Synthesis and photophysical properties of chiral phthalocyanine dyes with swastika geometry
| Project/Area Number |
21750052
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | The Institute of Physical and Chemical Research |
|---|
Principal Investigator |
MURANAKA Atsuya The Institute of Physical and Chemical Research, 先進機能元素化学研究チーム, 基礎科学特別研究員 (20374902)
|
|---|
| Project Period (FY) |
2009 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
|
|---|
| Keywords | 磁気キラル二色性 / 円二色性 / 磁気円二色性 / フタロシアニン |
|---|
| Research Abstract |
Novel chiral phthalocyanine dyes with swastika geometry have been synthesized and their photophysical properties have been investigated in order to develop organic molecules having intense circular dichroism (CD) and magnetic circular dichroism (MCD) signals. Such a molecule is expected to exhibit magneto-chiral dichroism, which is regared as a new magneto-optical effect. Some chiral isomers of the phthalocyanine derivatives were separated by using HPLC techniques, and measured CD and MCD spectra. The absolute configuration of the chiral isomers was determined by quantum chemical calculations.
|
Report
(3 results)
Research Products
(11 results)
