| Project/Area Number |
21750038
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
SASE Shohei Tokyo Institute of Technology, 大学院・理工学研究科, 特任助教 (90515165)
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| Project Period (FY) |
2009 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Keywords | 有機金属化学 / N-複素環カルベン / ニッケル / パラジウム / 銀 / 触媒反応 |
|---|
| Research Abstract |
Various transition metal complexes bearing bowl-shaped carbene ligands based on m-phenylene dendrimer frameworks were synthesized. The nickel and palladium complexes bearing the bowl-shaped ligand were proved to act as a catalyst for cyclotrimerization of alkynes and Suzuki-Miyaura cross-coupling reaction, respectively. The silver complexes are a "bowl-shaped carbene transfer agent", and they reacted smoothly with various transition metal complexes, such as palladium and iridium complexes, to afford the corresponding metal complexes in good yield.
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