Creation of Functional Molecules Based on Borylated Porphyrins
| Project/Area Number |
21685011
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥27,430,000 (Direct Cost: ¥21,100,000、Indirect Cost: ¥6,330,000)
Fiscal Year 2011: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2010: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2009: ¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
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| Keywords | π共役系 / クロスカップリング / パラジウム / ホウ素 / ポルフィリン / 炭素.炭素結合生成 / 触媒 / 遷移金属 / 炭素-炭素結合生成 |
|---|
| Research Abstract |
Synthesis of novel porphyrin oligomers has been achieved with borylated porphyrins as key building blocks. Cross-coupling of tetraborylated porphyrin with tetrabromo porphyrin provided a tetrameric porphyrin tube, which has an inner cavity with a diameter of 14A. The X-ray diffraction analysis elucidated that the porphyrin tube encapsulates a C_60 molecule in its cavity and the interaction between the tube and C_60 constructs a 3D network in the solid state.
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Report
(4 results)
Research Products
(128 results)
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[Journal Article] Synthesis of a diimidazolylporphyrin pincer palladium complex2011
Author(s)
Yamamoto, J., Shimizu, T., Yamaguchi, S., Aratani, N., Shinokubo, H., Osuka, A.
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Journal Title
J.Porphyrins Phthalocyanines
Volume: 15
Issue: 07n08
Pages: 534-538
DOI
Related Report
Peer Reviewed
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[Journal Article] Regioselective Ru-Catalyzed Direct 2, 5, 8, 11-Alkylation of Perylene Bisimides2009
Author(s)
S. Nakazono, Y. Imazaki, H. Yoo, J. Yang, T. Sasamori, N. Tokitoh, T. Cedric, H. Kageyama, D. Kim, H. Shinokubo, A. Osuka
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Journal Title
Chem. Eur. J.
Volume: 15
Issue: 31
Pages: 7530-7533
DOI
Related Report
Peer Reviewed
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