Construction of π-Electron Rich Molecular Tubes Using para-Bridged Macrocyclic Host Molecules

• Project/Area Number: 21750140
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Functional materials chemistry
• Research Institution: Kanazawa University
• Principal Investigator: OGOSHI Tomoki Kanazawa University, 物質化学系, 准教授 (00447682)
• Project Period (FY): 2009 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000); Fiscal Year 2009: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
• Keywords: Pillar[5]arene / ポリロタキサン / 分子チューブ / 水素結合 / ピラー[5]アレーン / 環状ホスト分子 / フェノール / ホスト-ゲスト包接錯体 / 対称性 / 柱構造 / ピラー[5]アレン / 超分子 / ホストーゲスト包接錯体 / ビオロゲンポリマー / 電荷移動錯体

Research Abstract

New polyrotaxane composed of pillar[5]arene and viologen polymer was successfully prepared with extremely high yield by capping the chain ends with adamantyl moieties. We also prepared organo-nanotubes from pillar[5]arene molecules via inter-molecular hydrogen bonding between the molecules.

Research Products

• [Journal Article] Monofunctionalized Pillar[5]arenes : Synthesis and Supramolecular Structure. (2011)
  • Author(s): Ogoshi, T., Demachi K., Kitajima, K., Yamagishi, T.
  • Journal Title: Chem.Commun. in press
• [Journal Article] Facile, Rapid, and High-Yield Synthesis of Pillar[5]arene from Commercially Available Reagents and Its X-ray Crystal Structure (2011)
  • Author(s): 生越友樹、青木崇倫、北島啓資、藤波修平、山岸忠明、中本義章
  • Journal Title: J.Org.Chem. Volume: 76 Pages: 328-331
  • Peer Reviewed
• [Journal Article] Effect ofIntra-Molecular Hydrogen Bond Beltand Complexation with Guest onRotation Behavior of Phenolic Unitsin Pillar[5]arenes. (2010)
  • Author(s): Ogoshi, T., Kitajima, K., Aoki, Y., Yamagishi, T., Nakamoto, Y.
  • Journal Title: J.Phys.Chem.Lett. 1 Pages: 817-821
• [Journal Article] Polypseudorotaxane Constructed from Pillar[5]arene and Viologen Polymer. (2010)
  • Author(s): Ogoshi, T., Nishida, Y., Yamagishi, T., Nakamoto, Y.
  • Journal Title: Macromolecules 43 Pages: 3145-3147
• [Journal Article] High Yield Synthesisof Polyrotaxane Constructed from Pillar[5]arene and Viologen Polymerand Stabilization of Its RadicalCation. (2010)
  • Author(s): Ogoshi, T., Nishida, Y., Yamagishi, T., Nakamoto, Y.
  • Journal Title: Macromolecules 43 Pages: 7068-7072
• [Journal Article] High Yield Synthesis of Polyrotaxane Constructed from Pillar[5]arene and Viologen Polymer and Stabilization of Its Radical Cation (2010)
  • Author(s): 生越友樹、西田陽子、山岸忠明、中本義章
  • Journal Title: Macromolecules Volume: 43 Pages: 7068-7072
  • Peer Reviewed
• [Journal Article] Synthesis and Conformational Chazacteristics of Alkyl-Substituted Pillaz[5]arenes (2010)
  • Author(s): 生越友樹、北島啓資、青木崇倫、藤波修平、山岸忠明、中本義章
  • Journal Title: J.Org.Chem. Volume: 75 Pages: 3268-3273
  • Peer Reviewed
• [Journal Article] Polypseudorotaxane Constructed from Pillar[5]arene and Viologen Polymer (2010)
  • Author(s): 生越友樹、西田陽子、山岸忠明、中本義章
  • Journal Title: Macromolecules 43 Pages: 3145-3147
  • Peer Reviewed
• [Journal Article] Effect of Intra-Molecular Hydrogen Bond Belt and Complexation with Guest on Rotation Behavior of Phenolic Units in Pillar [5] arenes (2010)
  • Author(s): 生越友樹、北島啓資、青木崇倫、山岸忠明、中本義章
  • Journal Title: J.Phys.Chem.Lett. 1 Pages: 817-821
  • NAID: 130004597247
  • Peer Reviewed
• [Journal Article] Synthesis and Conformational Characteristics of Nonsymmetric Pillar [5] arene (2010)
  • Author(s): 生越友樹、北島啓資、山岸忠明、中本義章
  • Journal Title: Org.Lett. 12 Pages: 636-638
  • Peer Reviewed
• [Journal Article] Through-Space・-Delocalized Pillar[5]arene. (2009)
  • Author(s): Ogoshi, T., Umeda, K., Yamagishi, T., Nakamoto, Y.
  • Journal Title: Chem.Commun. Pages: 4874-4876
• [Presentation] 新規環状ホスト分子"Pillar[5]arene"の合成と超分子材料への応用 (2011)
  • Author(s): 生越友樹
  • Organizer: 第11回リング-チューブ超分子研究会シンポジウム
  • Place of Presentation: 東京工業大学・大岡山キャンパス 招待講演
  • Year and Date: 2011-03-10
• [Presentation] 新規環状ホスト分子"Pillar[5]arene"の合成と超分子材料への応用 (2011)
  • Author(s): 生越友樹
  • Organizer: 第11回リング・チューブ超分子研究会シンポジウム
  • Place of Presentation: 東京工業大学大岡山キャンパス
  • Year and Date: 2011-03-10
• [Presentation] 新規環状ホスト分子"Pillar[5]arene"の合成と超分子材料への応用 (2010)
  • Author(s): 生越友樹
  • Organizer: 第56回高分子研究発表会(神戸)
  • Place of Presentation: 兵庫県民会館 ヤングサイエンティスト講演
  • Year and Date: 2010-07-16
• [Presentation] 環状ホスト分子の合成とハイブリッド材料への応用 (2010)
  • Author(s): 生越友樹
  • Organizer: 第131回東海高分子研究会講演会
  • Place of Presentation: 名古屋工業大学 招待講演
  • Year and Date: 2010-04-24
• [Presentation] 環状ホスト分子の合成とハイブリッド材料への応用 (2010)
  • Author(s): 生越友樹
  • Organizer: 10-1精密ネットワークポリマー研究会
  • Place of Presentation: 東京工業大学・大岡山キャンパス 招待講演
  • Year and Date: 2010-04-16
• [Presentation] 環状ホスト分子の合成とハイブリッド材料への応用 (2009)
  • Author(s): 生越友樹
  • Organizer: 国際高分子基礎センター講演会
  • Place of Presentation: 東京工業大学・大岡山キャンパス 招待講演
  • Year and Date: 2009-12-02
• [Presentation] 環状ホスト分子の合成とハイブリッド材料への応用 (2009)
  • Author(s): 生越友樹
  • Organizer: 平成21年度北陸地区高分子若手研究会
  • Place of Presentation: ウェルサンピア新潟(新潟県)
  • Year and Date: 2009-08-26
• [Remarks] ホームページ等
  • URL: http://kohka.ch.t.kanazawa-u.ac.jp/lab3/lab3.html6
• [Remarks]
  • URL: http://kohka.ch.t.kanazawa-u.ac.jp/lab3/lab3.html
• [Remarks]
  • URL: http://kohka.ch.t.kanazawa-u.ac.jp/lab3/lab3.html