhancement behavior of phenanthro [9, 10-d] imidazole-type fluorescent hosts upon inclusion of carboxylic acids2009

    • Author(s)
      Yousuke Ooyama
    • Journal Title

      Eur.J.Org.Chem. 34

      Pages: 5979-5990

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photophysical properties of phenanthro [9, 10-d] imidazole-type fluorescent hosts upon inclusion of organic solvent molecules2009

    • Author(s)
      Yousuke Ooyama
    • Journal Title

      Tetrahedron 65

      Pages: 8336-8343

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] ラクトン-ラクタム系蛍光色素の合成と溶液、固体、高分子フィルム中における光物性2012

    • Author(s)
      田中純平、洲口達哉、吉田勝平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学
    • Year and Date
      2012-03-27
    • Related Report
      2011 Final Research Report
  • [Presentation] 複素多環系蛍光色素の合成と溶液、固体、高分子フィルム中における光物性2012

    • Author(s)
      宮田祥平、地海拓未、吉田勝平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学
    • Year and Date
      2012-03-27
    • Related Report
      2011 Final Research Report
  • [Presentation] ラクトン-ラクタム系蛍光色素の合成と溶液、固体、高分子フィルム中における光物性2012

    • Author(s)
      田中純平、吉田勝平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(横浜市)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 複素多環系蛍光色素の合成と溶液、固体、高分子フィルム中における光物性2012

    • Author(s)
      宮田祥平、吉田勝平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(横浜市)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 縮合多環フェナジン系蛍光色素の高分子フィルム中における光物性と耐光性評価2012

    • Author(s)
      上村和稔、宮里一吉、吉田勝平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学
    • Year and Date
      2012-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] 縮合多環キノイド系蛍光色素の高分子フィルム中における光物性と耐光性評価2012

    • Author(s)
      上村和稔、板倉章博、吉田勝平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学
    • Year and Date
      2012-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] 縮合多環フェナジン系蛍光色素の高分子フィルム中における光物性と耐光性評価2012

    • Author(s)
      上村和稔、吉田勝平
    • Organizer
      2011年日本化学会西日本大会
    • Place of Presentation
      慶応義塾大学(横浜市)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] 縮合多環キノイド系蛍光色素の高分子フィルム中における光物性と耐光性評価2012

    • Author(s)
      上村和稔、吉田勝平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(横浜市)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] ピーマンにおけるフラボノイド生合成に対する光の影響2012

    • Author(s)
      手林慎一、吉田勝平
    • Organizer
      日本農芸化学会中国四国支部第32回講演会
    • Place of Presentation
      鳥取大学
    • Year and Date
      2012-01-21
    • Related Report
      2011 Final Research Report
  • [Presentation] ピーマンにおけるフラボノイド生合成に対する光の影響2012

    • Author(s)
      手林慎一、吉田勝平
    • Organizer
      日本農芸化学会中国四国支部第32回講演会
    • Place of Presentation
      鳥取大学(鳥取市)
    • Year and Date
      2012-01-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] ジラクトン系蛍光色素の合成と光物性評価2011

    • Author(s)
      田中純平、吉田勝平
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      徳島大学
    • Year and Date
      2011-11-13
    • Related Report
      2011 Final Research Report
  • [Presentation] 縮合多環キノイド系蛍光色素の合成と光物性2011

    • Author(s)
      上村和稔、吉田勝平
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      徳島大学
    • Year and Date
      2011-11-13
    • Related Report
      2011 Final Research Report
  • [Presentation] ジラクトン系蛍光色素の合成と光物性2011

    • Author(s)
      田中純平、吉田勝平
    • Organizer
      2011年日本化学会西日本大会
    • Place of Presentation
      徳島大学(徳島市)
    • Year and Date
      2011-11-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] 縮合多環キノイド系蛍光色素の合成と光物性2011

    • Author(s)
      上村和稔、吉田勝平
    • Organizer
      2011年日本化学会西日本大会
    • Place of Presentation
      徳島大学(徳島市)
    • Year and Date
      2011-11-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] 固体発光性蛍光色素の波長変換特性と植物栽培への応用2011

    • Author(s)
      吉田勝平
    • Organizer
      近畿化学協会機能性色素部会研修セミナー(招待講演)
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2011-10-11
    • Related Report
      2011 Final Research Report
  • [Presentation] 固体発光性蛍光色素の波長変換特性と植物栽培への応用2011

    • Author(s)
      吉田勝平
    • Organizer
      近畿化学協会機能性色素部会研修セミナー
    • Place of Presentation
      大阪府立大学(大阪府堺市)(招待講演)
    • Year and Date
      2011-10-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] 近赤外発光を示す新規な複素多環アゾ-ヒドラゾン系ホウ素錯体の合成と光物性評価2011

    • Author(s)
      大山晴香、坂本雄大、池麻希、吉田勝平
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-11
    • Related Report
      2011 Final Research Report
  • [Presentation] 新規な複素多環アゾ-ヒドラゾン系ホウ素錯体の合成と光物性評価2011

    • Author(s)
      坂本雄大、池麻希、吉田勝平
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-11
    • Related Report
      2011 Final Research Report
  • [Presentation] 複素多環アントラキノイド系蛍光色素の合成と機能評価2011

    • Author(s)
      上村和稔、板倉章博、吉田勝平
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-11
    • Related Report
      2011 Final Research Report
  • [Presentation] 近赤外発光を示す新規な複素多環アゾーヒドラゾン系ホウ素錯体の合成と光物性評価2011

    • Author(s)
      大山晴香
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春季年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新規な複素多環アゾーヒドラゾン系ホウ素錯体の合成と光物性評価2011

    • Author(s)
      坂本雄大
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春季年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 複素多環アントラキノイド系蛍光色素の合成と光物性評価2011

    • Author(s)
      板倉章博
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春季年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and photophysical properties of novel fluorescent azo-hydrazone-type boron complexes2010

    • Author(s)
      H. E. Ooyama, and K. Yoshida
    • Organizer
      International Chemical Congress of Pacific Basin Societies(PACIFICHEM 2010)
    • Place of Presentation
      ハワイ(米国)
    • Year and Date
      2010-12-17
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis and photophysical properties of novel fluorescent azo-hydrazone-type boron complexes.2010

    • Author(s)
      Haruka Ooyama
    • Organizer
      International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010)
    • Place of Presentation
      ハワイ(米国)
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 蛍光色素含有波長変換フィルムの植物組織培養への応用2010

    • Author(s)
      大山晴香、浜田和俊、島崎一彦、吉田勝平
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-28
    • Related Report
      2011 Final Research Report
  • [Presentation] Development of New Wavelength Conversion Films including Fluorescent Dyes and their Photophysical Properties and Light Stability2009

    • Author(s)
      Haruka E.Ooyama
    • Organizer
      6th International Symposium on Light in Horticulture
    • Place of Presentation
      Tsukuba International Congress Center
    • Year and Date
      2009-11-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] Synthesis and Photophysical Properties of Polycyclic Phenazine-type Fluorescent Dyes(2)2009

    • Author(s)
      K. Yoshida, H. E. Ooyama
    • Organizer
      The Eleventh International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-11
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] Synthesis and Photophysical Properties of New Oxazole-type Fluorescent Dyes2009

    • Author(s)
      T. Sakamoto, H. E. Ooyama, K. Yoshida
    • Organizer
      The Eleventh International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-11
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] Synthesis and Photophysical Properties of Poly-cyclic Phenazine-type Fluorescent Dyes(1)2009

    • Author(s)
      H. E. Ooyama, and K. Yoshida
    • Organizer
      The Eleventh International Kyoto Con-ference on New Aspects of Organic Chemistry
    • Place of Presentation
      Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-10
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis and Photophysical Properties of Polycyclic Phenazine-type Fluorescent Dyes(1)2009

    • Author(s)
      Haruka E.Ooyama
    • Organizer
      The Eleventh International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] アントラキノイド系ホウ素錯体の結晶構造と固体発光性2009

    • Author(s)
      板倉章博、上野友徳、吉田勝平
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-07
    • Related Report
      2011 Final Research Report
  • [Presentation] 複素多環フェナジン系蛍光色素の合成と光物性2009

    • Author(s)
      谷上拓也、日野利彦、吉田勝平
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-07
    • Related Report
      2011 Final Research Report
  • [Presentation] 新規アゾ-ヒドラゾン系蛍光色素の光物性に及ぼすホウ素錯体化と置換基効果2009

    • Author(s)
      中川安由、大山晴香、坂本武大、吉田勝平
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-07
    • Related Report
      2011 Final Research Report
  • [Presentation] 新規アゾーヒドラゾン系蛍光色素の光物性に及ぼすホウ素錯体化と置換基効果2009

    • Author(s)
      吉田勝平
    • Organizer
      2009日本化学会西日本大会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] 複素多環フェナジン系蛍光色素の合成と機能評価2009

    • Author(s)
      吉田勝平
    • Organizer
      2009日本化学会西日本大会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] アントラキノイド系ホウ素錯体の結晶構造と固体発光性2009

    • Author(s)
      吉田勝平
    • Organizer
      2009日本化学会西日本大会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-07
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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