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Direct Observation of Dynamic Heterogeneity in Glass Forming Materials with Temperature Modulated X-ray Diffraction

Research Project

Project/Area Number 21654059
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Biophysics/Chemical physics
Research InstitutionKyoto Institute of Technology

Principal Investigator

SARUYAMA Yasuo  京都工芸繊維大学, 工芸科学研究科, 教授 (50162532)

Co-Investigator(Kenkyū-buntansha) YAO Haruhiko  京都工芸繊維大学, 工芸科学研究科, 准教授 (60212271)
Co-Investigator(Renkei-kenkyūsha) FUKAO Koji  立命館大学, 理工学部, 教授 (50189908)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,340,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2009: ¥1,200,000 (Direct Cost: ¥1,200,000)
Keywords物性実験 / 温度変調X線回析 / ガラス転移 / 動的不均一性 / 熱容量測定 / 温度変調X線回折 / X線小角散乱
Research Abstract

In this research direct observation of the dynamic heterogeneity has been tried using X-ray diffraction coupled with temperature modulation technique which has been developed as a technique for thermal analysis. An experimental system was successfully developed, however, the heterogeneity could not be observed. It has been considered that the reason of the failure was the one dimensional shape of the dynamically heterogeneous regions as proposed recently. It was found that the temperature modulated X-ray experiment was very useful in studies of the structure of semi-crystalline polymers.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (5 results)

All 2011 2010

All Presentation (5 results)

  • [Presentation] Simultaneous Measurement of Calorimetry and X-ray Diffraction with AC Calorimeter and Synchrotron Radiation2011

    • Author(s)
      Yukari Oka, Naoki Koyabu, Haruhiko Yao, Yasuo Saruyama
    • Organizer
      6th International & 8th Japan-China Joint Symposium on Calorimetry and Thermal Analysis
    • Place of Presentation
      首都大学東京、南大沢キャンパス
    • Year and Date
      2011-08-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] X線回折とACカロリメトリーの同時測定:ポリエチレンオキシド結晶のアニーリング効果2011

    • Author(s)
      小薮尚紀、岡有香里、八尾晴彦、深尾浩次、猿山靖夫
    • Organizer
      第47回熱測定討論会
    • Place of Presentation
      桐生市市民文化会館
    • Related Report
      2011 Final Research Report
  • [Presentation] X線回折とacカロリメトリーの同時測定2010

    • Author(s)
      岡有香里、田中康裕、及川孝、百田洋、八尾晴彦、猿山靖夫
    • Organizer
      第46回熱測定討論会
    • Place of Presentation
      三重大学
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] A Novel Apparatus for Simultaneous Measurement of X-ray Scattering and Heat Capacity2010

    • Author(s)
      Y.Oka, Y.Saruyama, H.Yao
    • Organizer
      21st IUPAC International Conference on Chemical Thermodynamics
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2010-08-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] Novel Apparatus for Simultaneous Measurement of X-ray Scattering and Heat Capacity2010

    • Author(s)
      Y. Oka, Y. Saruyama, H. Yao
    • Organizer
      ICCT-2010
    • Place of Presentation
      つくば市
    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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