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Approach using reactor design to suppress a deep oxidation in the oxidative dehydrogenation of propane over solid catalysts

Research Project

Project/Area Number 21656210
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Catalyst/Resource chemical process
Research InstitutionThe University of Tokushima

Principal Investigator

SUGIYAMA Shigeru  徳島大学, 大学院・ソシオテクノサイエンス研究部, 教授 (70175404)

Co-Investigator(Kenkyū-buntansha) SOTOWA Ken-ichiro  徳島大学, 大学院・ソシオテクノサイエンス研究部, 准教授 (00336009)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,380,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2009: ¥1,700,000 (Direct Cost: ¥1,700,000)
Keywords触媒反応 / マイクロリアクタ / プロパン / 酸化脱水素 / プロピレン / 単元系酸化物触媒 / イソブタン / イソブチレン / ストロンチウム水酸アパタイト / マグネシウムモリブデート / カルシウム水酸アパタイト / マグネシウバナデート
Research Abstract

A microreactor was employed for the oxidative dehydrogenation of propane to propylene in order to suppress a deep oxidation of the resultant propylene to CO and CO_2. The enhancement of the selectivity to propylene was the most advantageous effect from using the microreactor, and it occurred when calcium hydroxyapatite was used under an unsteady-state on reaction temperature. For example, the selectivity to propylene was 0 and 73. 0% using a fixed-bed continuous-flow reactor and the microreactor, respectively, under almost identical propane conversion of 3. 1 and 3. 2%, respectively.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (22 results)

All 2011 2010 2009

All Journal Article (4 results) (of which Peer Reviewed: 2 results) Presentation (16 results) Book (2 results)

  • [Journal Article] アパタイトの特異触媒活性と接触型マイクロリアクタを用いた省資源化の試み2011

    • Author(s)
      杉山茂
    • Journal Title

      セラミックス

      Volume: Vol.46、No.9 Pages: 735-738

    • NAID

      10030200791

    • URL

      http://www.ceramic.or.jp/ihensyub/bulletin_j/contents_j/2011_j/2011_09.html

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Journal Article] 希少資源リンの高度化利用に向けた新規リン戦略2010

    • Author(s)
      杉山茂
    • Journal Title

      Phosphorus Letter

      Volume: No.68 Pages: 19-26

    • NAID

      40017171747

    • URL

      http://www.jaipc.jp/?page_id=164

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Journal Article] Application of a Microreactor in the Oxidative Dehydrogenation of Propane to Propylene on Calcium Hydroxyapatite and Magnesium ortho-Vanadate Doped and Undoped with Palladium2010

    • Author(s)
      S. Sugiyama, N. Sugimoto, A. Ozaki, Y. Furukawa, K. Nakagawa and K.-I. Sotowa
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: Vol.43, No.7 Pages: 575-580

    • NAID

      10027373076

    • URL

      https://www.jstage.jst.go.jp/article/jcej/43/7/43_43.575/_pdf

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Application of a Microreactor in the Oxidative Dehydrogenation of Propane to Propylene on Calcium Hydroxyapatite and Magnesium ortho-Vanadate Doped and Undoped with Palladium2010

    • Author(s)
      Sugiyama S, et al.
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: 43 Pages: 575-580

    • NAID

      10027373076

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] プロパンの接触酸化脱水素用マイクロリアクタに対する最適触媒の探索2011

    • Author(s)
      杉山茂・古川幸美・米田沙織・杉本直登・中川敬三・外輪健一郎
    • Organizer
      第108回触媒討論会(触媒討論会A)
    • Place of Presentation
      北見工業大学(北見市)
    • Year and Date
      2011-09-22
    • Related Report
      2011 Final Research Report
  • [Presentation] プロパンの接触酸化脱水素用マイクロリアクタに対する最適触媒の探索2011

    • Author(s)
      杉山茂
    • Organizer
      第108回触媒討論会(触媒討論会A)
    • Place of Presentation
      北見工業大学(北海道)
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] 固体触媒によるプロパン酸化脱水素反応の完全酸化抑制に対するマイクロリアクタの応用2011

    • Author(s)
      杉山茂
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学(愛知県)(優秀論文賞受賞講演)(招待講演)
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] 固体触媒によるプロパン酸化脱水素反応の完全酸化抑制に対するマイクロリアクタの応用2011

    • Author(s)
      杉山茂・杉本直登・尾崎あずさ・古川幸美・中川敬三・外輪健一郎
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学(名古屋市)
    • Year and Date
      2011-09-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Application of Magnesium Vanadates and Calcium Hydroxyapatite as a Catalyst for the Oxidative Dehydrogenation of Propane Using Microreactor2010

    • Author(s)
      S. Sugiyama, N. Sugimoto, A. Ozaki, Y. Furukawa, K. Nakagawa, K.-I. Sotowa
    • Organizer
      6th Tokyo Conference on Advanced Catalytic Science and Technology & 5th Asia Pacific Congress on Catalysis
    • Place of Presentation
      Sapporo Convention Center(Japan)
    • Year and Date
      2010-07-20
    • Related Report
      2011 Final Research Report
  • [Presentation] マイクロリアクタによるプロパン酸化脱水素反応への酸化物およびリン酸塩触媒の適応性2010

    • Author(s)
      杉山茂, 他
    • Organizer
      第105回触媒討論会(触媒討論会A)
    • Place of Presentation
      京都テルサ(京都)
    • Year and Date
      2010-03-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] マイクロリアクタによるプロパン酸化脱水素反応への酸化物およびリン酸塩触媒の適応性2010

    • Author(s)
      杉山茂・杉本直登・尾崎あづさ・古川幸美・中川敬三・外輪健一郎
    • Organizer
      第105回触媒討論会(触媒討論会A)
    • Place of Presentation
      京都テルサ(京都市)
    • Year and Date
      2010-03-24
    • Related Report
      2011 Final Research Report
  • [Presentation] 希少資源リンの高度化利用に向けた新規リン戦略2010

    • Author(s)
      杉山茂
    • Organizer
      第2回機能性材料勉強会
    • Place of Presentation
      神戸薬科大学
    • Year and Date
      2010-03-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Highly Selective Production of Propylene from the Oxidative Dehydrogenation of Propane on Hydroxyapatite Using Micro-reactor2010

    • Author(s)
      S. Sugiyama, N. Sugimoto, A. Ozaki, Y. Furukawa, K. Nakagawa, K.-I. Sotowa
    • Organizer
      11th International Conference on Microreaction Technology
    • Place of Presentation
      Kyoto Research Park, Kyoto(Japan)
    • Year and Date
      2010-03-08
    • Related Report
      2011 Final Research Report
  • [Presentation] Application of Magnesium Vanadates and Calcium Hydroxyapatite as a Catalyst for the Oxidative Dehydrogenation of Propane Using Microreactor2010

    • Author(s)
      Sugiyama S, et al.
    • Organizer
      6th Tokyo Conference on Advanced Catalytic Science and Technology & 5th Asia Pacific Congress on Catalysis Catalytic
    • Place of Presentation
      Sapporo Convention Center
    • Related Report
      2010 Annual Research Report
  • [Presentation] Highly Selective Production of Propylene from the Oxidative Dehydrogenation of Propane on Hydroxyapatite Using Microreactor2010

    • Author(s)
      Sugiyama S, et al
    • Organizer
      11th International Conference on Microreaction Technology
    • Place of Presentation
      Kyoto Research Park, Kyoto (Japan)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Oxidative Dehydrogenation of Propane in Microreactor under Steady-state and Unsteady-state Opera-tions2009

    • Author(s)
      N. Sugimoto, K. Nakagawa, K.-I. Sotowa, S. Sugiyama
    • Organizer
      22nd Symposium on Chemical Engineering
    • Place of Presentation
      International Convention Center(Daejeon, Korea)
    • Year and Date
      2009-12-05
    • Related Report
      2011 Final Research Report
  • [Presentation] Oxidative Dehydrogenation of Propane in Microreactor under Steady-state and Unsteady-state Operations2009

    • Author(s)
      Sugiyama S, et al
    • Organizer
      22nd Symposium on Chemical Engineering
    • Place of Presentation
      International Convention Center (Daejeon, Korea)
    • Year and Date
      2009-12-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] 定常操作下におけるマイクロリアクタによるプロパンの酸化脱水素反応2009

    • Author(s)
      杉山茂・杉本直登・古川幸美・中川敬三・外輪健一郎
    • Organizer
      第2回化学工学3支部合同北九州大会
    • Place of Presentation
      西日本総合展示場(北九州市)
    • Year and Date
      2009-10-31
    • Related Report
      2011 Final Research Report
  • [Presentation] マイクロリアクタによるプロパン酸化脱水素反応2009

    • Author(s)
      杉本直登・尾崎あづさ・中川敬三・外輪健一郎・杉山茂
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学(広島市)
    • Year and Date
      2009-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] マイクロリアクタによるプロパン酸化脱水素反応2009

    • Author(s)
      杉山茂, 他
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学
    • Related Report
      2009 Annual Research Report
  • [Book] 触媒調製ハンドブック第2編金属酸化物触媒第3章複合酸化物第5節ヒドロキシアパタイト2011

    • Author(s)
      杉山茂
    • Publisher
      (株)エヌ・ティー・エス
    • Related Report
      2011 Final Research Report
  • [Book] 触媒調製ハンドブック第2編金属酸化物触媒第3章複合酸化物5節ヒドロキシアパタイト2011

    • Author(s)
      杉山茂(共著)
    • Publisher
      株式会社エヌ・ティー・エス
    • Related Report
      2011 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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