Project/Area Number |
21550208
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Polymer/Textile materials
|
Research Institution | Nagoya Institute of Technology |
Principal Investigator |
OKAMOTO Shigeru 名古屋工業大学, 大学院・工学研究科, 准教授 (50262944)
|
Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
|
Keywords | ポリマーアロイ / ブロック共重合体 / 準希薄溶液 / 選択溶媒 / 巨大グレイン / フォトニック結晶 / 小角X線散乱 / 超高分子量 / ミクロ相分離構造 / 構造形成メカニズム |
Research Abstract |
We found that microphase separation takes place in semidilute solutions of various kinds of block copolymers using common solvent, such as toluene, tetrahydrofuran, dioctylphthalate, diisopropylbenzene, benzene, etc and non-solvent, such as methanol, cyclohexane, octane, decane, tetradecane, etc. It was also found that selectivity was effectively controlled by temperature change to induce microphase separation in semi-dilute solutions. This technique allowed us to observe the grain formations in detail.
|