| Project/Area Number |
21656198
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Properties in chemical engineering process/Transfer operation/Unit operation
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| Research Institution | Akita University |
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Principal Investigator |
MURAKAMI Kenji 秋田大学, 工学資源学研究科, 准教授 (10272030)
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| Co-Investigator(Kenkyū-buntansha) |
INOUE Yukihiko 秋田大学, 工学資源学研究科, 講師 (50232567)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥3,250,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2009: ¥1,400,000 (Direct Cost: ¥1,400,000)
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| Keywords | メソポーラスシリカ / 感温性高分子 / イオン交換 / 有機無機複合体 / ゾルゲル法 / 分子ふるい |
|---|
| Research Abstract |
A novel adsorbent was developed by immobilizing a temperature-responsive polymer (the volume of this polymer changes with changing in the solution temperature) on the external surface of adsorbent. This material adsorbed and desorbed molecules with pH of the solution reversibly at lower temperature of 25℃, while it did not adsorb and desorb molecules independent of pH of the solution at higher temperature of 40℃. Also, it was found this phase-transition temperature shifted by about 5℃ to the higher temperature for the adsorbent prepared by the addition of cross-linking agent during the polymer synthesis. From these results, this temperature-responsive adsorbent can be applied to the carrier for drug delivery system and column packing agent for temperature-gradient chromatography.
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