Development of chiral economical and highly efficient asymmetric catalysis
| Project/Area Number |
21750093
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
AIKAWA Kohsuke Tokyo Institute of Technology, 大学院・理工学研究科, 助教 (30401532)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2009: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | 不斉合成 / 不斉反応 / 不斉金属触媒 / 立体選択的 / 有機合成化学 / 有機ケイ素化合物 / ヘテロ環 / ルイス酸触媒 / フラン / ピロール / 有機金属錯体 / 不斉配位子 / ラセミ体 / アリール化 / エン反応 |
|---|
| Research Abstract |
We have developed a variety of novel and atom economical asymmetric carbon-carbon forming reactions catalyzed by cationic chiral palladium complex as a Lewis acid. We demonstrated that the chiral Pd-complexes are 1) air- and moisture-stable, 2) easily synthesized, and 3) catalytically very active (up to 0.01mol%) with high yield and enantioselectivity.
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Report
(3 results)
Research Products
(40 results)
